SPI Supplies Division|
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Date Effective... July 31, 2009
(most recent revision)
Chemical Name..... Silver paint
Chemical family...
Mixture of solvents, resins
and silver metal particles
Emergencies
Use Only #'s:
Contacting CHEMTREC 24 Hour Emergency
Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name...
SPI #05001 and #05002 SPI Silver Paint;
#05005-AB Silver Streaker;
#05008-AB Silver Quick-Stik
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Hazardous Material Information System USA |
Health | 2 |
National Fire Protection Association USA |
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| Fire Hazard | 3 | |||
| Reactivity | 1 | |||
| Personal Protection | B |
CAS #............. Chemical Name V.P. mm LEL Weight%
Hg@20C
7440-22-4 Silver (metallic) n/a n/a 35-65
108-65-6 1-methoxy-2-propanol acetate 3.7 1.5 10-30
123-86-4 Butyl acetate 1.0 1.7 10-30
65859-05-4 Acrylic resin n/a n/a 5-10%
Chemical Formula......... Proprietary mixture
Emergency overview: Appearance: Gray Paste Flash Point: 76 °F (TCC), Butyl Acetate – Lowest Flashing component Warning! Flammable; Eye or Skin Irritant Target Organs: Liver, Kidneys, Central Nervous System Potential Health Effects Eye: Irritating to the eyes. May cause tearing, redness, swelling or temporary corneal damage. Skin: Irritating to the skin. Prolonged contact may cause dermatitis. Ingestion: May cause headache, drowsiness and unconsciousness. Inhalation: May cause irritation to the respiratory tract and to other mucous membranes. Silver metallic Human effects of higher level acute, repeated or chronic overexposure my include argyria. 1-methoxy-2-propanol acetate Toxic effects described in animals include: By skin or eye contact: Mild skin irritation; eye irritation. Toxic effects of repeated or prolonged animal exposures include, by skin or eye contact: Skin effects; by inhalation. Respiratory effects: Degeneration of the olefractory epithelium; renal effects; non-specific effects, e.g. weight loss and irritation; liver effects. Additional animal tests have shown: No genetic damage in bacterial or mammalian cell cultures; no developmental toxicity. Human health effects of over exposure may include: By skin or eye contact; Skin irritation with discomfort or rash Eye irritation with discomfort, tearing or blurring of vision By inhalation: Nonspecific discomfort, e. g. nausea, headache, or weakness Human effects of higher level acute, repeated, or chronic overexpose my include: By inhalation: Irritation to the upper respiratory passages with coughing and discomfort. In addition, animal tests indicate commercial grade 1- methoxy-2-propanol acetone does not cause developmental toxicity. However, the tests of pure 2-methoxy-1-propanol acetate in rabbits and rats by inhalation have shown developmental toxicity. 2-methoxy-propanol acetate did not show developmental toxicity by skin contact. 2-methoxy-1-propanol acetate did not show developmental toxicity by skin contact. 2-methoxy-1-propanol acetate is present in commercial grade 1-methoxy-2-propanol acetate in low concentrations. Butyl acetate Toxic effects described in animals include: By skin or eye contact: Skin Irritation; eye irritation By inhalation: Eye irritation, narcosis; upper respiratory irritation By ingestion: Narcosis Toxic effects of repeated or prolonged animal exposures include: By inhalation: Eye irritation; lower weight gain By ingestion: Liver effects Toxic effects of chronic animal tests include: By inhalation: Liver effects Additional animal tests have shows: Developmental toxicity at dosage levels showing maternal toxicity ; no genetic damage in animals, bacterial, or mammalian cell cultures. Human health effects of overexposure may include: By skin or eye contact: Skin irritation with discomfort, tearing, or blurring of vision By inhalation: Irritation of the upper respiratory passages with coughing and discomfort; nonspecific discomfort, e. g. nausea, headache or weakness. Human effects of higher level acute repeated or chronic overexposure may include: Temporary nervous system depression with anaesthetic effect, e. g. dizziness, headache, confusion, loss of coordination, loss of consciousness. Abnormal liver function as detected by laboratory tests. In addition: By skin or eye contact: Significant skin permeation appears unlikely; there are inconclusive or unverified reports of human sensitization. Acrylic resin Toxic effects described in animals include: Slight skin irritation Human health effects of overexposure my include: Allergic skin rashes Eye irritation with discomfort, tearing, or blurring of vision Nonspecific discomfort, e. g. nausea, headache, weakness Irritation of the upper respiratory passages, dizziness
Eyes: Immediately flush with copious amounts of water for at least 15 minutes. Seek medical attention if discomfort persists. Skin: Remove contaminated clothing and wash skin with soap and water. If irritation persists, seek medical attention. Ingestion: Give two or more glasses of water immediately. Do NOT induce vomiting. Seek immediate medical attention. Inhalation: Remove to fresh air. If breathing is difficult, give oxygen and seek immediate medical attention.
Flash Point..................... 76°F Explosive Limits (%V in air): LEL: 1.5 UEL: 10.0 Fire Extinguishing Media: Dry Chemical, CO2, water foam, "alcohol" foam, water spray to cool fire-exposed containers and disperse vapor. Firefighting Procedure: Toxic decomposition products may form under fire conditions. Wear full protective clothing and a full facepiece, positive pressure, self contained breathing apparatus (SCBA). Fire and explosion hazards: Easily ignited material which burns wit intense heat. Keep away from sparks and open flames. Do not smoke in area with open product. The solvent vapors are heavier than air and may travel along the floor to a source of ignition and flashback. Use the product in areas and equipment with appropriate National Electrical Code (NEC) classification. Consider the need for spark proof tools. If the product could be heated above its flashpoint during processing or use, remove all sources of ignition, such as sparks, flames, or static discharge to prevent vapor ignition. Be sure also to decontaminate contaminated clothing and equipment with soap and water. Dispose of residues per federal, state, and local regulations. Closed containers may explode from increased vapor pressure when exposed to extreme heat. Cool overheated closed containers with water spray, but do not spread the fire with cooling water.
Spill Response: Evacuate the area of all unnecessary personnel. Action to take for spills: For small spills: Absorb on to rags, sand, or other absorbent material. For large spills: Get workers out of the affected area. If flammable liquids or vapors may be present, turn off electrical devices or other sources of sparks or flames. Wear protective equipment. Use supplied-air respiratory protection if vapor concentrations are not known. Contain spill at source by diking or absorbing with sand. Do not allow spill to spread to or intentionally flush to sewer or ground. Wash area thoroughly. Adequately ventilate area. Spill residue, cleaning rags, and absorbent may be refined to recover the precious metal content. Disposal considerations: Components of this product may be considered hazardous, waste product may be refined to recover previous metal content.
Handling: Adequate local ventilation should be used to keep exposures below applicable limits. Other engineering controls such as totally enclosed handling systems are also preferred; respiratory protection will be needed if exposures can not be kept below applicable limits by other means. Respiratory protection: Selection of a suitable respirator will depend on the properties of the contaminant (s) and their actual or expected air concentration vs. applicable limits. Consult ANSI Standard Z988.2 for decision logic to select appropriate NIOSH/MESA approved respirators. If respirators are needed to meet applicable limits, a respiratory protection program up to the level of OSHA Standard 29 CFR 1910.134 is mandatory. This includes air monitoring, selection, medical approval, training, fit testing, inspection, maintenance, cleaning, storage, etc. Gloves: Should be used when the possibility of skin contact exists. Impervious gloves (rubber or neoprene) should be used to avoid direct skin contact. Eye Protection: Chemical splash goggles. Protective Clothing: Protective clothing suitable to prevent skin contact should be used. Smoking and eating: Do not smoke, consume or store food or drinks in areas where the product is handled or stored. After handling the product, wash hands thoroughly before leaving the work area. Additional engineering controls, work practices and training may be required depending on exposure levels. These are discussed in the OSHA respiratory protection standard (290 CFR 1910.134) and OSHA Hazard Communications Standard(29 CFR 1910.120). Contaminated items: Empty product containers, contaminated clothing and cleaning materials, etc. should be considered hazardous until decontaminated or properly disposed according to federal, state and local laws and regulations.
Engineering Controls:
An eyewash station and emergency shower must be available to the work station.
Exposure Limits:
Chemical Name ACGIH NIOSH OSHA - Final PELs
Silver(metallic) 0.1 mg/m3 0.01 mg/m3 TWA 0.01 mg/m3 TWA
10 mg/m3 IDHL
Propylene Glycol Methyl Ethyl Acetate
N/A N/A N/A
Butyl Acetate 150 ppm 150 ppm TWA 150 ppm TWA
200 ppm STEL 170 mg/m3 TWA 710 mg/m3 TWA
1700 ppm IDHL
OSHA Vacated PELs: n-Butyl Acetate: 150 ppm TWA; 710 mg/m3 TWA
Personal Protective Equipment
Eyes: Chemical splash goggles
Skin: Impervious gloves (rubber, neoprene) to prevent skin contact
Clothing: Protective clothing suitable to prevent skin contact.
Respirators:
Selection of a suitable respirator will depend on the properties of the contaminant (s) and
their actual or expected air concentration vs. applicable limits. Consult ANSI Standard Z988.2
for decision logic to select appropriate NIOSH/MESA approved respirators. If respirators are
needed to meet applicable limits, a respiratory protection program up to the level of OSHA Standard
29 CFR 1910.134 is mandatory. This includes air monitoring, selection, medical approval, training,
fit testing, inspection, maintenance, cleaning, storage, etc.
Boiling Point............ 259-284 ° F Formula Weight........... Not available Coeff. of Water/Oil Dist. Not available pH (Liquids Only)........ Not available % Volatile By Volume..... 30-40% Melting Point............ Not available Vapor Pressure........... 6mm @ 20 ° C Vapor Density/Air is 1... Heavier than air Solubility In Water Appreciable >10% Appearance and Color...... Gray paste Specific Gravity (H2O = 1) 1.8 – 2.0 Evaporation Rate (n-butyl acetate = 1): Slower Odor..................... Mild "fruity" smell Flash Point: 76° F Explosive Limits: (TAG) Lower: 1.5 Upper: 10.0
Stable: Yes Hazardous Polymerization: This product does not normally polymerize significantly. Hazardous Decomposition Products: At high temperature may include COx (carbon dioxide / carbon monoxide), water, nitrogen oxides, ethyl methacrylate, methyl acrylate Conditions to avoid: Heat, Contact with ignition source Materials to avoid: Oxidizing agents, acids, potassium tert-butoxide, reducing agents Instability: This product is normally stable.
1-methoxy-2-propanol acetate Toxic effects described in animals include: By skin or eye contact: Mild skin irritation; eye irritation. Toxic effects of repeated or prolonged animal exposures include, by skin or eye contact: Skin effects; By inhalation. Respiratory effects: Degeneration of the olefractory epithelium; renal effects; non-specific effects, e.g. weight loss and irritation; liver effects. Additional animal tests have shown: No genetic damage in bacterial or mammalian cell cultures; no developmental toxicity. Human health effects of over exposure may include: By skin or eye contact; Skin irritation with discomfort or rash Eye irritation with discomfort, tearing or blurring of vision By inhalation: Nonspecific discomfort, e. g. nausea, headache, or weakness Human effects of higher level acute, repeated, or chronic overexpose may include: Irritation to the upper respiratory passages with coughing and discomfort. In addition, animal tests indicate commercial grade 1- methoxy-2-propanol acetone does not cause developmental toxicity. However, the tests of pure 2-methoxy-1-propanol acetate in rabbits and rats by inhalation have shown developmental toxicity. 2-methoxy-propanol acetate did not show developmental toxicity by skin contact. 2-methoxy-1-propanol acetate did not show developmental toxicity by skin contact. 2-methoxy-1-propanol acetate is present in commercial grade 1-methoxy-2-propanol acetate in low concentrations. Butyl acetate Toxic effects described in animals include: By skin or eye contact: Skin Irritation; eye irritation By inhalation: Eye irritation, narcosis; upper respiratory irritation By ingestion: Narcosis Toxic effects of repeated or prolonged animal exposures include: By inhalation: Eye irritation; lower weight gain By ingestion: Liver effects Toxic effects of chronic animal tests include: By inhalation: Liver effects Additional animal tests have shows: Developmental toxicity at dosage levels showing maternal toxicity ; no genetic damage in animals, bacterial, or mammalian cell cultures. Human health effects of overexposure may include: By skin or eye contact: Skin irritation with discomfort, tearing, or blurring of vision By inhalation: Irritation of the upper respiratory passages with coughing and discomfort; nonspecific discomfort, e. g. nausea, headache or weakness. Human effects of higher level acute repeated or chronic overexposure may include: Temporary nervous system depression with anaesthetic effect, e. g. dizziness, headache, confusion, loss of coordination, loss of consciousness. Abnormal liver function as detected by laboratory tests. In addition: By skin or eye contact: Significant skin permeation appears unlikely; there are inconclusive or unverified reports of human sensitization. Silver metallic: Human effects of higher level acute, repeated or chronic overexposure my include argyria. Acrylic resin: Toxic effects described in animals include: Slight skin irritation Human health effects of overexposure my include: Allergic skin rashes Eye irritation with discomfort, tearing, or blurring of vision Nonspecific discomfort, e. g. nausea, headache, weakness.
Exotoxicity: No information found in our selected sources Environmental Fate: No information found in our selected references. Bioaccumulation: Not expected to occur.
Use only licensed transporters and permitted disposal facilities and conform to all laws. Recycle to process, if possible. Silver is a non-renewable resource. Care must be taken to prevent environmental contamination from the use of this material. The user of this material has the responsibility to dispose of unused materials, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. RCRA P-Series: None listed RCRA U-Series: None listed
Shipping information: Shipping name: Paint Related Material Hazard Class: 3 UN/NA Class: UN1263 Label: Flammable liquid Packing Group III
United States:
This MSDS has been prepared to be in compliance with OSHA regulations and with the Pennsylvania
Right-to-know regulations. Section 2 lists the chemical name and CAS# for each:
Specially hazardous ingredient >0.01% (OSHA is .0.1%)
Hazardous ingredient >1.0 % (OSHA is the same)
Non-hazardous ingredient >3.0% (OSHA does not regulate)
RTECS:
CAS# 1440-22-4: VW3500000
CAS# 108-65-6: AI8925000
CAS# 123-86-4: AF7350000
TSCA
All ingregients in this product appear on the TSCA Inventory.
Health & Safety Reporting List
Chemical Test Rules:
CAS# 123-86-4: CFR 799.5000
Section 12b: None listed
TSCA Significant New Use Rule:
CERCLA Section 103:
CAS# 123-86-4 >5000 lbs RQ
SARA:
Hazard Classification: Fire Hazard
SARA Codes:
CAS# 123-86-4: acute, flammable
Section 313:
CAS# 7440-22-4: Wt% 35-65%
Clean Air Act:
None listed
Clean Water Act:
None listed
OSHA:
State (Individual states in the USA)
CAS# 123-86-4 is found on the following state Right-to-Know lists: California, Massachusetts, Minnesota, New Jersey, Pennsylvania
California No Significant Risk Level:
California Prop. 65:
None listed
European/International Regulations:
European Labeling in Accordance with EC Directives
Hazard Symbols: Xi
Risk Phrases:
R10 Flammable
R33 Danger of cumulative effects
R36 Irritating to eyes
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapours may cause drowsiness and dizziness
Safety Phrases:
S28A After contact with skin, wash immediately with plenty of water
S25 Avoid contact with eyes
S37 Wear suitable gloves
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible
WGK (Water Danger/Protection):
CAS# 7440-22-4: 0
CAS# 108-65-6: 1
CAS# 123-86-4: 1
Canada
DSL/NDSL:
CAS# 7440-22-4 is listed on the DSL List.
CAS# 108-65-6 is listed on the DSL List
CAS# 123-86-4 is listed on the DSL List
This product has a WHMIS classification of B2, D2B
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