SPI Supplies SPI-Chem™ SPI Supplies Division
Structure Probe, Inc.

P.O. Box 656 West Chester, PA 19381-0656 USA
Phone: 1-(610)-436-5400 Fax: 1-(610)-436-5755
E-mail: spi3spi@2spi.com

WWW: http://www.2spi.com
Manufacturer's CAGE: 1P573

Material Safety Data Sheet

SPI# 17023-AB/#17023-AA Microshield™ Remover


Section 01 Identification

Date Effective......... January 8, 2009 
                        (most recent revision)

Chemical Name/Synonyms. Microshield Remover

Chemical Family........ Organic solvents, primarily ketones


Emergencies             Contacting CHEMTREC 24 Hour Emergency 
Use Only #'s........... Worldwide phone : 1-(703)-527-3887
                        Worldwide FAX   : 1-(703)-741-6090
                        Toll-free phone : 1-(800)-424-9300 USA only

Product or Trade Name... Microshield Remover 
                           
                           
CAS #................... None assigned to formulated composition 
                         (see below)

Chemical Formula........ Chemical mixture of ketones and toluene

Hazardous Material
Information System
USA
Health 3 National Fire
Protection Association
USA
Fire Hazard 3
Reactivity 0
Personal Protection
Flammability classification: HMIS rating: Health Hazard: 3 Fire Hazard: 3 Reactivity: 0


Section 2 Composition


See below, Section 3.



Section 3: Hazard Identification

Chemical Names           CAS #     % Wt    TLV-TWA    PEL      Sec.313

Methyl ethyl ketone     78-93-3   15-15    200 ppm    200 ppm   Yes

Toluene                108-88-3   15-25    100 ppm     50 ppm   ---
Tetrahydrofuran        109-99-9   25-35    750 ppm    750 ppm   ---
Propylene oxide         75-56-9   25-35    200 ppm    200 ppm   Yes

This product contains components that are subject to reporting under SARA 
Title III, Section 313.

Emergency overview:
       Material is highly volatile and flammable.  Vapors are heavier 
       than air and may travel along low areas to source of ignition.


Physical Health Hazards:
       Can cause eye irritation on contact, inhalation can cause 
       dizziness and ingestion can cause serious gastrointestinal 
       difficulties including nausea and vomiting. Skin contact can 
       cause defatting of the skin and solvents can penetrate the 
       skin in to the body.


Physical state:  
       Liquid 

Color:
       Clear

Odor: 
       Ketone type

Odor threshold:   
       No data available



Potential Health Effects:

Routes of exposure

        Eye contact, ingestion, skin contact, inhalation




Section 4: First Aid Measures


Take proper precautions to ensure your own health and safety before 
attempting to rescue and providing first aid.  For specific information 
refer to the Emergency Overview in Section of this MSDS.

Inhalation:   Remove to fresh air. Never give liquids to an 
                     unconscious person. Call medical assistance at once.

Eye Contact:  Wash eyes with clean low-pressure water. Seek 
                     medical advice.

Skin Contact: Wash with soap and water.


Ingestion:         Do not induce vomiting, seek medical attention
                      at once.




Section 5: Fire Fighting Measures

      

Flash Point/Method: 
        -17C (1F)  TCC

Auto-Ignition Temperature:

        Not determined

Flammable Limits (%V):  
         Lower:   LEL:  2%
         Upper:   UEL: 10%


Hazardous Combustion Products:
         Thermal decomposition may liberate carbon monoxide and 
         carbon dioxide.

Special Conditions to Avoid:
         Materials to avoid:   Strong oxidizing agents
         Conditions to avoid:  Heat or ignition sources

Extinguishing Media:
         Small fires:  Use dry chemicals, CO2, alcohol type foam. 




Fire Fighting Instructions:

Special exposure hazards:     None known

Special protective equipment: Self contained breathing apparatus 
                                     and personal protective equipment.





Section 6: Accidental Release Measures

      

Release response:

     Personal precautions:      
            Spilled product constitutes a slip hazard.

     Environmental precautions: 
            Try to keep liquid from getting into sewers or drainage of 
            building.

     Decontamination procedures: 
            Use absorbent materials, to soak up spilled liquid, which 
            is then placed in containers for later disposal as a 
            hazardous waste.  
          

  See paragraph 13 regarding disposal.





Section 7: Handling and Storage



Handling: 
     Wear NIOSH approved respirator is point-of-use generates vapors 
     above recommended limits.

Ventilation:   
     Local exhaust is required.

Protective clothing:  
     Long sleeve shirt, trousers, safety shoes, solvent 
     resistant gloves.

Eye protection:  
     Chemical splash goggles


Other precautions:  
     Wash hands with soap and water before handling food. 
     Material is flammable, store in a cool dry area away 
     from heat sources.

Storage:
     Keep cap tightly screwed on to protect integrity of 
     the product and to keep vapors from escaping into the 
     environment. Empty containers may contain residual vapors.  




Section 8: Exposure Controls and Personal Protection


Engineering Controls:  
    Local exhaust ventilation


Personal Protection:
    Inhalation:
           Wash hands after use, using soap and water to
           remove all residues of the product. 

    Skin:
           Solvent resistant gloves

    Eye:
           Always use safety chemical goggles when handling 
           this material.



Section 9: Physical and Chemical Properties


Physical State:       Liquid
Odor:                 Ketone
Flash Point:          > -17C (1F)
Boiling Point/Range 
      760 mm Hg:         63C (145F)

Explosive Limits:     Not determined
Water Solubility:     Not soluble
Color:                Clear
Melting Point:        Not known
Autoignition Point:   Not determined

pH:                   Not applicable

Vapor Pressure:       Not determined
Viscosity:            Not applicable

Vapor density 
      (air = 1):         2.5


Octanol/Water Partition Coefficient in Kow: 
      Specific value not known

Evaporation Rate:     Very low

Specific Gravity:     0.82


Evaporation Rate 
      (BuAc = 1):        6




Section 10: Stability and Reactivity


Chemical Stability:
      The product is stable and will not polymerize.

Conditions to Avoid:
      Elevated temperatures and ignition sources


Incompatibility with:
      Strong oxidizing agents.

Hazardous Products of Deposition:
      Thermal decomposition may liberate carbon monoxide 
      and carbon dioxide.

Reactions with Air and Water:
      Does not react with air, water or other common materials.



Section 11: Toxicological Information


Based on the product's components:

Acute Health Effects:
      Eyes: 
          May cause transient irritation from vapors, irritation 
          and blurred vision from prolonged exposure to vapors or 
          direct contact..

      Inhalation:  
          Dizziness, nausea, headache, fatigue

      Ingestion:   
          Gastrointestinal discomfort including irritation of
          gastrointestinal tract, nausea, and vomiting.

      Chronic Health Effects: 
          Dizziness, fatigue, nausea, possible vomiting, possible skin 
          irritation. Prolonged exposure may aggravate preexisting lung 
          and skin disorders.

      Chronic Effects/Carcinogenicity:  
          Not known about formulated composition, however exposure to 
          toluene is thought to be carcinogenic.

      Reproductive/Development Effects:

          Not known




Section 12: Ecological Information


Environmental:  
        When used and/or disposed of as indicated, no adverse 
        environmental effects are foreseen.

Mobility:
        Non-volatile/Insoluble in water.

Degradability:

        Not known.




Section 13: Disposal Considerations


Product and packaging must be disposed of in accordance with local and 
national regulations.  Maybe incinerated. 

This material IS classified as a hazardous waste.  It must be disposed 
of in accordance with all federal, state, and local regulations. Use 
only licensed transporters and permitted disposal facilities and 
conform to all laws.



Section 14: Transport Information


Material is classified as hazardous for transport by air, sea, or road.

Proper Shipping Name:
        Flammable Liquid Class 3

DOT Hazard Class:
        Flammable Liquid Class 3, UN #1123 

Packing Group:      II
Labels:             Flammable
Marine Pollutant:   Not known

NAER Guidebook:     Not known
DOT Status:         Flammable



Section 15: Regulatory Information

TSCA: 
    All components of this product are listed on the TSCA 8(b) 
    inventory. If identified components of this product are listed 
    under the TSCA 12(b) Export Notification Rule, they will be 
    listed below.

    TSCA 12(b) Component      Listed under TSCA Section


SARA-Section 313 Emissions Reporting:

    Component                         Reporting Threshold
       Methyl ethyl ketone
       Toluene
       Propylene Oxide
       Orange pigment solvent Yellow 14

SARA-Section 311/312: Not determined yet


CERCLA Hazardous Substances and their Reportable Quantities:

    Component                  Reportable Quantity




Section 16: Other Information


Disclaimer of Liability:

Caution!  Do not use SPI Supplies products or materials in applications 
involving implantation within the body; direct or indirect contact 
with the blood pathway; contact with bone, tissue, tissue fluid, or 
blood; or prolonged contact with mucous membranes.  Products offered 
by SPI Supplies are not designed or manufactured for use in implantation 
in the human body or in contact with internal body fluids or tissues.  
SPI Supplies will not provide to customers making devices for such 
applications any notice, certification, or information necessary for 
such medical device use required by US FDA (Food and Drug Administration) 
regulation or any other statute. SPI Supplies and Structure Probe, Inc. 
make no representation, promise, express warranty or implied warranty 
concerning the suitability of these materials for use in implantation 
in the human body or in contact with internal body tissues of fluids.

**********************************************************************
The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation.

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