Information System
USA
Protection Association
USA
SPI Supplies Division
Date Effective........... May 23, 2007
(most recent revision)
Chemical Name/Synonyms... Black Nail Enamel
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s...
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name:SPI Supplies® Brand Glass Knife Boat Sealer Black
Synonyms................. Black Nail Enamel
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Hazardous Material Information System USA |
Health | 2 |
National Fire Protection Association USA |
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| Fire Hazard | 3 | |||
| Reactivity | 0 | |||
| Personal Protection |
Component Name CAS # EC# Ethyl Acetate 141-78-6 205-500-4 Butyl Acetate 13-86-4 204-658-1 Isopropyl Alcohol 63-67-0 200-661-7 Nitrocellulose 9004-70-0 none Polyester Resin Not available none Trimethyl pentanediol di-isobutyrate 6846-50-0 229-934-9 Triphenyl phospate 115-86-6 204-112-7 Styrene acrylic polymers not available none
Emergency overview: Appearance: Black enamel paint Flash Point: 24°F (Tag Closed Cup) Warning! Flammable liquid Target Organs: Eyes, Skin, Nervous system Potential Health Effects Eye: May cause irritation or burning eyes. Skin: Prolonged or repeated skin contact may cause irritation or contact dermatitis. Ingestion: In case of ingestion, seek medical attention. Inhalation: May cause nose and throat irritation. Chronic: Repeated and prolonged overexposure to solvent has been associated with permanent brain damage.
Eyes: In case of eye contact, immediately flush with copious amounts of water for at least 15 minutes. Seek medical attention. Skin: In case of skin contact, wash with plenty of soap and water. If irritation occurs, seek medical attention. Ingestion: Seek medical attention. Inhalation: Remove to fresh air. If symptoms persist, seek medical attention.
Flash Point: 24° F (Tag Closed Cup) General Information: Flammable vapors may be emitted if heated above the flash point. Fine mists or sprays may be flammable at temperatures lower than the flash point. Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam Protection: Toxic decomposition products may form under fire conditions. Wear full protective clothing and a full facepiece, positive pressure, self contained breathing apparatus (SCBA). Water fog may be used to cool containers to prevent pressure build-up: Unusual Fire and Explosion Hazards: Keep away from sparks and open flames. Do not smoke in area with open product. The solvent vapors are heavier than air and may travel along the floor to a source of ignition and flashback. Use the product in areas and equipment with appropriate National Electrical Code (NEC) classification. Consider the need for spark proof tools. If the product could be heated above its flash point during processing or use, remove all sources of ignition, such as sparks, flames, or static discharge to prevent vapor ignition.
General Information: Ventilate area. Remove sources of ignition. Prevent skin contact. Do not breathe vapors. Spills/Leaks: Confine and remove with inert absorbent. Dispose of in accordance with all applicable Federal, State and Local Regulations.
Handling: Use in accordance with good industrial practice. Avoid skin and eye contact. Avoid breathing vapors. Wash thoroughly after handling. Storage: Store in tightly closed original container in dry, cool area. Do not store over 120°F.
Engineering Controls: Use local exhaust. Eye bath and safety shower should be available to the work place. Exposure Limits: Chemical Name ACGIH-TWA,ppm OSHA – PELs,ppm Ethyl acetate 400.00 400.00 Butyl acetate 150.00 150.00 Isopropyl alcohol 400.00 400.00 Nitrocellulose 400.00 not available Polyester resin not available not available Trimethyl pentanediol di-isobutyrate not available not available Triphenyl phosphate not available not available Styrene acrylic polymers not available not available Personal Protective Equipment Eyes: Safety glasses with splash guards and side shields Skin: Neoprene gloves Clothing: Coveralls Respirators: Use with adequate ventilation and avoid breathing vapors.
Physical State: liquid Appearance: shiny black Odor: strong solvent pH: not available Vapor Pressure: Not available Vapor Density: Not available Evaporation Rate: Slower than ether Viscosity: Not available Boiling Range: 171 - 640°F Freezing/Melting Point: Not available Autoignition Temperature: Not available Flash Point: 24°F Decomposition Temperature: Not available Explosion Limits: Lower: Not available Upper: Not available Solubility in water: Not available Specific Gravity/Density: Not available Molecular Formula: Not available Molecular Weight: Not available
Chemical Stability: Stable Conditions to Avoid: Do not store over 120°F Incompatibility with Other Materials: Acids, Alkalis and Peroxides Hazardous Decomposition of Products: Carbon monoxide, Carbon dioxide, Nitrous Oxides, Smoke Hazardous Polymerization: Will not occur.
CAS#: RTECS#: 141-78-6 AH5425000 123-86-4 AF7350000 67-63-0 NT8050000 6846-50-0 SA1420000 115-86-6 TC8400000 LD50/LC50 Information: CAS# 141-78-6 LD50 Rat, oral 5620 mg/kg LC50 Rat, inhalation 200,000 mg/m3 LD50 Rabbit, oral 4935 mg/kg DL50 Rabbit, skin >20 ml/kg CAS# 123-86-4 LD50 Rat, oral 10768 mg/kg LC50 Rat, inhalation 390 ppm LD50 Rabbit, oral 3200 mg/kg LD50 Rabbit, skin >17600 mg/kg CAS# 67-63-0 LD50 Rat, oral 5045 mg/kg LC50 Rat, inhalation 16,000 ppm LD50 Rabbit, oral 6410 mg/kg LD50 Rabbit, skin 12800 mg/kg CAS# 6846-50-0 Guinea pig, skin 5,000 mg/kg mild irritation effect CAS# 115-86-6 LD50 Rat, oral 3500 mg/kg LC50 Mammal, inhalation 4,200 mg/m3 LD50 Mouse, oral 1320 mg/kg LD50 Rabbit, skin >7,900 mg/kg
No data available.
Use only licensed transporters and permitted disposal facilities and conform to all laws. Care must be taken to prevent environmental contamination from the use of this material. The user of this material has the responsibility to dispose of unused materials, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes.
US DOT Hazard Class:
Flammable Liquid Class 1B
UN No. 1263
Packing Group II
Hazard Class 3
IATA (for international shipments):
Flammable Liquid
UN No. 1263
Packaging Group II
Hazard Class 3
United States: TSCA All components of this product are listed on the TSCA Inventory List or are not required to be listed. CERCLA Section 103: CAS# 141-78-6 has an RQ of 5,000 lbs. CAS# 123-86-4 has a RQ of 5,000 lbs. SARA Section 313 CAS# 67-63-0 is listed under SARA Section 313. California Prop. 65: None of the components of this product are listed under California Prop. 65. European/International Regulations: European Labeling in Accordance with EC Directives Hazard Symbols: Xi irritant; F highly flammable Risk Phrases: R11 Highly flammable. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapors may cause drowsiness and dizziness. Safety Phrases: S2 Keep out of reach of children. S7 Keep container tightly closed. S16 Keep away from sources of ignition – No smoking. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33 Take precautionary measures against static discharges. WGK (Water Danger/Protection): CAS# 67-63-0 : 1 Canada: This product has a WHMIS classification of B2. DSL/NDSL: CAS# 141-78-6 is on the DSL List and is not on the NDSL List. CAS# 123-86-4 is on the DSL List and is not on the NDSL List. CAS# 67-63-0 is on the DSL List and is not on the NDSL List. CAS# 9004-70-0 is on the DSL List and is not on the NDSL List. CAS# 6846-50-0 is on the DSL List and is not on the NDSL List. CAS# 115-86-6 is on the DSL List and is not on the NDSL List.
If this product should be used in ways that are outside of the intended applications in scanning electron microscope laboratories, and if it is going to be formulated into some other system, so that it becomes just another component of that other system, read the MSDS sheets for the other components before blending as the resulting mixture may have the hazards of all of its parts.
Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute.
SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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