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Date Effective... January 8, 2009
(most recent revision)
Chemical Name/Synonyms:
1,1,1,2-tetrafluoroethane
Chemical family:
1,1,1,2-tetrafluoroethane
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s......
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #07605-AB Two-in-One OK Easy Dusters™
CAS #.................... 811-97-2
Chemical Formula......... 1,1,1,2-tetrafluoroethane
CHEMICAL C.A.S. Number Weight %
1,1,1,2-tetrafluoroethane 811-97-2 100
OSHA Hazardous Components (29 CFR 1910.1200):
Exposure Limits 8 Hours TWA
(PPM)
OSHA PEL ACGIH TLV
Supplier
1,1,1,2-tetrafluoroethane NIF 1000
Emergency Overview:
Potential Health Effects:
Inhalation:
Major potential rout of exposure. Minimal effects observed
below 1000 ppm. Dizziness, drowsiness, and throat irritation
possible at levels above 1,000 ppm. Unconsciousness and death
at levels above 10,000 ppm. Blood pressure depression, cardiac
sensitization, and ventricular arrhythmia can result from
exposure to near-anesthetic levels.
Eyes:
Liquid can cause slight, temporary irritation with slight temporary
corneal injury. Vapors can irritate eyes.
Skin:
Prolonged or repeated contact with liquid can cause freezing of skin
tissues, defatting, and dermatitis.
Ingestion:
Single dose toxicity is low to moderate. If vomiting occurs
the liquid can be aspirated into the lungs, which can cause
chemical pneumonia and systemic effects. Human psychotropic,
gastrointestinal, and central nervous system effects possible.
Inhalation: Move to fresh air in case of accidental inhalation
of vapors. If victim has stopped breathing, give
artificial respiration. Call for prompt medical
attention.
Eye Contact: Flush eyes with large amounts of water for 15
minutes or until irritation subsides. If irritations
persist, get medical attention.
Skin Contact: Remove contaminated clothing (including shoes)
and wash before reuse. Flush with large amounts
of water. Use soap if available. If irritation
persists, seek medical attention.
Ingestion: Do not induce vomiting unless directed by a
physician. If conscious and alert, give two
glasses of water. Seek medical attention
immediately.
Flash Point & Method: None TCC Method
Flammable Limits: LEL: NA UEL: NA
Autoignition Temperature:
General Hazard:
Aerosol cans may erupt with force at temperatures above 49°C (120° F).
Fire Fighting Instructions:
Fire fighters should wear self contained, positive-pressure breathing
apparatus and avoid skin contact.
Fire Fighting Equipment:
Water, foam, dry chemical, carbon dioxide.
Hazardous Combustion Products:
Smoke, fumes and oxides of carbon.
Land Spill: Evacuate area. Ventilate area well and avoid breathing vapors. Vapor concentration will be highest along floor and in low lying areas. Pick up liquid on suitable absorbent and store in sealed containers. Water Spill: The high vapor pressure of this material will result in its evaporation before it could make its way into any sewer or waterway.
Storage Temperature: Ambient
Storage Pressure: Atmospheric
General: Keep container closed when not in use. Store in
cool, well ventilated place out of direct sunlight
and away from incompatible materials.
(See STABILITY AND REACTIVITY Section 10.) Follow all MSD Sheet
and Label warnings even after container is emptied.
Engineering Controls:
Local Exhaust ventilation acceptable.
See section 2 for component exposure guidelines.
Personal Protection:
Respirator:
If concentrations are over the exposure limit and are
known, air purifying respirator with Organic Vapor
Cartridges may be acceptable. Refer to cartridges
for acceptable levels. If concentrations are over
exposure limit and are unknown, use a supplied air
respirator.
Hand Protection:
(X) Gloves recommended
(X) Solvex (X) Neoprene
(X) Butyl (X) Buna
(X) Natural Latex (X) Cotton/Jersey
Eye Protection:
(X) Safety Glasses ( ) Chemical Goggles ( ) Full Face Shield
Other Recommendations:
( ) Rubber Boots ( ) Splash-proof chemical resistant suit/apron
Density................. 1.202 pH...................... 7-8 Boiling Point........... -16C / -27F % Volatile.............. 100 Freezing Point.......... NIF % Solids................ 0 Vapor Density (Air=1):.. 3.0 Evaporation Rate (H2O=1) >1 Solubility in Water..... 0 Viscosity............... N/A Molecular Weight........ N/A Physical State.......... LIQUID Non-Exempt VOC (g/l).... 0 Odor.................... NIF Appearance: Clear water-white liquid with low odor.
General:
Stable, will not under go hazardous polymerization.
Incompatible materials and conditions to avoid:
Contact with open flame, heat.
Reactive alkali metals, strong acids & bases.
Hazardous decomposition products:
Hydrogen fluoride, carbon dioxide, and carbon monoxide
Results of component toxicity test performed:
Information not available.
Human experience:
Information not available.
This product does not contain any compounds listed by NTP or IARC or
regulated by OSHA as a carcinogen.
Exotoxicity: Exotoxicity is expected to be very low based on the fact that the material will evaporate long before it has had a chance to enter the water streams or other aspects of the environment. Environmental Fate: No information found in our selected references. Bioaccumulation: Not expected to occur.
RCRA 40 CFR 261 Classification: Federal, State, and Local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.
U.S. DOT Information:
Proper Shipping Name: CONSUMER COMMODITY ORM-D
Hazard Class: N/A
Packaging Group: N/A
UN Number: N/A
Limitations:
Must place CONSUMER COMMODITY ORM-D on box.
Must have a copy of the DOT-E-10232 with each
shipment.
IATA
Proper Shipping Name: CONSUMER COMMODITY ID8000
Hazard Class: 9
Packing Group: N/A
UN Number: ID8000
Limitations:
A copy of the DOT-E-10232 must be attached to the
shipment. Domestic shipments only. When shipping
International contact Stratus shipping department.
Must have a copy of the DOT-E-10232 with each
shipment.
IMO
Proper Shipping Name: AEROSOLS IN LIMITED QUANTITIES OF CLASS 2
Class: 2.2
UN Number: UN1950
Packaging Group: N/A
EMS: 2-13
MFAG: 350
Marine Pollutant: N/A
Canadian TDG: N/A
IMDG Page: 2102
Limitations:
UNITED STATES FEDERAL REGULATIONS:
MSDS complies with OSHAs Hazard Communication Rule, 29 CFR 1910.1200.
CERCLA/SUPERFUND, 40 CFR 117, 302:
--- None of the chemicals are Superfund hazards ---
SARA SUPERFUND AND REAUTHORIZATION ACT OF 1986
TITLE III Sections 302, 311, 312 and 313:
Section 302 - Extremely hazardous substances (40 CFR 355):
--- None of the chemicals are Section 302 hazards ---
Section 311/312 - Material Safety Data Sheet Requirements (40 CFR 370)
( ) By our hazard evaluation, this product is non-hazardous.
(X) By our hazard evaluation, this product is hazardous. It
should be reported under the following EPA hazard.
(X) Immediate (acute) health hazard
( ) Delayed (chronic) chronic health hazard
( ) Sudden release of pressure hazard
( ) Reactive hazard
( ) Flammable
Section 313 - List of Toxic Chemicals (40 CFC 372)
This product contains the following chemicals (at levels of 1% or greater)
which are found on the 313 list of Toxic Chemicals.
CHEMICAL C.A.S. NUMBER WEIGHT %
--- None of the chemicals are 313 Toxic Chemicals ---
TOXIC SUBSTANCE CONTROL ACT (TSCA):
All substances are TSCA Listed.
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA 40 CFR 261) Subpart C & D:
Refer to Section 11. for RCRA classification.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15
(FORMERLY SECTION 307), 40 CFR 116 (FORMERLY SECTION 311)
This product contains the following chemicals which are listed:
CHEMICAL C.A.S. NUMBER WEIGHT %
CLEAN AIR ACT: --- No Information ---
INTERNATIONAL REGULATIONS:
CANADA WHMIS: NIF
EUROPE EINECS NUMBERS: Tetrafluoroethane; 811-97-2
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer products
into the State of California to provide a warning statement if the product
contains ingredients for which the State has found to cause cancer, birth
defects or other reproductive harm. If this product contains an ingredient
listed by the State of California to cause cancer or reproductive toxicity,
it will be listed below:
This product does not contain any such ingredients known to cause cancer.
Label Information:
European risk and Safety Phrases: S2, S23, S24/25, S51
European Symbols Needed: NONE
Canadian WHMIS Symbols: NIF
NFPA HAZARD RATING:
(0) Fire (1) Health (1) Reactivity
Disclaimer of Liability:
Caution! Do not use SPI Supplies products or materials in applications
involving implantation within the body; direct or indirect contact with
the blood pathway; contact with bone, tissue, tissue fluid, or blood; or
prolonged contact with mucous membranes. Products offered by SPI Supplies
are not designed or manufactured for use in implantation in the human body
or in contact with internal body fluids or tissues. SPI Supplies will not
provide to customers making devices for such applications any notice,
certification, or information necessary for such medical device use required
by US FDA (Food and Drug Administration) regulation or any other statute.
SPI Supplies and Structure Probe, Inc. make no representation, promise,
express warranty or implied warranty concerning the suitability of these
materials for use in implantation in the human body or in contact with
internal body tissues of fluids.
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