Date Effective... January 8, 2009 (most recent revision) Chemical Name/Synonyms: 1,1,1,2-tetrafluoroethane Chemical family: 1,1,1,2-tetrafluoroethane Emergencies Contacting CHEMTREC: 24 Hour Emergency Use Only #'s...... Worldwide phone: 1-(703)-527-3887 Worldwide FAX: 1-(703)-741-6090 Toll-free phone: 1-(800)-424-9300 USA only Product or Trade Name.... SPI #07605-AB Two-in-One OK Easy Dusters CAS #.................... 811-97-2 Chemical Formula......... 1,1,1,2-tetrafluoroethane
CHEMICAL C.A.S. Number Weight % 1,1,1,2-tetrafluoroethane 811-97-2 100 OSHA Hazardous Components (29 CFR 1910.1200): Exposure Limits 8 Hours TWA (PPM) OSHA PEL ACGIH TLV Supplier 1,1,1,2-tetrafluoroethane NIF 1000
Emergency Overview: Potential Health Effects: Inhalation: Major potential rout of exposure. Minimal effects observed below 1000 ppm. Dizziness, drowsiness, and throat irritation possible at levels above 1,000 ppm. Unconsciousness and death at levels above 10,000 ppm. Blood pressure depression, cardiac sensitization, and ventricular arrhythmia can result from exposure to near-anesthetic levels. Eyes: Liquid can cause slight, temporary irritation with slight temporary corneal injury. Vapors can irritate eyes. Skin: Prolonged or repeated contact with liquid can cause freezing of skin tissues, defatting, and dermatitis. Ingestion: Single dose toxicity is low to moderate. If vomiting occurs the liquid can be aspirated into the lungs, which can cause chemical pneumonia and systemic effects. Human psychotropic, gastrointestinal, and central nervous system effects possible.
Inhalation: Move to fresh air in case of accidental inhalation of vapors. If victim has stopped breathing, give artificial respiration. Call for prompt medical attention. Eye Contact: Flush eyes with large amounts of water for 15 minutes or until irritation subsides. If irritations persist, get medical attention. Skin Contact: Remove contaminated clothing (including shoes) and wash before reuse. Flush with large amounts of water. Use soap if available. If irritation persists, seek medical attention. Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert, give two glasses of water. Seek medical attention immediately.
Flash Point & Method: None TCC Method Flammable Limits: LEL: NA UEL: NA Autoignition Temperature: General Hazard: Aerosol cans may erupt with force at temperatures above 49°C (120° F). Fire Fighting Instructions: Fire fighters should wear self contained, positive-pressure breathing apparatus and avoid skin contact. Fire Fighting Equipment: Water, foam, dry chemical, carbon dioxide. Hazardous Combustion Products: Smoke, fumes and oxides of carbon.
Land Spill: Evacuate area. Ventilate area well and avoid breathing vapors. Vapor concentration will be highest along floor and in low lying areas. Pick up liquid on suitable absorbent and store in sealed containers. Water Spill: The high vapor pressure of this material will result in its evaporation before it could make its way into any sewer or waterway.
Storage Temperature: Ambient Storage Pressure: Atmospheric General: Keep container closed when not in use. Store in cool, well ventilated place out of direct sunlight and away from incompatible materials. (See STABILITY AND REACTIVITY Section 10.) Follow all MSD Sheet and Label warnings even after container is emptied.
Engineering Controls: Local Exhaust ventilation acceptable. See section 2 for component exposure guidelines. Personal Protection: Respirator: If concentrations are over the exposure limit and are known, air purifying respirator with Organic Vapor Cartridges may be acceptable. Refer to cartridges for acceptable levels. If concentrations are over exposure limit and are unknown, use a supplied air respirator. Hand Protection: (X) Gloves recommended (X) Solvex (X) Neoprene (X) Butyl (X) Buna (X) Natural Latex (X) Cotton/Jersey Eye Protection: (X) Safety Glasses ( ) Chemical Goggles ( ) Full Face Shield Other Recommendations: ( ) Rubber Boots ( ) Splash-proof chemical resistant suit/apron
Density................. 1.202 pH...................... 7-8 Boiling Point........... -16C / -27F % Volatile.............. 100 Freezing Point.......... NIF % Solids................ 0 Vapor Density (Air=1):.. 3.0 Evaporation Rate (H2O=1) >1 Solubility in Water..... 0 Viscosity............... N/A Molecular Weight........ N/A Physical State.......... LIQUID Non-Exempt VOC (g/l).... 0 Odor.................... NIF Appearance: Clear water-white liquid with low odor.
General: Stable, will not under go hazardous polymerization. Incompatible materials and conditions to avoid: Contact with open flame, heat. Reactive alkali metals, strong acids & bases. Hazardous decomposition products: Hydrogen fluoride, carbon dioxide, and carbon monoxide
Results of component toxicity test performed: Information not available. Human experience: Information not available. This product does not contain any compounds listed by NTP or IARC or regulated by OSHA as a carcinogen.
Exotoxicity: Exotoxicity is expected to be very low based on the fact that the material will evaporate long before it has had a chance to enter the water streams or other aspects of the environment. Environmental Fate: No information found in our selected references. Bioaccumulation: Not expected to occur.
RCRA 40 CFR 261 Classification: Federal, State, and Local laws governing disposal of materials can differ. Ensure proper disposal compliance with proper authorities before disposal.
U.S. DOT Information: Proper Shipping Name: CONSUMER COMMODITY ORM-D Hazard Class: N/A Packaging Group: N/A UN Number: N/A Limitations: Must place CONSUMER COMMODITY ORM-D on box. Must have a copy of the DOT-E-10232 with each shipment. IATA Proper Shipping Name: CONSUMER COMMODITY ID8000 Hazard Class: 9 Packing Group: N/A UN Number: ID8000 Limitations: A copy of the DOT-E-10232 must be attached to the shipment. Domestic shipments only. When shipping International contact Stratus shipping department. Must have a copy of the DOT-E-10232 with each shipment. IMO Proper Shipping Name: AEROSOLS IN LIMITED QUANTITIES OF CLASS 2 Class: 2.2 UN Number: UN1950 Packaging Group: N/A EMS: 2-13 MFAG: 350 Marine Pollutant: N/A Canadian TDG: N/A IMDG Page: 2102 Limitations:
UNITED STATES FEDERAL REGULATIONS: MSDS complies with OSHAs Hazard Communication Rule, 29 CFR 1910.1200. CERCLA/SUPERFUND, 40 CFR 117, 302: --- None of the chemicals are Superfund hazards --- SARA SUPERFUND AND REAUTHORIZATION ACT OF 1986 TITLE III Sections 302, 311, 312 and 313: Section 302 - Extremely hazardous substances (40 CFR 355): --- None of the chemicals are Section 302 hazards --- Section 311/312 - Material Safety Data Sheet Requirements (40 CFR 370) ( ) By our hazard evaluation, this product is non-hazardous. (X) By our hazard evaluation, this product is hazardous. It should be reported under the following EPA hazard. (X) Immediate (acute) health hazard ( ) Delayed (chronic) chronic health hazard ( ) Sudden release of pressure hazard ( ) Reactive hazard ( ) Flammable Section 313 - List of Toxic Chemicals (40 CFC 372) This product contains the following chemicals (at levels of 1% or greater) which are found on the 313 list of Toxic Chemicals. CHEMICAL C.A.S. NUMBER WEIGHT % --- None of the chemicals are 313 Toxic Chemicals --- TOXIC SUBSTANCE CONTROL ACT (TSCA): All substances are TSCA Listed. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA 40 CFR 261) Subpart C & D: Refer to Section 11. for RCRA classification. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 (FORMERLY SECTION 307), 40 CFR 116 (FORMERLY SECTION 311) This product contains the following chemicals which are listed: CHEMICAL C.A.S. NUMBER WEIGHT % CLEAN AIR ACT: --- No Information --- INTERNATIONAL REGULATIONS: CANADA WHMIS: NIF EUROPE EINECS NUMBERS: Tetrafluoroethane; 811-97-2 California Prop. 65: Proposition 65 requires manufacturers or distributors of consumer products into the State of California to provide a warning statement if the product contains ingredients for which the State has found to cause cancer, birth defects or other reproductive harm. If this product contains an ingredient listed by the State of California to cause cancer or reproductive toxicity, it will be listed below: This product does not contain any such ingredients known to cause cancer.
Label Information: European risk and Safety Phrases: S2, S23, S24/25, S51 European Symbols Needed: NONE Canadian WHMIS Symbols: NIF NFPA HAZARD RATING: (0) Fire (1) Health (1) ReactivityDisclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
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