SPI Supplies Division|
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Date Effective... June 19, 2006
(most recent revision)
Chemical Name/Synonyms... Silver Paint
Emergencies
Use Only #'s:
Contacting CHEMTREC 24 Hour Emergency
Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name:
SPI Silver Wires for evaporation;
SPI Sputter Coater Silver Cathodes; SPI Silver Grids
Product or Trade Name.... SPI #05003-AB Dotite® D-550 Silver Paint
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Hazardous Material Information System USA |
Health | 2 |
National Fire Protection Association USA |
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| Fire Hazard | 3 | |||
| Reactivity | 0 | |||
| Personal Protection |
Component Name CAS # Percent EINECS/ELINCS Silver 7440-22-4 55-65 231-131-3 Toluene 108-88-3 5-10 203-625-9 2-Butanone 78-93-3 20-30 201-159-0
Emergency overview: This product contains hazardous material. This product causes eye, skin, and respiratory tract irritation. Exposure to this material's vapors may produce central nervous system effect. Target Organs: Eyes, Skin, Respiratory tract, Central nervous system. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation Ingestion: May cause irritation of the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache dizziness, unconsciousness and coma. Causes respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. May produce numbness in the extremities. Chronic: Prolonged or repeated skin contact may cause defatting or dermatitis. Chronic overexposure to vapors may cause lung damage.
Emergency and first aid procedures:
Get medical assistance for all cases of over-exposure.
Skin: Get medical aid. Immediately flush skin thoroughly
with water for at least 15 minutes. Remove contaminated clothing
and shoes. Wash clothing before reuse.
Eyes: Get medical aid immediately. Immediately flush
thoroughly with water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Do not allow victim to rub
or keep eyes closed.
Inhalation: Get medical aid immediately. Remove to fresh
air immediately. Artificial respiration if breathing has stopped.
If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased, apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and
a mask.
Ingestion: Do NOT induce vomiting. If conscious and alert,
give 2-4 cupfuls of water to drink. Never give anything by
mouth to an unconscious person. Get medical aid immediately.
Notes to Physician: Treat symptomatically and supportively.
Chronic: Concentrated, prolonged or deliberate inhalation of
this product may cause central nervous system damage.
Flash Point.................... -7°C Autoignition Temperature....... 505°C Explosion Limits: Lower 1.8 vol % Upper 11.5 vol % Firefighting Procedure: Wear self-contained breathing apparatus in pressure-demand full protective gear. Keep all flammable substances away from the heat and flame. Closed container may explode when exposed to extreme heat. Extinguishing Media: CO2, Foam, Dry Chemical, Dry Sand.
Spill Response:
Evacuate the area of all unnecessary personnel.
Action to take for spills:
For small spills:
Absorb on to rags, sand, or other absorbent material.
For large spills:
Get workers out of the affected area. If flammable liquids or
vapors may be present, turn off electrical devices or other
sources of sparks or flames. Wear protective equipment. Use
supplied-air respiratory protection if vapor concentrations are
not known. Contain spill at source by diking or absorbing with
sand. Do not allow spill to spread to or intentionally flush to
sewer or ground. Wash area thoroughly. Adequately ventilate
area. Spill residue, cleaning rags, and absorbent may be refined
to recover the precious metal content.
Disposal considerations:
Components of this product may be considered hazardous, waste
product may be refined to recover previous metal content.
Handling: Wash hand thoroughly after using. Wear chemical splash goggles and solvent resistant gloves. Avoid contact with eyes, skin and clothing. Avoid inhalation and ingestion. If the TLV of the product is exceeded, a mechanical exhaust system or self-contained breathing apparatus is advised. No special equipment is deemed necessary under normal usage. Storage: Store in tightly sealed container. Ground all metal containers during storage and handling to avoid buildup of electrostatic charges. Store at room temperature. Avoid direct sunshine, heat.
Engineering Controls:
Use explosion proof local exhaust ventilation. An eyewash fountain and
a safety shower should be readily available in areas of use or handling.
Exposure Limits:
Chemical Name ACGIH NIOSH OSHA - Final PELs
Silver (metallic) 0.1mg/m3TWA 0.01mg/m3 0.01 mg/m3 TWA
Methyl Ethyl Ketone 200 ppm TWA 200 ppm TWA 200ppm TWA
300 ppm STEL 590 mg/m3 TWA 590 mg/m3 TWA
3000 ppm IDHL
Toluene 50 ppm TWA 100 ppm TWA 200 ppm TWA
375 mg/m3 TWA 300 ppm Ceiling
500 ppm IDHL
OSHA Vacated PELs:
Silver (metallic): 0.01 mg/m3 TWA
Methyl Ethyl Ketone: 200 ppm TWA; 590 mg/m3 TWA; 300 ppm STEL;
885 mg/m3 = STEL
Toluene: 100 ppm TWA; 375 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear chemical splash goggles
Skin: Wear solvent resistant gloves to prevent skin contact.
Clothing: Wear appropriate protective clothing to prevent skin
exposure.
Respirators: If the TLV of the product is exceeded, a mechanical
exhaust system or appropriate NIOSH approved self-contained
breathing apparatus is advised. Follow OSHA regulations in 29
CFR 1910.134 or European Standard EN 149.
Physical State: Liquid Appearance: Silver Color Odor: Sweetish odor pH: Not applicable Vapor Pressure: 9492 Pa/30°C (for CAS# 78-93-3) Vapor Density: Not available Evaporation Rate: Not available Viscosity: Not available Boiling Point: 79.6°C (for CAS# 78-93-3) Freezing/Melting Point: Not available Autoignition Temperature: 505°C (for CAS# 78-93-3) Flash Point: -7°C Decomposition Temperature: Not available Explosion Limits, Lower: 1.8 vol.% Upper: 11.5 vol.% Solubility in water: Not available Specific Gravity/Density: 2.4-2.6 Molecular Formula: Not available Molecular Weight: Not applicable
Chemical Stability: Stable Conditions to Avoid: Heat; direct sunlight. Incompatibility with Other Materials: Strong oxidizing agents. Hazardous Decomposition of Products: CO and low molecular weight monomer. Hazardous Polymerization: Will not occur.
RTECS#:
CAS# 7440-22-4: VW3500000
CAS# 108-88-3: XS5250000
CAS# 78-93-3: EL6475000
Toxicity data:
CAS# 7440-22-4: not available
CAS# 108-88-3
Draize test, Rabbit, skin: 435 mg - mild
Inhalation, Mouse LC50 400 ppm/24H
Inhalation, Rat LC50 49 gm/m3/4H
Oral, Rat 636 mg/kg
CAS# 78-93-3
Draize test, Rabbit, skin: 500mg/24H Moderate
Inhalation, Mouse LC50 32 gm/m3/4H
Inhalation, rat LC50 23500 mg/m3/8H
Oral, Mouse LD50 3000 mg/kg
Oral, rat LD50 2737 mg/kg
Carginogenicity:
CAS# 7440-22-4: Not listed by ACGIH, IARC, NIOSH, NTP or OSHA
CAS# 78-93-3: Not listed by ACGIH, IARC, NIOSH, NTP or OSHA
CAS# 108-88-3: Not listed by ACGIH, IARC, NIOSH, NTP or OSHA
Edidemiology: No information available
Teratogenicity: CAS# 78-93-3 Embryo or Fetus:death ihl-rat
TCLo=1000ppm Developmental Abnormalities: ihl-rat TCLo=3000ppm/6H
Musculoskeletal abnormalities ihl-rat TCLo+ 1000ppm
CAS# 108-88-3: Occupational exposures to toluene have been reported to be
associated with an increased incidence of renal, urinary,
gastrointestinal, and cardiac anomalies.
Reproductive effects:
CAS# 7440-22-4: No information available
CAS# 778-93-3: No information available
CAS# 108-88-3: Women exposed to toluene in the work place exhibit a 4.7
fold increase in the occurrence of spontaneous abortion.
Neurotoxicity:
No information available
Mutagenicity:
CAS# 78-93-3: Sex chromosome loss: S.cerevisiae 33800 = ppm. See entry in
RTECS for complete information.
Ecotoxicity:
CAS# 7440-22-4: No data available
CAS# 78-93-3
Fish: Fathead Minnow LC50 3220 mg/L; 96H; Unspecified ria: Phytobacterium
phosphoreum: EC50=51.9 mg/L; 25min; Microtox test ria:
Phytobacterium phosphoreum: EC50=3373 mg/L; 30 min; Microtox
test Fathead minnow LC50=3220 mg/L/96H.
CAS# 108-88-3
Bluegil: LC50=17 mg/L/24H; Shrimp LC50=4.3 ppm/96H; Fathead minnow
LC50=36.2 mg/L/96H; Sunfish (fresh water) TLm=1180 mg/L/96H.
Environmental:
CAS# 7440-22-4: Is more concentrated in bed sediments than in overlying
waters due to precipitation and sorption processes.
CAS# 78-93-3: Evaporates in water with half life of 3 days for rivers to
12 days for lakes; is not expected to bioconcentrate in aquatic
organisms. Photodegrades in air with half life of 2.3 days.
CAS# 108-88-3
Evaporates from soil and volatizes from water and is biodegraded.
Consult state and local hazardous waste regulations to ensure complete and accurate classification. US EPA guidelines for hazard classification determination are listed in 40 CFR Parts 261.3. RCRA P-Series: None listed RCRA U-Series: CAS# 78-93-3: waste number U159 CAS# 108-88-3: waste number U220
US DOT Hazard Class: UN No. 1263 Packing Group II Hazard Class 3 IATA (for international shipments) Packaging Group II IMCO No. 3.2 Flammable liquid
United States:
TSCA
CAS# 7440-22-4 is listed on the TSCA inventory.
CAS# 78-93-3 is listed on TSCA inventory.
CAS# 108-88-3 is listed on the TSCA Inventory.
Health & Safety Reporting List:
CAS# 78-93-3: Effective Date Oct. 4, 1982; Sunset Date Oct. 4, 1992
CAS# 108-88-3: Effective Date Oct. 4, 1982; Sunset Date Oct. 4, 1992
Chemical Test Rules: None of the chemicals in this product are under
a = Chemical Test Rule.
Section 12b: None of the chemicals in this product are listed under
TSCA Section 12b
TSCA Significant New Use Rule: None of the chemicals in this
material have a SNUR under TSCA.
CERCLA Hazardous RQ's:
CAS# 7440-22-4: 1000 lb final RQ (no reporting of releases of this
hazardous substance is required.)
CAS# 78-93-3: final RQ =3D 5000 pounds (2270 kg)
CAS# 108-88-3: 1000 lb final RQ; 454 kg final RQ
Section 302 (TPQ): None of the chemicals in this product have a TPQ.
SARA Codes:
CAS # 7440-22-4: delayed, fire
CAS# 78-93-3: acute, flammable
CAS# 108-88-3: immediate, fire
Section 313:
This material contains Silver (CAS# 7440-22-4, 99.9%),which is subject to
the reporting requirements of Section 313 of SARA Title III and 40
CFR Part 373.
This material contains Methyl ethyl ketone (CAS# 78-93-3, 20-30%) which
is subject to the reporting requirements of Section 313 of SARA
Title III and 40 CFR Part 373.
This material contains Toluene (CAS# 108-88-3, >99%),which is subject
to the reporting requirements of Section 313 of SARA Title III
and 40 CFR Part 373.
Clean Air Act:
CAS# 78-93-3 is listed as an hazardous air pollutants (HAP).
CAS# 108-88-3 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors, nor any Class 2
Ozone depletors.
Clean Water ACT.
CAS# 108-88-3 is listed as a Hazardous Substance under the CWA.
CAS# 7440-22-4 is listed as a Priority Pollutant under the Clean
Water Act.
CAS# 108-88-3 is listed as a Priority Pollutant under the Clean Water
Act.
CAS# 7440-22-4 is listed as a Toxic Pollutant under the Clean Water
Act.
CAS# 108-88-3 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA: None of the chemicals in this product are considered highly
hazardous by OSHA.
State Right to Know Lists:
CAS# 7440-22-4 is listed with California, Massachusetts, Minnesota,
New Jersey, and Pennsylvania.
CAS# 108-93-3 is listed with California, Florida, Massachusetts,
Minnesota, New Jersey, and Pennsylvania.
CAS# 108-88-3 Is listed with California, Massachusetts, Minnesota,
New Jersey, and Pennsylvania.
California Prop 65
WARNING: This product contains Toluene, a chemical known to the state of
California to cause developmental reproductive toxicity.
California No Significant Risk Level: None of the
chemicals in this product are listed.
European/International Regulations:
European Labeling in Accordance with EC Directives
Hazard Symbols: +F Highly Flammable; Xn Harmful; Xi Irritant
Risk Phrases:
R11 Highly Flammable
R36 Irritating to the eyes
R38 Irritating to skin
R48/20 Harmful: danger of serious damage to health by prolonged
inhalation
R63 Possible risk of harm to the unborn child
R65 Harmful: May cause lung damage if swallowed
R66 Repeated exposure may cause skin cracking or dryness
R67 Vapor may cause drowsiness or dizziness
Safety Phrases:
S2 Keep out of the reach of children
S9 Keep container in a well-ventilated area
S16 Keep away from sources of ignition - No Smoking
S 28A After contact with skin, wash immediately with plenty of water
S36/37 Wear suitable protective clothing and shoes
S46 If swallowed seek medical attention immediately and show this
container or label
S62 If swallowed, do not induce vomiting: seek medical attention
immediately and show this container or label
WGK (Water Danger/Protection):
CAS# 7440-22-4: 0
CAS# 78-93-3: 1
CAS# 108-88-3: 0
CANADA LISTS:
DSL List
CAS# 7440-22-4 is listed on Canada's DSL List.
CAS# 78-93-3 is listed on Canada's DSL List.
CAS# 108-88-3 is on Canada's DSL List.
Canada's Ingredient Disclosure List
CAS# 7440-22-4 is listed on Canada's Ingredient Disclosure List.
CAS# 78-93-3 is on Canada's Ingredient Disclosure List.
CAS# 108-88-3 is on Canada's Ingredient Disclosure List.
WHMIS
CAS# 7440-22-4 has a WHMIS classification of D2A.
CAS# 78-93-3 has a WHMIS classification of B2, D2A.
CAS# 108-88-3 has a WHMIS classification of D2A.
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