SPI Supplies Division|
|
Date Effective........... January 8, 2009
(most recent revision)
Chemical Name/Synonyms: Conductive Coating
Chemical Family: Silver in Vinyl Resin Solution
Emergencies
Use Only #'s:
Contacting CHEMTREC 24 Hour Emergency
Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #04998-AB, 04999-AB
SPI Supplies™ Flash Dry Silver Paint
CAS # Component Chemical Formula
7440-22-4 Silver (metallic) Ag
108-10-1 Methyl isobutyl ketone CH3CH2CH(CH3)COCH3
n/a Proprietary Vinyl Resin n/a
| Hazardous
Material Information System USA | Health | 2 | National Fire Protection Association USA |  |
| Fire Hazard | 3 | |||
| Reactivity | 1 | |||
| Personal Protection |
Component Name CAS # Wt Percent EINECS/ELINCS Silver (metallic) 7440-22-4 50 231-131-3 Methyl Isobutyl Ketone 108-10-1 20 203-550-1 Proprietary Vinyl Resin n/a 30 n/s
Emergency overview: Appearance: Thin silver liquid Flash Point: 64°F Tag closed cup method Warning! Flammable liquid and vapor. Target Organs: Eyes, Skin, Respiratory System, Liver, Central Nervous System Potential Health Effects: Eye: May cause severe irritation, burning sensation, blurred vision. Skin: Repeated or prolonged contact can cause irritation and dermatitis. Ingestion: May cause gastrointestinal irritation, nausea, vomiting and diarrhea. Effects may be cumulative. Aspiration hazard: Aspiration of material into lungs may cause chemical pneumonitis, which may be fatal. Inhalation: May cause nasal and respiratory irritation, dizziness, nausea, headache. Exposure may cause central nervous system depression. May cause liver abnormalities. Chronic: Chronic inhalation or ingestion of silver salts may cause argyria characterized by a permanent blue-gray discoloration of the eyes, skin, mucous membranes and internal organs. Chronic skin exposure to methyl isobutyl ketone may cause defatting and dermatitis of the skin.
Eyes: Wear chemical splash goggles. Skin: Wear solvent resistant gloves. Ingestion: Keep away from all food sources. Not for human consumption. Inhalation: Provide sufficient local exhaust ventilation to maintain exposure below TLV(S). Notes to Physician: Treat symptomatically and supportively.
General Information:
Flash point: 64 °F, Tag Closed Cup
Extinguishing Media: Foam, Carbon Dioxide, or Dry Chemical.
Water may not be effective.
Flammable Limits in Air, % by volume:
LEL (Lower Explosive Limit): Not applicable
UEL (Upper Explosive Limit): Not applicable
Special Fire Fighting Procedure: Self-contained breathing apparatus
should be worn.
Unususal Fire and Explosion Hazards: Keep away from sparks, open flames
or other sources of ignition.
General Information: Use proper protective equipment. Remove all sources of ignition and ventilate area, apply absorbent material and transfer to suitable disposal container. Spills/Leaks: Because of its high intrinsic value, and also because it is a non-renewable resource, this material should be reclaimed when possible. When reclaiming is not feasible and disposal is the only alternative, then it should be done in accordance with all applicable federal, state and local regulations.
Handling: Wash hand thoroughly after using. Wear chemical splash goggles and solvent resistant gloves. Avoid contact with eyes, skin and clothing. Avoid inhalation and ingestion. If the TLV of the product is exceeded, a mechanical exhaust system or self-contained breathing apparatus is advised. No special equipment is deemed necessary under normal usage. Storage:
Engineering Controls:
An eyewash fountain and a safety shower should be readily
available in areas of use or handling.
Exposure Limits:
Chemical Name ACGIH NIOSH OSHA - Final PELs
Silver (metallic) 0.1mg/m3TWA 0.01mg/m3 0.01 mg/m3 TWA
(dust) 0.01mg/m3TWA 10 mg/m3 IDHL(dust)
Methyl isobutyl ketone 50ppm TWA 50ppm TWA 100ppm TWA
75ppm STEL 205 mg/m3 410 mg/m3 TWA
Proprietary Vinyl Resin n/a n/a n/a
OSHA Vacated PELs:
Silver (metallic): 0.01 mg/m3 TWA
Methyl isobutyl ketone: 50 ppm TWA; 205 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear chemical splash goggles
Skin: Wear solvent resistant gloves to prevent skin contact.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: If the TLV of the product is exceeded, a mechanical exhaust
system or appropriate NIOSH approved self-contained breathing apparatus is advised.
Follow OSHA regulations in 29 CFR 1910.134 or European Standard EN 149.
Physical State: Liquid
Appearance: Thin silver liquid
Odor: sharp ketone odor
pH: n/a
Vapor Pressure: 14.5
Vapor Density: n/a
Evaporation Rate: Greater than butyl acetate
Viscosity: n/a
Boiling Point: 237° F
Freezing/Melting Point: n/a
Autoignition Temperature: n/a
Flash Point: 64° F
Decomposition Temperature: n/a
Explosion Limits, Lower: n/a
Upper: n/a
Solubility in water: partial
Specific Gravity/Density: 1.71
Molecular Formula: n/a
Molecular Weight: n/a
Chemical Stability: Under normal laboratory usage conditions material is stable. Conditions to Avoid: Ignition sources, excess heat, confined spaces. Incompatibility with Other Materials: Strong Oxidizers. Hazardous Decomposition of Products: CO, CO2 Hazardous Polymerization: Will not occur.
RTECS#: CAS# 108-10-1: SA9275000 CAS# 7440-22-4: VW3500000 LD50/LC50 Information: CAS# 7440-22-4: n/a CAS#: 108-10-1: Draize test, rabbit, eye: 40 mg Severe Draize test, rabbit, skin: 500mg/24H Mild Inhalation, mouse: LC50 = 23300 mg/m3 Inhalation, rat: LC50 = 100 gm/m3 Oral, mouse: LD50 = 1900 mg/kg Oral, rat: LD50 = 2080 mg/kg Carcinogenicity: CAS# 108-10-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65 ACGIH: California: NIOSH: NTP: OSHA: IARC: CAS# 7440-22-4: IARC Group 4; nonclassified with regard to carcinogenicity. Teratogenicity: CAS# 7440-22-4: n/a CAS# 108-10-1: n/a Reproductive Effects: CAS# 7440-22-4: n/a CAS# 108-10-1: n/a Neurotoxicity: CAS# 7440-22-4: n/a CAS# 108-10-1: Not considered to be a neurotoxin. Mutagenicity: CAS# 7440-22-4: n/a CAS# 108/10/1: Not found Other Studies:
Exotoxicity:
CAS# 7440-22-4: n/a
CAS# 108-10-1:
Flathead Minnow: LC50 = 505 mg/L, 96 hours
Goldfish: LC50 = 460 mg/L, 24 hours
Daphnia: EC50 = 4280 mg/L, 24 hours
Algae: EC50 = 400 mg/L, 96 hours
Environmental Fate:
CAS# 7440-22-4: Use of manganese dioxide or precipitation with halides are the
dominant controls for reducing the concentration of dissolved silver in aquatic
environments, resulting in higher concentrations of silver in the bed sediments
than in the waters above the sediments.
CAS# 108-10-1: In water will undergo direct photolysis and volatilization.
In soil, with undergo direct photolysis, volatilization, or aerobic biodegradation.
Is not predicted for bioaccumulation.
Physical:
CAS# 7440-22-4: May be accumulated by Flathead minnow, daphnia and algae,
but no food chain magnification has been noted.
CAS# 108-10-1: n/a
Dispose of in accordance with federal, state and local regulations. RCRA P-Series: CAS# 7440-22-4: Not listed CAS# 108-10-1: Not listed RCRA U-Series: CAS# 7440-22-4: Not listed CAS# 108-10-1: Waste number U161 - Ignitable waste
US DOT Hazard Class: Shipping name: Methyl Isobutyl Ketone Solution Hazard Class: 3 UN/NA Class: UN1263 Label: Flammable liquid Packing Group II IATA (for international shipments)
United States:
TSCA
CAS# 7440-22-4 is listed on the TSCA inventory.
CAS# 108-10-1 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 7440-22-4: Not listed
CAS# 108-10-1: Effective 10/4/80, Sunset 10/4/92.
Chemical Test Rules
CAS# 7440-22-5: Not listed
CAS# 108-10-1: Test for Health Effects
Section 12b:
CAS# 7440-22-4: Not listed
CAS# 108-10-1: Section 4 (applies only to those companies that signed an Enforceable
Consent Agreement)
TSCA Significant New Use Rule:
CAS# 7440-22-4: Does not have a SNUR under TSCA.
CAS# 108-10-1: Does not have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs:
CAS# 7440-22-4: 1000 lb final RQ (no reporting of releases of this hazardous
substance is required.)
CAS# 108-10-1: 5000 lb final RQ, 2270 kg final RQ.
SARA:
Section 302 (TPQ)
CAS# 7440-22-4: does not have a TPQ.
CAS# 108-10-1: does not have a TPQ.
SARA Codes
CAS# 7440-22-4: chronic, flammable
CAS# 108-10-1: acute, chronic, flammable, reactive
Section 313
CAS# 7440-22-4: is subject to the reporting requirements of Section 313 of
SARA Title III and 40 CFR Part 373.
CAS# 108-10-1: is subject tot he reporting requirements of Section 313 of
SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 7440-22-4 does not contain any hazardous air pollutants, and does not
contain any Class 1 or Class 2 Ozone depletors.
CAS# 108-10-1 is listed as a hazardous air pollutant, but does not contain
any Class 1 or Class 2 Ozone depletors.
Clean Water Act:
CAS# 7440-22-4: is not listed as a Hazardous Substance under the CWA, is
listed as a Priority Pollutant under the CWA, is listed as a Toxic Pollutant
under the CWA.
CAS# 108-10-1: is not listed as a Hazardous Substance, a Priority Pollutant,
or a Toxic Pollutant under the CWA.
OSHA:
None of the chemicals in this product is considered highly hazardous by OSHA.
State (Individual states in the USA)
CAS# 7440-22-4: can be found on the following state right to know lists:
California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
CAS# 108-10-1: can be found on the following state right to know lists:
California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
California Prop. 65:
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations:
European Labeling in Accordance with EC Directives
Hazard Symbols:
CAS# 7440-22-4: n/a
CAS# 108-10-1: XN F
Risk Phrases:
CAS# 7440-22-4:
R33 Danger of Cumulative Effects
CAS# 108-10-1:
R11 Highly Flammable
R36/37 Irritating to eyes and respiratory system
R20 Harmful by inhalation
R66 Repeated exposure may cause skin dryness or cracking
Safety Phrases:
CAS# 7440-22-4:
S37 Wear suitable gloves
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S28A After contact with skin, wash immediately with plenty of water
CAS# 108-10-1:
S16 Keep away from sources of ignition - No smoking
S29 Do not empty into drains.
S9 Keep container in a well-ventilated place
WGK (Water Danger/Protection):
CAS#7440-22-4: 0
CAS# 108-10-1: 1
Canada DSL/NDSL:
CAS# 7440-22-4 is listed on Canada's DSL List.
CAS# 108-10-1 is listed on Canada's DSL List.
Canada WHMIS Classification:
CAS# 7440-22-4 has a WHMIS classification of D2A.
CAS# 108-10-1 has a WHMIS classification of B2.
Canadian Ingredient Disclosure List:
CAS# 7440-22-4 is listed on the Canadian Ingredient Disclosure List.
CAS# 108-10-1 is listed on the Canadian Ingredient Disclosure List.
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