Date Effective... February 16, 2009 (most recent revision) Chemical Name/Synonyms... Emergencies Contacting CHEMTREC: 24 Hour Emergency Use Only #'s... Worldwide phone: 1-(703)-527-3887 Worldwide FAX: 1-(703)-741-6090 Toll-free phone: 1-(800)-424-9300 USA only Product or Trade Name.... SPI #04990-AB Chemical Name................. Platinum Paint
|Health||2||National Fire |
Component Name CAS # Percent EINECS/ELINCS 1-Methoxy-2-propyl acetate 108-65-6 5-15% 203-603-9 N-Butyl acetate 123-86-4 10-20% 204-658-1 Platinum 7440-06-4 >70% 231-116-1
Emergency overview: Appearance: Black/gray paste Flash Point: 84°F (28°C) Warning! Flammable liquid and vapor. Vapor harmful. Inhalation may affect the brain or nervous system causing dizziness, headache or nausea. Routes of Entry: Skin contact, Inhalation, Ingestion, Eye contact Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May cause dermatitis. Ingestion: Harmful if swallowed. Ingestion is not an expected route of entry in industrial or commercial uses. Inhalation: Respiratory system irritant. May cause a variety of symptoms such as dryness of the throat, tightness of the chest, and shortness of breath. May cause central nervous system depression, characterized by headache, dizziness, staggering gait, confusion, unconsciousness or coma. Chronic: Repeated or prolonged solvent overexposure may result in permanent central nervous system damage. Chronic skin contact may cause dermatitis.
Eyes: Flush eyes immediately with copious amounts of water, holding the eyelids open, for at least 15 minutes. Seek medical attention. Skin: Flush skin with copious amounts of water, while removing contaminated clothing. Wash affected skin areas with soap and water. Wash contaminated clothing before reuse. Seek medical attention if symptoms develop. Ingestion: If swallowed, do not induce vomiting. If conscious, give victim one or two glasses of water or milk. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately for further instructions. Inhalation: Remove victim to fresh air. If breathing is difficult, give oxygen. Give artificial respiration if breathing has stopped. Seek immediate medical attention.
General Information: Flash point: 84°F, 28°C Explosive Limits: Upper(%): 13.1%(V) Lower(%): 1.3%(V) Autoignition Temperature: Not determined Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog Firefighting Procedures: Wear full firefighting protective clothing, including a full face piece, positive pressure, self contained breathing apparatus. Water spray may be ineffective. If water is used, fog nozzles are preferable. Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Keep containers tightly closed. Keep away from heat, electrical equipment, sparks, open flames, other sources of ignition. Use water spray to keep fire exposed containers cool. Closed containers may rupture when exposed to extreme heat. Under fire conditions, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion.
General Information: Before attempting clean-up, refer to hazard caution information in other sections of the msds. Spills/Leaks: Spill Response: Evacuate the area of all unnecessary personnel. Action to take for spills: For small spills: Absorb on to rags, sand, or other absorbent material. For large spills: Get workers out of the affected area. If flammable liquids or vapors may be present, turn off electrical devices or other sources of sparks or flames. Wear protective equipment. Use supplied-air respiratory protection if vapor concentrations are not known. Contain spill at source by diking or absorbing with sand. Do not allow spill to spread to or intentionally flush to sewer or ground. Wash area thoroughly. Adequately ventilate area. Spill residue, cleaning rags, and absorbent may be refined to recover the precious metal content.
Handling: Do not handle until all safety precautions have been read and understood. Keep container tightly closed and upright to prevent leakage. Ground and bond containers when transferring material. Avoid contact with skin and eyes. Wash thoroughly after handling. Avoid breathing of vapor or spray mists. Use with adequate ventilation. Empty containers should not be re-used. Because empty containers may retain product residue and flammable vapors, keep away from heat, sparks and flame. Do not cut, puncture or weld on or near the empty container. Do not smoke where product is used or stored. Storage: Do not store or use near heat, sparks or open flame. Store only in well-ventilated areas. Do not puncture, drag or slide container. Keep container closed when not in use. Refer to OSHA 29CFR Part 1910.103 “Flammable and Combustible Liquids” for specific storage requirements.
Engineering Controls: Safety shower and eyewash station must be readily available. Ventilation sufficient to maintain air contaminant levels below recommended exposure limits must be provided. Solvent vapors are heavier than air and collect in lower levels of the work area. Explosion-proof ventilation equipment should be provided to prevent flammable vapor/air mixtures from accumulating. Exposure Limits:
|Chemical Name||CAS Number||Weight %
|N-Butyl Acetate||123-86-4||15.0%||150 ppm||200 ppm||710 mg/m3
Personal Protective Equipment Eyes: Chemical splash goggles or safety glasses with side shields Skin: Neoprene, nitrile, or rubber gloves Clothing: Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse. Respirators: Consult ANSI Standard Z988.2 for decision logic to select appropriate NIOSH/MESA approved respirators. If respirators are needed to meet applicable limits, a respiratory protection program up to the level of OSHA Standard 290CFR 1910.134 is mandatory.
Physical State: paste Appearance: black/gray Odor: mild fruity smell pH: n/a Vapor Pressure: n/a Vapor Density: Heavier than air Evaporation Rate: Faster than n-butyl acetate Viscosity: n/a Boiling Point: 259°F-302°F Freezing/Melting Point: n/a Autoignition Temperature: n/a Flash Point: 84°F, 28°C Decomposition Temperature: n/a Explosion Limits(%) Lower: 1.3%(V) Upper: 13.1%(V) Solubility in water: insoluble Specific Gravity/Density: 3.32 g/cm3 Molecular Formula: n/a Molecular Weight: n/a Volatile by Volume: 76.5% Volatile by Weight: 21.1% VOC: 5.86 lb/gal 700 g/l
Chemical Stability: Stable under normal storage conditions Conditions to Avoid: High temperatures, Sources of ignition Incompatibility with Other Materials: Strong acids, bases, and strong oxidizers Hazardous Decomposition of Products: Carbon monoxide, Carbon dioxide Hazardous Polymerization: Will not occur under normal conditions
RTECS#: CAS# 108-56-6: AI 8925000 CAS# 123-86-4: AF 7350000 CAS# 7440-06-4: TP2160000 1-methoxy-2-propanol acetate: Toxic effects described in animals include: By skin or eye contact: Mild skin irritation, eye irritation. Respiratory effects: Degeneration of the olfactory epithelium; renal effects; non-specific effects, e.g. weight loss and irritation; liver effects. Additional animal tests have shown: No genetic damage in bacterial or mammalian cell cultures; no developmental toxicity. Human health effects of over exposure may include: By skin or eye contact: Skin irritation with discomfort or rash Eye irritation with discomfort, tearing or blurring of vision By inhalation: Nonspecific discomfort, e. g. nausea, headache, or weakness Human effects of higher level acute, repeated, or chronic overexpose may include: By inhalation: Irritation to the upper respiratory passages with coughing and discomfort. In addition, animal tests indicate commercial grade 1- methoxy-2-propanol acetone does not cause developmental toxicity. However, the tests of pure 2-methoxy-1-propanol acetate in rabbits and rats by inhalation have shown developmental toxicity. 2-methoxy-propanol acetate did not show developmental toxicity by skin contact. 2-methoxy-1-propanol acetate did not show developmental toxicity by skin contact. 2-methoxy-1-propanol acetate is present in commercial grade 1-methoxy-2-propanol acetate in low concentrations. Butyl acetate: Toxic effects described in animals include: By skin or eye contact: Skin Irritation; eye irritation By inhalation: Eye irritation, narcosis; upper respiratory irritation By ingestion: Narcosis Toxic effects of repeated or prolonged animal exposures include: By inhalation: Eye irritation; lower weight gain By ingestion: Liver effects Toxic effects of chronic animal tests include: By inhalation: Liver effects Additional animal tests have shows: Developmental toxicity at dosage levels showing maternal toxicity; no genetic damage in animals, bacterial, or mammalian cell cultures. Human health effects of overexposure may include: By skin or eye contact: Skin irritation with discomfort, tearing, or blurring of vision By inhalation: Irritation of the upper respiratory passages with coughing and discomfort; nonspecific discomfort, e. g. nausea, headache or weakness. Human effects of higher level acute repeated or chronic overexposure may include: Temporary nervous system depression with anaesthetic effect, e. g. dizziness, headache, confusion, loss of coordination, loss of consciousness. Abnormal liver function as detected by laboratory tests. In addition: By skin or eye contact: Significant skin permeation appears unlikely; there are inconclusive or unverified reports of human sensitization. Platinum (metallic): SKIN CONTACT: May cause skin irritation. SKIN ABSORPTION: May be harmful if absorbed through skin. EYE CONTACT: May cause eye irritation. INHALATION: Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled. INGESTION: May be harmful if swallowed. SENSITIZATION: Prolonged or repeated exposure may lead to allergic reaction. SIGNS AND SYMPTOMS: The toxicological properties of this material have not yet been thoroughly investigated.
Exotoxicity: No information found in our selected sources Environmental Fate: No information found in our selected references. Bioaccumulation: Not expected to occur.
Use only licensed transporters and permitted disposal facilities and conform to all laws. Recycle to process, if possible. Platinum is a non-renewable resource. Care must be taken to prevent environmental contamination from the use of this material. The user of this material has the responsibility to dispose of unused materials, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes.
US DOT IATA Proper Shipping Name: Paint Paint Hazard Class: 3 3 Secondary Hazard: None None UN/NA Number: 1263 1263 Packing Group: III III Emergency Response Guide: 128
United States: TSCA All components of this product are listed on the TSCA 8 inventory. SARA: Section 302 (RQ) none Section 302 (TPQ) none SARA Codes Section 313 none CERCLA CAS# 123-86-4 has an RQ of 5000 lbs. OSHA: This product is considered hazardous as defined by 29 CFR 1910.1200(OSHA HazCom Standard.) State (Individual states in the USA) n/a California No Significant Risk Level: n/a California Prop. 65: None European/International Regulations: European Labeling in Accordance with EC Directives Hazard Symbols: Xi irritant Risk Phrases: R10 Flammable R36 Irritating to eyes R66 Repeated exposure may cause skin dryness or cracking R67 Vapors may cause drowsiness and dizziness Safety Phrases: S2 Keep out of the reach of children S25 Avoid contact with eyes WGK (Water Danger/Protection): n/a Canada WHMIS classification: This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. DSL/NDSL CAS# 108-65-6 is listed on the DSL list. CAS# 108-65-6 is not listed on the NDSL list. CAS# 123-86-4 is listed on the DSL list. CAS# 123-86-4 is not listed on the NDSL list. CAS# 7440-06-4 is listed on the DSL list. CAS# 7440-06-4 is not listed on the NDSL list.
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