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SPI Supplies Division
Section 01: Identification
Date Effective... March 30, 2006
(most recent revision)
Chemical family.......... Resin solution
Emergencies
Use Only #'s:
Contacting CHEMTREC 24 Hour Emergency
Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #05004 Thinner for SPI Supplies Silver Paint
(Formulated for use with SPI# 05001 and 05002 Silver Paint)
CAS #'s.................... Mixture
Chemical Formula........... Mixture
Hazardous components: CAS #.................... 67/64/1 Acetone 75-95% CAS #.................... 141/78/6 Ethyl acetate 2-25% Nonhazardous components: CAS #.....................Not known Acrylatevinylacetate polymer
Emergency overview: Clear, colorless liquid. Warning! Highly flammable liquid and vapor. Irritant. Symptoms of exposure: Effects of eye exposure: Causes eye irritation. May cause chemical conjunctivitis and corneal damage. Vapors may cause eye irritation. Effects of skin contact: May cause skin irritation. May cause skin sensitization. Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. May be absorbed through the skin. Effects of ingestion: Low oral toxicity. May cause gastrointestinal irritation. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Effects of inhalation: Low oral toxicity. Vapors may cause drowsiness and dizziness. High concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause motor incoordination and speech abnormalities. Chronic Effects: Chronic exposure may produce dermatitis, anemia, leukocytosis, cloudy swelling, and fatty degeneration of the viscera. May cause liver and kidney damage. May cause fetal effects. May cause cardiac sensitization and severe heart abnormalities.
Emergency and first aid procedures:
Get medical assistance for all cases of over-exposure.
Skin: Get medical aid if irritation develops or persists. Flush skin
with plenty of soap and water for at least 15 minutes, while removing
contaminated clothing and shoes. Wash thoroughly before reusing.
Discard shoes.
Eyes: Get medical aid immediately. Immediately flush thoroughly with
water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Do not allow victim to rub or keep eyes closed.
Inhalation: Get medical aid immediately. Remove to fresh air immediately.
Artificial respiration if breathing has stopped. If breathing
is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
If breathing has ceased, apply artificial respiration using oxygen
and a suitable mechanical device such as a bag and a mask.
Ingestion: Never give anything by mouth to an unconscious person.
Get medical aid immediately.Treat symptomatically and supportively.
Notes to Physician: Treat symptomatically and supportively.
Flash Point....................-4°C (25°F)
Autoignition Temperature: . . .> 260°C (500°F)
Lower Explosion Limit (%) 2.0
Upper Explosion Limit (%) 19.0
Fire Extinguishing Media:
For small fires use dry chemical, CO2, or "alcohol" foam, water spray
to cool fire-exposed containers and disperse vapor; water on fire itself
may be ineffective. For large fires, use water spray, fog or alcohol-resistant
foam. Do NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
Firefighting Procedure:
Wear self-contained breathing apparatus in pressure-demand, MSHA/NIOSH
approved or equivalent, full protective gear.
Fire and explosion hazards:
Dangerous fire and explosion hazard. Vapors may form an explosive mixture
with air. Vapor can travel distance to ignition source and flash back.
During a fire, thermal decomposition or combustion may generate irritating
and highly toxic gases. Flammable mixture. Can release vapors that form
explosive mixtures with air. Hot organic chemical vapors or mists are
susceptible to sudden spontaneous combustion when mixed with air.
Material is lighter than water and a fire may be spread by the use of water.
Containers may explode in the heat of a fire. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined areas.
Spill Response:
General Information: Wear suitable protective equipment listed under
exposure/personal protection, including self contained breathing apparatus.
Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to
waterways. Avoid all sources of ignition. Absorb spill with an absorbent,
non-combustible material such as earth, sand or vermiculite and place in
suitable container for proper disposal, using a spark-proof tool. A vapor
suppressing foam may be used to reduce vapors, but may not prevent ignition
in closed spaces.
Handling: Store at room temperature and use only in a well-ventilated area. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin and clothing. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with heat, sparks and flame. Empty containers may contain residue - do not pressurize, or expose empty containers to heat, sparks or open flames. Do not take internally. Eye wash and safety equipment should be readily available. Storage: Keep away from sources of ignition. Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a flammables area, away from incompatible materials. Store in cool, dry, well ventilated area.
An eyewash facility and a safety shower should be available. Use adequate
general or local exhaust ventilation to keep airborne concentrations below
the permissible exposure limits.
Airborne Exposure Limits:
Chemical Name ACGIH NIOSH OSHA - Final PEL
Ethyl Acetate 400 ppm TWA 400 ppm TWA 400ppm TWA
1400 mg/m3 TWA 1400 mg/m3 TWA
2000 ppm IDHL
Acetone 500 ppm TWA 250 ppm TWA 1000 ppm TWA
750 ppm STEL 590 mg/m3 TWA 2000 mg/m3 TWA 2500 ppm IDHL
OSHA Vacated PELS:
Ethyl Acetate: 400 ppm TWA; 1400 mg/m3
TWAAcetone: 1800 mg/m3 TWA; 1000 ppm STEL; 2400 mg/m3 = STEL
Personal Protective Equipment:
Eyes: Wear chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or the European Standard EN166.
Skin: Wear impervious Neoprene® or nitrile rubber protective gloves to
prevent skin exposure.
Clothing: Wear appropriate protective clothing, such as a long sleeve lab
coat, to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134
or the European Standard EN149. Always us a NIOSH or European Standard
approved respirator when necessary.
Pure substance or preparation: Preparation Physical form: Liquid Boiling Point.(760mm Hg). > 56°C (133°F) pH (Liquids Only)........ N/A Melting Point............ N/A Vapor Density/Air is 1... 2.0 Solubility In Water...... Insoluble Appearance and Color...... Mixture is a clear, colorless liquid Specific Gravity(H2O=1): 0.79 Evaporation Rate > 1 (in N-Butyl acetate unless otherwise noted) Odor..................... Like gasoline (petrol) Viscosity................ 12000-24000 mPa*s Volatiles 92-98% Volatile Organic Compounds (VOCs): 650-750 g/liter Relative density: 0.87
Stable: Stable at room temperature in closed containers under normal storage and handling conditions. May form explosive mixtures with air. Hazardous Polymerization: Has not been reported. Hazardous Decomposition Products: COx (Carbon Dioxide / Carbon Monoxide), irritating and toxic fumes and gases Conditions to avoid: Heat, incompatible materials, ignition sources, contact with ignition source, strong oxidants, plastics, resins, rubber. Materials to avoid: Water; Oxidizing agents; Reducing agents; Strong acids; Nitrates; Caustics and strong bases;
RTECS #: CAS# 141-78-6: AH5425000 CAS# 67-64-1: AL3150000 ------------------------------------------------------------------------------------- Toxicity data: CAS# 141-78-6 CAS# 67-64-1 Draize test, Rabbit, eye: n/a 20mg Severe; 20mg/24H Moderate Draize test, Rabbit, skin: n/a 500mg/24H Mild Inhalation,Mouse LC50: 45 gm/m3/2H 44gm/m3/4H Inhalation, rat LC50: 200gm/m3 50100 mg/m3/8H Oral, Mouse LD50: 4100mg/kg 3 gm/kg Oral, Rabbit LD50: 4935mg/kg 5340 mg/kg Oral, rat LD50: 5620mg/kg 5800 mg/kg Skin, rabbit LD50: >20mL/kg n/a Dermal, guinea pig LD50: n/a >9400uL/kg Carginogenicity: CAS# 141-78-6: Not listed by ACGIH, IARC, NIOSH, NTP or OSHA CAS# 67-64-1: A4 - Not listed by ACGIH or IARC Epidemiology: No information available Neurotoxicity: No information available Mutagenicity: 141-78-6: Cytogenetic Analysis: hamster fibroblast 9g/L Sex Chromosome Loss/Non-disjunction: S. cerevisiae 24400 ppm.67-64-1: Sex chromosome loss and nondisjunction (Yeast-Saccharomyces cerevisiae)=47600 ppm; Cytogenetic analysis (Rodent-hamster Fibroblast)= 40 gm/L
CAS# 141-78-6 CAS# 67-64-1
Ecotoxicity: Unknown Fish: Fathead Minnow
LC50 7280-8120 mg/L Bluegill LC50 8300mg/L
Environmental: Unknown Terrestrial:
volatilizes, leaches, and biodegrades when released in soil.
Persistence and degradability: Unknown
Consult state and local hazardous waste regulations to ensure complete and
accurate classification.
US EPA guidelines for hazard classification determination are listed in 40
CFR Parts 261.3.
RCRA P-Series: None listed
RCRA U-Series: CAS# 141-78-6: waste number U112 (Ignitable Waste)
Empty container warnings: Empty containers may contain product residue;
follow MSDS and label warnings even after they have been emptied.
IATA Classification Proper shipping name: Adhesives Hazard Class: 3 Subsidiary hazard class UN Number: UN1133 Packaging group: II IMDG Classification Proper shipping name: Adhesives Hazard Class: 3.2 Subsidiary Hazard Class UN Number: UN1133 Packaging group: II ADR/RID Proper shipping name: Adhesives Packaging group: 3 Subsidiary Hazard Class UN Number: UN 1133 Packaging group II
US FEDERAL:
TSCA
CAS# 141-78-6 is listed on the TSCA inventory.
Cas3 67-64-1 is listed on the TSCA inventory
Health & Safety Reporting List
None of the chemicals in this product are on the Health & Safety
Reporting List
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule
Section 12b
CAS# 141-78-6: 4/12b
CAS# 67-64-1: 4/12b
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
CAS# 141-78-6: final RQ = 5000 pounds (2270 kg)
CAS# 67-64-1: final RQ = 5000 pounds (2270 kg)
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS# 141-78-6: flammable
CAS# 67-64-1: acute, chronic, flammable
Section 313
No Section 313 chemicals
Clean Air Act:
This material does not contain any Class 1 Ozone depletors. This
material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None present
OSHA:
None of the chemicals in this product are considered highly
hazardous
by OSHA.
STATE:
CAS# 141-78-6 and CAS# 67-64-1 can be found on the following state
right to know
lists:
California, New Jersey, Florida, Pennsylvania, Minnesota,
Massachusetts.
European/International Regulations
Hazard Symbols:
CAS# 141-78-6: XI F
CAS# 67-64-1: XI F
Risk Phrases:
R11 Highly flammable
R36 Irritating to eyes
R 66 Repeated exposure may cause skin dryness or cracking
R 67 Vapors may cause drowsiness and dizziness
Safety Phrases:
S9 Keep container in a well-ventilated place
S16 Keep away from sources of ignition - No smoking
S26 In case of contact with eyes, rinse immediately with plenty of
water
and seek medical advice
S37 Wear suitable gloves
WGK (Water Danger/Protection)
141-78-6:1
67-64-1
Canada - DSL/NDSL
141-78-6 is listed on Canada's DSL List.
67-64-1 is listed on Canada's DSL List
Canada - WHMIS
CAS# 0141-78-6: B2, D2B
CAS# 67-64-1: B2, D2B
Canada Ingredient Disclosure List
141-28-6, is listed on the Canadian Ingredient Disclosure List.
67-64-1 is on the Canadian Ingredient Disclosure List
Exposure Limits Around the World
TWA for: Ethyl acetate Acetone
Australia 400 ppm 550 ppm
Belgium 400 ppm 750 ppm
Czechoslovakia 400 mg/m3 800 mg/m3
Denmark 300 ppm 250 ppm
Finland 300 ppm 500 ppm
France 400 ppm 750 ppm
Germany 400 ppm 1000 ppm
Hungary 400 mg/m3 600 mg/m3
Japan 400 ppm 200 ppm
The Netherlands 400 ppm 750 ppm
The Philippines 400 ppm 1000 ppm
Poland 200 ppm 200 mg/m3
Russia 400 ppm 200 ppm
Sweden 150 ppm 250 ppm
Switzerland 400 ppm 750 ppm
Turkey 400 ppm 1000 ppm
United Kingdom 400 ppm 750 ppm
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