Date Effective........... January 8, 2009 (most recent revision) Chemical Name/Synonyms... Mixture Emergencies Contacting CHEMTREC: 24 Hour Emergency Use Only #'s... Worldwide phone: 1-(703)-527-3887 Worldwide FAX: 1-(703)-741-6090 Toll-free phone: 1-(800)-424-9300 USA only Product or Trade Name.... SPI #04976-AB Thinner for SPI SafeShip™ Nonflammable Silver Paint Synonyms................. Mixture
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Component Name CAS # Percent EINECS/ELINCS Water 7732-18-5 90-95 231-971-2 Butyl Cellosolve 111-76-2 5-10 203-905-0 Ammonium Hydroxide 1336-21-6 <1 215-647-6
Emergency overview: Appearance: Colorless liquid Flash Point: n/a Warning! May cause eye and skin irritation. May be harmful if swallowed, inhaled or absorbed through the skin. May cause respiratory tract irritation. May cause central nervous system depression. Target Organs: Central nervous system, eyes Potential Health Effects Eye: May cause eye irritation. May cause transient corneal injury. Skin: May cause skin irritation. Ingestion: May be harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: May be harmful if inhaled. May cause respiratory tract irritation. May cause central nervous system effects such as nausea and headache. Chronic: Not expected.
Eyes: In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. Seek medical attention immediately. Skin: In case of contact, wash with soap and flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Seek medical attention if irritation develops and persist. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Seek medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention. Notes to Physician: Treat symptomatically and supportively.
General Information: As in any fire, prevent human exposure to fire, smoke, fumes or products of combustion. Evacuate non-essential personnel from the fire area. Fire fighters should wear full-face, self-contained breathing apparatus in pressure demand, MSHA/NIOSH approved or equivalent and impervious protective clothing. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.
General Information: Use proper protective equipment as indicated in Section 8. Spills/Leaks: Provide ventilation. Absorb spill with inert material, such as vermiculite, sand or earth, and place in suitable container for disposal. Avoid run-off into storm sewers and ditches which lead to waterways. Clean up spills immediately. Remove all sources of ignition. Use a spark-proof tool.
Handling: Use with adequate ventilation. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin and clothing. Storage: Keep away from sources of ignition. Store in tightly closed container. Store in cool, dry, well ventilated area.
Engineering Controls: Eyewash and safety shower should be readily available. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits: Chemical Name ACGIH NIOSH OSHA - Final PELs 2-Butoxyethanol 20 ppm TWA 5 ppm TWA 50 ppm TWA 24 mg/m3 TWA 240 mg/m3 TWA 700 ppm IDHL Ammonia 25 ppm TWA 25 ppm TWA 50 ppm TWA 35 ppm STEL 18 mg/m3 TWA 35 mg/m3 TWA 300 ppm IDHL OSHA Vacated PELs: 2-Butoxyethanol: 25 ppm TWA; 120 mg/m3 /TWA Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Physical State: liquid Appearance: colorless Odor: mild ammonia-like pH: n/a Vapor Pressure: n/a Vapor Density: n/a Evaporation Rate: n/a Viscosity: n/a Boiling Point: n/a Freezing/Melting Point: n/a Autoignition Temperature: n/a Flash Point: n/a Decomposition Temperature: n/a Explosion Limits, Lower: n/a Upper: n/a Solubility in water: soluble Specific Gravity/Density: ~1 Molecular Formula: n/a Molecular Weight: n/a
Chemical Stability: Stable under normal storage conditions. Conditions to Avoid: Ignitions sources, excess heat. Incompatibility with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition of Products: Carbon monoxide, carbon dioxide, irritating and toxic fumes and gases. Hazardous Polymerization: Will not occur.
RTECS#: CAS# 7732-18-5: ZC0110000 CAS# 111-76-3: KJ8575000 CAS# 1336-21-6: BQ9625000 LD50/LC50 Information: CAS #: 111-75-2 1336-21-6 Inhalation, mouse, LC50 700 ppm/7H n/a Inhalation, mouse, LC50 3380 mg/m3 /7H n/a Inhalation, rat, LC50 450 ppm/4H n/a Inhalation, rat, LC50 2900 mg/m3/7H n/a Draize test, rabbit, eye 100 mg Severe 250 µg Severe Draize test, rabbit, eye 100 mg/24H Moderate 44 µg Severe Oral, mouse, LD50 1230 mg/kg n/a Oral, rabbit, LD50 300 mg/kg n/a Oral, rat, LD50 470 mg/kg 350 mg/kg Carcinogenicity: CAS#: 111-76-2 1336-21-6 ACGIH: A3-Confirmed animal carcinogen Not listed California Prop 65 Not listed Not listed NTP: Not listed Not listed: IARC: Not listed Not listed Teratogenicity: n/a Reproductive Effects: n/a Neurotoxicity: n/a Mutagenicity: n/a Other Studies: n/a To the best of our knowledge, the chemical, physical and toxicological properties have not been thoroughly investigated.
Exotoxicity: CAS# 111-76-2: LC50, goldfish, 1650 mg/L/96H LC50, Bluegill sunfish, 1490 mg/L/96H CAS# 7664-41-4: LC50, Rainbow trout, 0.008 mg/L/24H LC50, Bluegill sunfish, 0.024-0.093 mg/L/48H Environmental Fate: CAS# 111-76-2: An estimated BCF value of 2.5 suggests that bioconcentration in aquatic organisms will be low. CAS# 7664-41-7: No information found. Aquatic: n/a Atmospheric: n/a Physical: n/a
RCRA P-Series: None listed. RCRA U-Series: None listed. Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. Consult a licensed profession to dispose of this material. Dissolve or mix with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
US DOT Hazard Class: None This substance is considered to be non-hazardous for transport. IATA (for international shipments): None This substance is considered to be non-hazardous for air transport.
United States: TSCA CAS# 7732-18-5 is listed on the TSCA inventory. CAS# 111-76-2 is listed on the TSCA inventory. CAS# 1336-21-6 is listed on the TSCA inventory. Health & Safety Reporting List CAS# 111-76-2 is listed on the Health & Safety Reporting List. Effective 4-13-89, Sunset 6-30-98. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b: None of the chemicals in this product are listed under TSCA Section 12b. TSCA Significant New Use Rule: None of the chemicals in this product have a SNUR under TSCA. CERCLA Hazardous Substances and RQs: CAS# 1336-21-6: 1000 lb final RQ; 454 kg final RQ. SARA Section 302 (TPQ) None of the chemicals in this product have a TPQ. SARA Codes CAS# 111-76-2: Immediate, delayed, fire CAS# 1336-21-6: Immediate, delayed Section 313 This material contains 2-Butoxyethanol, <10%, (CAS# 111-76-2) which is subject to the reporting requirements of Section 313 of SARA Title III and 49 CFR Part 373. Clean Air Act: CAS# 111-76-2 is listed as a hazardous air pollutant (HAP) This product does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 1336-21-6 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. State (Individual states in the USA) CAS# 111-76-2 can be found on the following state right to know lists: California, Massachusetts, Minnesota, New Jersey, Pennslyvania. CAS# 1336-21-6 can be found on the following state right to know lists: California, Massachusetts, New Jersey, Pennsylvania. California Prop. 65: California No Significant Risk Level: None of the chemicals in this product are listed under California Prop 65 European/International Regulations: European Labeling in Accordance with EC Directives CAS#: 111-76-2 1336-21-6 Hazard Symbols: XN, Xi C, N Risk Phrases: R20/21/22 R34 R36/38 R50 Safety Phrases: S2 S1/2 S36/37 S26 S46 S36/37/39 S45 S61 R20 Harmful by inhalation R21 Harmful by skin contact R22 Harmful if swallowed R34 Causes burns R36 Irritating to eyes R38 Irritating to skin R50 Very toxic to aquatic organisms S1Keep locked up S2 Keep out of reach of children S26 In case of eye contact, rinse immediately with plenty of water and seek medical attention. S36 Wear suitable protective clothing. S37 Wear suitable gloves S39 Wear suitable eye/face protection S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S46 If swallowed, seek medical advice immediately and show this container or label. S61 Avoid release to the environment. Refer to special instructions/Safety data sheets WGK (Water Danger/Protection): CAS# 111-76-2:1 CAS# 1336-21-6: 2 Canada CAS# 111-76-2 has a WHMIS classification of B3, D2B. CAS# 111-76-2 is listed on the Canadian DSL. CAS# 1336-21-6 is listed on the Canadian DSL.
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