Information System
USA
Protection Association
USA
SPI-Chem™ SPI Supplies Division
Section 01 Identification
Date Effective........ January 8, 2009
(most recent revision)
Chemical Name........ Not known
Synonyms............. Not known
Chemical family...... Not known
Emergencies Contacting CHEMTREC 24 Hour Emergency
Use Only #'s...... Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name.. SPI #02851-AB/02851-AF/02851-XK/02851-XL
LP-33 Polysulfide Liquid Polymer
CAS #.................. 68611-50-7
Chemical Formula....... HS(C2H4OCH2OC2H4SS)nC2H4OCH2OC2H4SH
Product Use............ Monomeric component for certain
epoxy based formulations
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Hazardous Material Information System USA |
Health | 0 |
National Fire Protection Association USA |
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| Fire Hazard | 1 | |||
| Reactivity | 0 | |||
| Personal Protection |
This product is not considered hazardous by OSHA Hazard Communication Standard. Chemical Name Composition Chemical Formula CAS # Liquid diethoxymethane > 99.7% 68611-50-7 polysulfide polymer HS(C2H4OCH2OC2H4SS)nC2H4OCH2OC2H4SH TSCA: Registered
Emergency Overview: Ingestion may cause nausea, vomiting, pain, upset stomach, diarrhea, prolonged or repeated contact may cause skin irritation, processing vapors may cause respiratory tract irritation. See Sections 3, 5, and 6. Physical and Chemical Hazards: Product is flammable when heated above 200° C (392°F). Primary Routes of Exposure: Eye, Skin Eye Contact: Incidental contact is not expected to cause irritation. Skin Contact: Prolonged or repeated contact may cause irritation. Inhalation (Breathing): Not hazardous in normal industrial use. Processing vapors may cause respiratory tract irritation. Ingestion (Swallowing): May cause nausea, vomiting, pain, and stomach upset (e.g. diarrhea). Target Organs/Chronic Effects: None known. Conditions Aggravated by Exposure: Exposure to this product is not expected to contribute, worsen, or aggravate any pre-existing medical conditions. Carcinogenicity: No regulated ingredients. Environmental Effects: No data available.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention at once. Remove any contact lenses that might be worn by the victim. Skin Contact: Immediately flush with water. Remove contaminated clothing and shoes. Get medical attention if irritation persists. Professionally wash clothing and shoes before re-use. Inhalation (Breathing): Remove the victim from the contamination immediately to fresh air. If breathing is weak, irregular, or has stopped, open the victim's air way, loosen collar and belt and administer artificial respiration. Seek medical advice immediately. Ingestion (Swallowing): Seek medical attention. Immediately induce vomiting as directed by medical personnel. Never give anything by mouth to an unconscious person. Notes to Physicians: Treatment should be directed at preventing absorption, administering to symptoms (if they occur), and providing supportive therapy.
Flash Point > 93.3°C (200°F) Open Cup Method Auto Ignition Temperature: No data available Upper Explosion Limit: No data available Lower Explosion Limit: No data available Hazardous Combustion and Decomposition Products: Smoke, soot and toxic/irritating fumes (i. e. carbon dioxide, carbon monoxide, etc.). Formaldehyde and/or other aldehydes. Oxides of sulfur. Hydrogen sulfide. Low molecular weight hydrocarbons. Fire and Explosion Hazards: During a fire, irritating and highly toxic gases may be generated during combustion or decomposition. Extinguishing Media: Small fires: Dry chemical, carbon dioxide, dry sand, or foam. Large fires: Water spray, fog, or alcohol foam. Fire Fighting Procedure/Equipment: Fire fighters and others who may be exposed to the products of combustion should be equipped with NIOSH-approved positive pressure self-contained breathing apparatus (SCBA) and full protective clothing.
Evacuation:
Isolate hazard area. Keep unnecessary and unprotected
personnel from entering. Eliminate all sources of ignition and
ventilate the area.
Containment:
Safely stop discharge. Contain material, as necessary, with a dike
or barrier. Stop material from contaminating soil, or from entering
sewers or bodies of water.
Collection and Disposal:
Stop discharge, if safe to do so. Use proper protective equipment.
Cover spills with absorbent clay or sawdust and place in closed
chemical waste containers. Dispose of according to applicable
local, state, and federal regulations.
Reporting:
Spills of this material in excess of a component's RQ must be reported
to the National Response Center(USA: 1-800-424-8802) and to the
appropriate state and local emergency response organizations.
No regulated ingredients.
Storage Conditions: Store in cool, dry, well ventilated area. Transfer: No special precautions are needed. Follow good manufacturing and handling practices. Personal Hygiene: Wash thoroughly after handling, especially before eating, drinking, smoking, and using restroom facilities. Wash contaminated goggles, faceshield, and gloves. Professionally launder contaminated clothing before reuse. Protective measures against fire and explosion: Shut off all gas and pilot lights or sources of electrical spark until the area has been cleared of all vapors and orders from the chemical. Use explosion proof hand tools. In case of fire or explosion, do not inhale fumes. Do not mix this product with strong oxidizers or bases. Empty Container Precautions: Attention! This container can be hazardous when empty. Follow label warnings even after container is emptied since empty containers may retain product residues. Do not reuse empty container without professional cleaning for food, clothing or products for human or animal consumption or where skin contact can occur.
Exposure Guidelines
Control parameters:
Content
Liquid diethoxymethane polysulfide polymer
OSHA ppm(mg/m3) N. A.
ACGIH ppm(mg/m3) N. A.
Labor Safety & Health Act (Japan) ppm(mg/m3) N. A.
Engineering Controls/Ventilation
Local exhaust ventilation is recommended when
vapors, mists, or dusts can be released.
Eye Protection:
Wear chemical splash goggles or safety glasses with side shields.
An eye wash facility should be readily available.
Skin Protection:
Wear protective clothing and appropriate impervious gloves.
Because a variety of protective gloves exists, consult glove
manufacturer to determine the proper type for a specific operation.
Respiratory Protection:
Industrial hygiene consultation is recommended because airborne
exposure levels vary depending on the nature of the operation
performed. Respiratory protection is not usually required.
Appearance: Amber liquid Vapor pressure (mm Hg): No data available Vapor density (air=1): No data available Viscosity: 1.8Pa . s (25° C) Evaporation rate: No data available Volatile %: 99 Boiling point: No data available Odor threshold (ppm): Mercaptan Physical state: Liquid Specific gravity (20°C): 1.29 Solubility in water: <0.01g/l Solubility in other solvents: Xylene, Toluene Coefficient of oil/water: No data available Pour point: Not known Melting point: No data available pH: ~7 Cloud point: No data available Flash point: > 93.3°C (200°F) Flash method: Open cup method Upper explosion limit: No data available Lower explosion limit: No data available Auto ignition temperature: No data available Dust explosion: None Self-reactivity: None Oxidizability: None Note: The physical data presented above are typical values and should not be construed as a specification. This product is considered stable under normal and anticipated storage and handling conditions. Incompatibilities: Oxidizers, strong bases
Chemical Stability: Stable under normal conditions of use. Incompatibilities with Other Materials: Oxidizers, acids, alkalis Keep away from heat. Polymerization: Hazardous polymerization is not expected to occur.
Product: Found not to induce skin sensitization reactions when tested in guinea pigs. Studies with laboratory animals indicate that this product is not an eye irritant. Rats exposed to airborne concentrations of 230 mg/L for 4-hours developed eye and respiratory irritation; however, this level is believed to far exceed any that might be encountered in normal workplace environments. Oral LD50: Rat 3,000 mg/kg Dermal LD50: Rabbit > 2,000 mg/kg
Ecotoxicological Information: The ecological toxicity of this product is not known. Distribution: Other ecological information on this product is not known. Chemical Fate: Chemical fate information on this product is not known.
Disposal: Dispose in accordance with all local, state, and federal regulations. General Statements: Federal regulations may apply to empty container. State and/or local regulations may be different. General Recommendations: Of the methods of disposal currently available, it is recommended that an alternative be selected according to the following order of preference, based upon environmental acceptability: (1) recycle or rework, if feasible (2) incinerate at an authorized facility, or (3) treat at an acceptable waste treatment facility. Special Instructions: Be sure to contact the appropriate government environmental agencies if further guidance is required.
Not Regulated: 49 CFR IATA IMO DOT Label: Not applicable UN/NA ID Number: Not applicable
US Federal:
SARA Title III - Section 311/312 - Hazard Categories
Fire Hazard: No
Sudden Release of Pressure Hazard: No
Reactivity Hazard: No
Immediate (acute) Health Hazard: No
Delayed (chronic) Health Hazard: No
Ozone Depleting Chemicals:
No regulated ingredients
SARA Section 302 Extremely Hazardous Material:
No regulated ingredients
SARA Section 313 Toxic Chemicals:
No regulated ingredients
Chemical Listing:
Listed on the following country's chemical inventories:
United States Toxic Substance Control Act
Chemical component(s) in this product are on the section 8 (b)
Chemical Substance Inventory List (40 CFR 710)
EINECS: Registered
CAS: Registered
State Right-To-Know
Pennsylvania - New Jersey R-T-K
Non-hazardous trade secret ingredients
Proprietary Balance
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer
products into the State of California to provide a warning statement
if the product contains ingredients for which the State has found to
cause cancer, birth defects or other reproductive harm. If this product
contains an ingredient listed by the State of California to cause cancer
or reproductive toxicity, it will be listed below:
Warning: This product contains a chemical(s) known to the State of
California to cause cancer and birth defects or other reproductive harm.
Component CAS # Amount
Formaldehyde 50-00-0 Trace
(cancer hazard)
Ethylene oxide 75-21-8 Trace
(cancer and reproductive hazard)
Explanation of "Trace": Present at less than 0.01%
CONEG:
Canada:
Not a controlled product
CEPA-NPRI:
No regulated ingredients
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.********************************************************************** The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation.
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