Date Effective........... January 8, 2009 (most recent revision) Synonyms................. Dimethylaminoethanol; DMAE; N,N-Dimethylaminoethanol; 2-(Dimethylamino)ethanol; N,N-Dimethyl-2-hydroxyethyl)amine Product Use.............. Accelerator for epoxy resin formulations Chemical family.......... Alkyl alkanol amines Chemical name ........... 2-Dimethylaminoethanol CAS #.................... 108-01-0 Chemical Formula......... C4H11NO Emergencies Contacting CHEMTREC 24 Hour Emergency Use Only #'s............. Worldwide phone : 1-(703)-527-3887 Worldwide FAX : 1-(703)-741-6090 Toll-free phone : 1-(800)-424-9300 USA only
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HMIS Rating: Health: 3 Flammability: 2 Reactivity: 0 Personal NFPS Rating: Health: 3 Flammability: 2 Reactivity: 0
Substance Description CAS# RTECS # Dimethylaminoethanol 108-01-0 KK6125000 (See Section 8 for exposure guidelines) (See Section 15 for regulatory information)
Emergency overview: Combustible, corrosive Harmful by inhalation, in contact with skin and if swallowed. Causes burns. May cause sensitization by skin contact. Lachrymator. Target organ(s): Central nervous system. Potential Health Effects: Eye: Causes burns; lachrymator Skin: Causes burns; harmful if absorbed through skin Inhalation: Material is extremely destructive to mucous membrane tissue and to the upper respiratory tract. Harmful if inhaled. Ingestion: Harmful if swallowed.
Inhalation - First Aid If inhaled, remove victim to fresh air. If not breathing, give artificial respiration. If breathing becomes difficult, give oxygen and get medical attention. Skin Contact - First Aid Immediately remove contaminated clothing and shoes. Flush skin with plenty of soap and water for at least 15 minutes. Get medical attention immediately. Eye Contact - First Aid Immediately flush eyes with large quantities of running water for a minimum of 15 minutes. If the victim is wearing contact lenses, remove them. Hold the eyelids apart during the flushing to ensure rinsing of the entire surface of the eye and lids with water. Contact a physician at once. Ingestion - First Aid If swallowed, wash out mouth with water provided person is conscious. Get medical attention by calling a physician or a poison control center immediately. Do not induce vomiting.
Flash Point 39°C (102°F) closed cup method Auto Ignition Temperature: 245 °C Upper Explosion Limit: 12.2 % Lower Explosion Limit: 1.4 % Extinguishing Media Water, carbon dioxide, foam or dry powder. Fire Fighting Instructions: Combustible liquid. Emits toxic fumes under fire conditions. Use carbon dioxide, dry chemical powder, or appropriate foam. Protective equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Spill Procedure: Evacuate area. Shut off all sources of ignition Safeguards (Personnel): Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. Initial Containment: Cover with dry lime or soda ash, pick up, keep in closed container and hold for waste disposal. Ventilate area and wash spill site after material pickup is complete.
Handling (Personnel): Wash contaminated clothing before reuse. Discard contaminated shoes. Wash thoroughly after handling. Do not breathe vapor. Do not get in eyes, on skin, or on clothing. Avoid prolonged or repeated exposure. Handling (Physical aspects): Keep container tightly closed. Keep away from heat and open flame. Handle and store under inert gas. Storage: Store in a cool, dry place.
Engineering Controls: Facilities storing or using this material should be equipped with an eye wash and safety shower. Use only in a chemical fume hood. Eye/Face Protection Requirements: Chemical safety goggles are recommended to avoid contact with eyes. Other: Faceshield (8-inch minimum) Skin Protection Requirements: Wear protective clothing and chemical-resistant gloves to avoid all Skin contact. Respiratory Protection Requirements: Follow the OSHA respirator regulations found in 29CFR 1910.134 and ANSI Z88.2 requirements or the European Standard EN149 whenever workplace conditions warrant a respirator’s use.
Physical form: Liquid Molecular weight 89.1 Color: Clear, faintly yellow liquid Odor: Fishy Boiling point: 134-136°C Melting point: -70 °C Solubility in water: Soluble Solubility in other solvents: Not determined Specific Gravity: 0.886 (Water = 1) Vapor pressure (mm Hg): 6.12 mm Hg (20 °C Vapor density (air=1): 3.1 g/l Evaporation rate: No data available Volatile %: No data available Odor threshold (ppm): No data available Coefficient of oil/water: No data available Refractive index: 1.43 Flash point: 39°C (102°F) Flash method: Closed Cup Auto ignition temperature: 245 °C
Stability: This product is stable at ambient conditions. Polymerization: Hazardous polymerization will not occur. Incompatibility with other materials: Incompatible with oxidizing agents, copper, copper alloys, zinc Galvanized iron, acids Decomposition: Decomposition products include carbon monoxide, carbon dioxide and Nitrogen oxides.
Toxicological - Inhalation: Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Harmful if inhaled. Toxicological - Dermal: Causes burns. Harmful if absorbed through skin. May cause allergic skin reaction. Toxicological - Eye: Causes burns. Lachrymator. Toxicological - Ingestion: Harmful if swallowed. Target organ(s): Central nervous system Signs and symptoms of exposure: Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes and skin. Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis, and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Carcinogenicity: CAS# 108-01-0 is not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Toxicity data: Oral, Rat LD50 2000 mg/kg Inhalation, Rat LC50 1641 ppm Intraperitoneal, Rat LD50 1080 mg/kg Inhalation, Mouse LC50 3250 mg/m3 Intraperitoneal, Mouse LD50 234 mg/kg Subcutaneous, Mouse LD50 961 mg/kg Skin, Rabbit LD50 445 µl/kg
Ecotoxicological Information: LC50 Fish (Leuciscus idus): >100-220mg/l or 96h EC50 Daphnia (Daphnia): 98.37 mg/l for 48 h EC50 Algae: 35 mg/l for 72h LC50 Bacteria: >8000 mg/l for 17h Distribution: Other ecological information on this product is not known. Chemical Fate: Chemical fate information on this product is not known.
Material that can not be used or chemically reprocessed should be disposed of in accordance with all applicable regulations. All waste materials should be packaged, labeled, and transported in accordance with all national, state/provincial, and local requirements. Product containers and/or bottles should be thorough emptied before disposal. NOTE: State and local regulations as well as those in other countries might be more stringent than USA federal regulations. Container Disposal: Containers and bottles should be drained of all residual product before disposal. Empty containers should be disposed of in accordance with all applicable laws and regulations. RCRA P-Series: Not listed RCRA U-Series: Not listed
Shipping Name: 2-Dimethylaminoethanol US DOT Hazard Class: 8 UN Number: UN2051 Packing Group: II Hazard label: Corrosive Hazard label: Flammable liquid
Section 15: Regulatory Information Chemical Inventory Information: This material is listed on the Inventory of Existing Chemical Substances under the Toxic Substance Control Act (TSCA). Health & Safety Reporting List: This chemical is not on the Health & Safety reporting List. Chemical Test Rules: This chemical is not under a Chemical Test Rule. Section 12b: This chemical is not listed under TSCA Section 12b. CERCLA Hazardous Substances and corresponding RQs: This chemical does not have a RQ. This chemical does not have a TPQ. SARA Codes: CAS# 108-01-0: acute, flammable Section 313: Is not reportable under Section 313. Clean Air Act: Does not contain any hazardous air pollutants, any Class 1 Ozone depletors, nor any Class 2 Ozone depletors. Clean Water Act: Is not listed as an Hazardous Substance under the CWA; is not listed As a Priority Pollutant nor as a Toxic Pollutant. OSHA: Is not considered as highly hazardous by OSHA. State: Is listed on the state right to know lists of New Jersey, Pennsylvania, and Massachusetts. California No Significant Risk Level: Is not listed. European and International Regulations: Risk Phrases: R10 Flammable R20 Harmful by inhalation R21 Harmful in contact with skin R22 Harmful if swallowed R34 Causes burns Safety Phrases: S25 Avoid contact with eyes S26 In case of contact with eyes, rinse immediately with plenty Of water and seek medical advice. S36 Wear suitable protective clothing S37 Wear suitable gloves S38 Wear suitable eye/face protection S45 In case of accident or if you feel unwell, seek medical Advice immediately (show label where possible). WGK (Water Danger/Protection) CAS# 108-01-0: 1 Canada – DSL/NDSL CAS# 108-01-0 is listed on Canada’s DSL list. Canada – WHMIS CAS# 108-01-1 has a WHMIS classification of B3, E Exposure Limits: CAS# 108-01-0: OEL-Russia: STEL 5 mg/m3, skin
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