SPI Supplies Division|
|
Date Effective...........July 2, 2007
(most recent revision)
Chemical Name/Synonyms...Tris-2,3,6-(dimethylaminomethyl)phenol;
DMP-30; Ancamine K54; Araldyte DY 064;
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s...
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI-Chem™ DMP-30 Epoxy Accelerator, DY 064
Synonyms.................
| Hazardous
Material Information System USA | Health | 3 | National Fire Protection Association USA |  |
| Fire Hazard | 1 | |||
| Reactivity | 0 | |||
| Personal Protection |
Component Name CAS # % EINECS/ELINCS Tris-2,4,6-(dimethylaminomethyl)phenol 90-72-2 <95% 202-013-9 Bis(dimethylaminomethyl)phenol 71074-89-0 <5% 275-162-0
Emergency overview: Warning! Harmful in contact with skin. Harmful if swallowed. Corrosive. Severe skin irritant. Severe eye irritant. Components of this product may affect the nervous system. Appearance: light yellow liquid Flash Point: 149.89°C Target Organs: Skin, Eyes, Central nervous system Potential Health Effects Eye: Causes eye burns. May cause blindness. Severe eye irritant. Skin: Harmful in contact with skin. Causes skin burns. If absorbed through skin, may cause central nervous systems effects, such as dizziness, confusion, breathing difficulties, headache, nausea. Symptoms of overexposure may include headache, dizziness, tiredness, nausea and vomiting Ingestion: Harmful if swallowed. Causes severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. May cause central nervous system effects, such as dizziness, confusion, breathing difficulties, headache, nausea, vomiting, abdominal pain. Severe cases of overexposure may result in respiratory failure. Inhalation: May cause severe eye, skin and respiratory tract burns. May cause central nervous system effects, such as breathing difficulties, headache, nausea, dizziness, confusion. Severe cases of overexposure may result in respiratory failure. Chronic: Prolonged contact may result in chemical burns and permanent damage. Sub-chronic exposure of this material or component in test animals has caused abnormalities in the central nervous system. Aggravated Medical Conditions: Eye disease, Skin disorders, Allergies, Neurological disorders.
General advice: Seek medical attention. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. If breathing has stopped or is labored, give artificial respiration. Supplemental oxygen may be needed. Eyes: Holding eyelids apart, initiate and maintain gentle and continuous irrigation until the patient receives medical care. If medical care is not promptly available, continue to irrigate for ONE HOUR. Skin: Immediately remove contaminated clothing and any extraneous chemical, if possible to do so without delay. Initiate and maintain gentle and continuous irrigation until the patient receives medical care. If medical care is not promptly available, continue to irrigate for ONE HOUR. Cover wound with sterile dressing. Ingestion: Do NOT induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Prevent aspiration of vomit. Turn victim’s head to the side. Inhalation: Remove to fresh air. If breathing is labored or has stopped, give artificial respiration. Supplemental oxygen may be indicated.
General Information: May generate ammonia gas. May generate toxic nitrogen oxide gases. Use of water may result in the formation of very toxic aqueous solutions. Do not allow run-off from fire fighting to enter drains or water courses. Incomplete combustion may form carbon monoxide. Downwind personnel must be evacuated. Burning produces obnoxious and toxic fumes. Extinguishing Media: Alcohol-resistant foam, Carbon dioxide, Dry chemical, Dry sand, Limestone powder. Protective Equipment: Use personal protective equipment and face shield to avoid contact with the skin. Fire fighters should wear full-face, self-contained breathing apparatus, in pressure-demand, MSHA/NIOSH or European Standard EN 149 (approved or equivalent), and impervious protective clothing.
General Information: Evacuate personnel to safe areas. Wear self-contained breathing apparatus, chemically protective clothing, heavy rubber boots, rubber gloves, and eye/face protection. Spills/Leaks: Construct a dike to prevent spreading. If possible, stop flow of product. Approach suspected leak areas with caution. Absorb on sand or vermiculite and place in closed containers for disposal. Ventilate area and wash spill site after material pickup is complete.Section 7: Handling and Storage
Handling: Do not breathe vapor. Avoid contact with eyes, skin and clothing. Avoid prolonged or repeated exposure. Storage: Store in tightly closed containers in cool, dry, well-ventilated area. Do not store near acids.
Engineering Controls: Eye wash station and safety shower. Natural or explosion-proof ventilation adequate to ensure concentrations are kept below exposure limits. Personal Protective Equipment Eyes: Chemical safety goggles. Skin: Neoprene or butyl rubber gloves. Clothing: Suitable impervious clothing to prevent skin contact. Discard contaminated leather items. Respirators: Self-contained breathing apparatus, in pressure-demand, MSHA/NIOSH or European Standard EN 149 (approved or equivalent) if exposure limits exceeded.
Physical State: Liquid Appearance: Light yellow Odor: Amine-like pH: not available Vapor Pressure: <0.01 mm Hg at 70°F (21°C) Vapor Density: >1 g/l Evaporation Rate: not available Viscosity: not available Boiling Point: >212°F (>100°C) Freezing/Melting Point: not available Autoignition Temperature: not available Flash Point: 148.89°C Decomposition Temperature: not available Explosion Limits: Lower: not available Upper: not available Solubility in water: 3 grams/liter Specific Gravity/Density: 0.97 grams/cm3 Molecular Formula: CAS# 90-72-2: C15H27N3O CAS# 71074-89-0: C12H20N2O
Chemical Stability: Stable under normal conditions. Incompatibility with Other Materials: Sodium hypochlorite; strong oxidizing agents; organic acids; mineral acids; peroxides. Hazardous Decomposition of Products: Nitric acid; ammonia; nitrogen oxides; carbon monoxide; carbon dioxide. Hazardous Polymerization: Will not occur.
RTECS#: SN3500000
LD50/LC50 Information:
Ingestion Rat LD50: 1,670 mg/kg
Inhalation No data available
Skin Rabbit DL50: 1,400 mg/kg
Eye irritation/corrosion: Severe eye irritation
Acute dermal irritation/corrosion: Severe skin irritation
Dermal sensitization to this product or component has been seen in some humans.
Teratogenicity: not available
Reproductive Effects: not available
Neurotoxicity: not available
Mutagenicity: not available
Other Studies: not available
Exotoxicity: No data available
Environmental Fate: No data available
Aquatic toxicity:
Rainbow trout (Oncorhynchus mykiss) LC50(24H): 222 mg/l
Rainbow trout (Oncorhynchus mykiss) LC100(96h): 240 mg/l
Rainbow trout (Oncorhynchus mykiss) LC0(96h): 180mg/l
Carp (Cyprinus carpio) LC50(24h): 249 mg/l
Carp (Cyprinus carpio) LC50(96h): 175 mg/l
Grass shrimp (Palaemonetes) EC50(96h): 718 mg/l
Mud crab (Neopanope) EC100(96h): 1,000 mg/l
Mud crab (Neopanope) EC0(96h): 750 mg/l
Atmospheric: No data available
Physical: No data available
Contact a licensed professional waste disposal service to dispose of this material. Observe all federal, state and local regulations. RCRA P-Series: not available RCRA U-Series: not available
US DOT Hazard Class:
Proper shipping name: Amines, liquid, corrosive, n.o.s.
Class: 8
UN#: UN2735
Packing Group: III
IATA (for international shipments)
Proper shipping name: Amines, liquid, corrosive, n.o.s.
Class: 8
UN#: UN2735
Packing Group: III
United States:
TSCA
All components of this product are listed on the TSCA Inventory or are not
required to be listed.
Health & Safety Reporting List
None of the components of this product are on the Health & Safety Reporting List.
Chemical Test Rules
None of the components of this product has a Chemical Test Rule.
Section 12b:
None of the components of this product is listed under TSCA 12B.
TSCA Significant New Use Rule:
None of the components of this product has an SNUR under TSCA.
CERCLA Section 103:
None of the components of this product has an RQ.
SARA:
Section 302 (TPQ)
None of the components of this product has a TPQ.
SARA Title III:
Section 312
Acute Health Hazard
Section 313
None listed
Clean Air Act:
Not listed
Clean Water Act:
Not listed
OSHA:
This product is classified as corrosive.
State (Individual states in the USA)
Not listed
California No Significant Risk Level:
Not listed
California Prop. 65:
This product does not contain any chemicals known to the State of California to
cause cancer, birth defects, or any other harm.
European/International Regulations:
European Labeling in Accordance with EC Directives
Hazard Symbols: Xn Harmful
Risk Phrases:
R 22 Harmful if swallowed.
R 36 Irritating to eyes.
R 38 Irritating to skin.
Safety Phrases:
S 2 Keep out of the reach of children.
S 26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S 28 After contact with skin, wash immediately with plenty of water and seek medical
attention. Continue irrigation for at least ONE HOUR if medical attention not
immediately available.
WGK (Water Danger/Protection):
Not available
Canada
DSL/NDSL
CAS# 90-72-2 is on the DSL List.
CAS# 71074-89-0 is not on the DSL List or the NDSL List.
This product has a WHMIS classification of
Toxic Material Causing Other Toxic Effects, Corrosive Material.
This material is included on the following inventories:
Australia AICS
Japan ENCS
South Korea ECL
China SEPA
Philippines PICCS
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty c oncerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids. ********************************************************************** The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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