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Date Effective........... February 7, 2008
(most recent revision)
Chemical Name............ Glyceringlycidether;
1,2,3-Propanetriol, polymer with (chloromethyl)-oxirane
Chemical Family.......... Epoxy Resin
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s......
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #02659-AB SPI-PON™ 812 Epoxy Resin Monomer
Also found as a component in
SPI#02635-AB SPI-Pon™ - Araldite® Epoxy Kit
SPI#02660-AB original SPI-Pon™ 812 Epoxy Kit
SPI#02663-AB modified SPI-Pon™ 812 Epoxy Kit with BDMA.
CAS #:.................... 90529-77-4
EC#:...................... 292-011-4
Chemical Formula.......... Not available
CAS #............ 90529-77-4 99.9+% Glyceringlycidether
NFPA Rating: Health: 2
Fire: 1
Reactivity: 0
HMIS Rating: Health: 1
Fire: 1
Reactivity: 0
Emergency overview:
This material may be irritating upon contact.
Physical Health Hazards:
Irritant.
Physical state: Liquid
Color: Clear Yellow
Odor: Odorless
Odor threshold: No data available
Potential Health Effects:
Routes of exposure
Eye, ingestion, skin contact
Signs and Symptoms of Acute Exposure:
Not known.
Take proper precautions to ensure your own health and safety before attempting to rescue and providing first aid. These practices include avoiding all unnecessary exposure and removal of the material from eye, skin , and clothing. For specific information refer to the Emergency Overview in Section of this MSDS. Skin contact: Wash affected area with copious amounts of water. If skin irritation persists, seek medical attention. Inhalation: Remove to fresh air. Give oxygen or artificial respiration, as needed. Seek immediate medical attention. Eye contact: Flush eyes with water for at least 15 minutes and seek medical attention. Ingestion: Drink 1 or 2 glasses of water. Seek medical attention. Chronic Health Effects Summary: No known chronic health effects. Conditions Aggravated by Exposure: No known conditions are aggravated by this material.
NFPA Rating: Health: 2 Fire: 1 Reactivity: 0
Flash Point: 118° -135° C (244° - 275° F
Auto-Ignition Temperature: 270° C (518° F)
Flammable Limits:
Lower: Not available
Upper: Not available
Hazardous Combustion/Decomposition Products:
Hydrogen chloride, phosgene, toxic pyrolysis products, carbon monoxide or
carbon dioxide may be formed.
Extinguishing Media:
Water spray, foam, dry powder or carbon dioxide. Do not use straight streams
of water. For large fires use alcohol resistant foam.
Fire Fighting Instructions:
Protective Equipment/Clothing: Wear a NIOSH approved positive
pressure self-contained breathing apparatus and firefighter
turnout gear. Remove non-emergency personnel from the area.
Release response:
Use proper protective equipment as indicated in Section 8.
Absorb with vermiculite, dry sand or earth. Pick up absorbed materials
and store in closed, labeled container for disposal. Prevent run-off
or release into sewers or ground water.
Handling: Use only with adequate mechanical ventilation. Use neoprene gloves, safety goggles. If respiratory protections is needed, use an approved chemical respirator. Wear protective clothing. Keep ignition sources away. A safety shower and eye wash should be available in the work place. Storage: Store in tightly closed container in cool, well ventilated area. Store away from metals, strong acids, alkalines, and oxidizing agents. Avoid contact with air / oxygen. Store at 15°C to 25°C.
Engineering Controls:
Use only with adequate mechanical ventilation. Safety shower and eye wash
station must be available to the workplace.
Personal Protection:
Inhalation: Use appropriate respiratory protection where needed.
Skin: Wear neoprene gloves. Protective clothing such as long
sleeves or a lab coat should be worn.
Eye: Always use safety goggles, even for work with small
quantities.
Boiling Point/Range: Decomposes
pH: (10 g/l) at 20°C: 6-8
Vapor Pressure: Not applicable
Viscosity: Dynamic at 20°C: 100-200 mPas
Specific Gravity (Water = 1): 1.22
Water solubility: 20-30 g/l
Melting/Freezing Point: Not applicable, resin not crystalline
Evaporation Rate: Not applicable
Flash Point: 118 – 135°C (244-275°F
Ignition Temperature: 270°C (518°F)
Chemical Stability:
Danger of polymerization
Conditions to Avoid:
Avoid contact with excessive heat, sparks or open flame. Overheating may
lead to spontaneous, possibly explosive, exothermic polymerization.
Incompatibility with:
Alkalies, strong acids, strong bases, some metallic salts, oxidizing
agents, some powdered metals.
Hazardous Products of Deposition:
Hydrogen chloride, phosgene, toxic pyrolysis products, carbon dioxide,
carbon monoxide.
Summary:
This material may be an irritant on skin contact. This material may be
harmful if swallowed or inhaled. This material may be a sensitizer on skin
contact.
Eye Effects:
Strong irritant.
Skin Effects:
Strong irritant. Sensitization possible.
Acute Oral Effects:
Harmful if ingested.
Acute Inhalation Effects:
Harmful if inhaled.
CAS# Dermal LD50 Oral LD50
90529-77-4 >2000 mg/kg rabbit 5000 mg/kg rat
Chronic Effects/Carcinogenicity:
CAS# 90529-77-4 is not listed by OSHA, IARC, NTP or CA Prop 65
Reproductive/Development Effects:
AMES Test: Mutagenic effects noted.
Exotoxicity: Persistence & Degradability: Does not biodegrade. Other Information: Not available. Ecotoxicity: No data available Avoid penetration into soil, sewage and water ways. CSB Value: At 0.11 wt% in water, COD= 19,800 At 0.05 wt% in water, COD= 5,300
Product must be landfilled or incinerated in accordance with all applicable local, state, and federal laws and regulations. Consult your appropriate regulatory officials for information on such disposal
Proper Shipping Name: Not applicable DOT Status: Not Regulated
TSCA: This product is listed on the TSCA 8(b) inventory.
If identified components of this product are listed
under the TSCA 12(b) Export Notification Rule, they
will be listed below.
TSCA 12(b) Component Listed under TSCA Section: None
SARA-Section 313 Emissions Reporting: Not listed
SARA-Section 311/312: Not listed
SARA-Section 355: Not listed
CERCLA Hazardous Substances and their Reportable Quantities: Not listed
WHMIS RATING: Not available
DSL: This product is listed on the DSL.
Carcinogenicity:
This product is not listed on EPA, IARC, NTP, TLV, MAX, NIOSH-Ca, OSHA-Ca
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer
products into the State of California to provide a warning statement
if the product contains ingredients for which the State has found to
cause cancer, birth defects or other reproductive harm. If this product
contains an ingredient listed by the State of California to cause cancer or
reproductive toxicity, it will be listed below:
EUROPEAN LABELING:
Hazard: XI Irritant
Risk Phrases:
R36/38 Irritating to eyes & skin
Safety Phrases:
S24/25 Avoid contact with skin & eyes
S26 In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice
S27/28 After contact with skin, take off immediately all
contaminated clothing, and wash immediately with plenty of
water
S36/37/39 Wear suitable protective clothing, gloves and eye/face
protection
WGK: 1
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
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