SPI Supplies
SPI Supplies Division
Structure Probe, Inc.
P.O. Box 656 West Chester, PA 19381-0656 USA
Phone: 1-(610)-436-5400 Fax: 1-(610)-436-5755
E-mail: spi3spi@2spi.com
WWW: http://www.2spi.com
Manufacturer's CAGE: 1P573

Material Safety Data Sheet

SPI #02655-AB, 02655T-AB NanoplastŪ FB-101 Water Soluble Embedding Resin Kit, Resin

Section 1: Identification

Date Effective..........January 8, 2009
                        (most recent revision)

Chemical Name/Synonyms..NanoplastŪ Resin;
                        MME 7002; Non-plastified melamine resin;
                        Hexamethylolmelamine methyl ether;
                        Hexamethoxymethylmelamine;
                        N-hexamethylolmelamine hexamethylether;
                        Hexakis(methoxymethyl) melamine 

Emergencies
Contacting CHEMTREC:

24 Hour Emergency Use Only #'s... 
Worldwide phone: 1-(703)-527-3887
Worldwide FAX:   1-(703)-741-6090 
Toll-free phone: 1-(800)-424-9300 USA only

Product or Trade Name.. SPI #02655-AB, 02655T-AB  NanoplastŪ Resin
Synonyms............... MME 7002;
                        Non-plastified melamine resin;
                        Hexamethylolmelamine methyl ether;
                        Hexamethoxymethylmelamine;
                        N-hexamethylolmelamine hexamethylether;
                        Hexakis(methoxymethyl) melamine




Hazardous
Material
Information System
USA		
Health0
National Fire
Protection
Association
USA		 





Fire Hazard1




Reactivity0




Personal Protection 




NFPA Rating:
(estimated) Health: 0 ; Flammability: 1 ; Reactivity:  0


Section 2: Composition


Component Name              CAS #       Percent     EINECS/ELINCS
Hexamethoxymethylmelamine   3089-11-0   >69%        n/a
Formaldehyde (in MME 7002)  50-00-0     <1%         200-001-8
Water                       7732-18-5   30%         231-791-2


Section 3: Hazard Identification


Emergency overview: Prolonged and continuous exposure may
cause irritation.

Appearance: Colorless aqueous solution

Flash Point: n/a 
 
Potential Health Effects

Eye: May cause eye irritation.

Skin: May cause skin irritation.

Ingestion: No data available.

Inhalation: May cause respiratory tract irritation.


Section 4: First Aid Measures


Eyes: In case of eye contact, flush eyes with water for at
least 15 minutes.  If irritation persists, seek medical attention.

Skin: Wash thoroughly with soap and water after handling. If
irritation persists, seed medical attention.

Ingestion: Seek immediate medical attention.

Inhalation: Remove to fresh air.  If symptoms occur, seek
immediate medical attention.


Section 5: Fire Fighting Measures


Flash Point: 100°C (DIN 53213)
Explosion Limits:
    Upper: n/a
    Lower: n/a
Autoignition Temperature: n/a
 
General Information:
In general, use the extinguishing media suitable for the surrounding
fire since realistically, this product is present only in small
quantities.  

Extinguishing Media:
Water spray, foam, dry media, carbon dioxide

Hazardous Combustion Products:
Nitrogen compounds


Section 6: Accidental Release Measures


General Information:
Absorb with a wet cloth and place in special container for disposal.

Spills/Leaks: 
Do not dispose of into sink, as product is water soluble.


Section 7: Handling and Storage


Handling:
Local ventilation, safety goggles, and protective gloves recommended.

Storage:
Store at room temperature.


Section 8: Exposure Controls and Personal Protection


Engineering Controls: Local ventilation recommended. Eye
wash station should be available to the work area.

Exposure Limits:

Chemical Name     ACGIH           NIOSH           OSHA - Final PELs
CAS# 3089-11-0    n/a             n/a             n/a
CAS# 7732-18-5    n/a             n/a             n/a
CAS# 50-00-0      0.3 ppm TLV     0.016 ppm TWA   0.75 ppm TWA
                  .037 mg/m3 TLV  20 ppm IDHL     2 ppm STEL
                                                  0.5ppm Action Level


OSHA Vacated PELs:
CAS# 50-00-0: 3 ppm TWA

Personal Protective Equipment

Eyes: Chemical safety goggles recommended.

Skin: Protective gloves recommended.

Respirators:
Where conditions warrant use of a respirator, follow the OSHA
respirator regulations found in 29CFR 1910.134 or the European 
Standard EN149. Always us a NIOSH or European Standard approved
respirator when necessary.


Section 9: Physical and Chemical Properties



Physical State:  Liquid
Appearance: clear, colorless
Odor:  n/a
pH:  8
Vapor Pressure:  Not available
Vapor Density:  Not available
Evaporation Rate: Not available 
Viscosity:  Not available
Boiling Point:  Not available
Freezing/Melting Point:  Not available
Autoignition Temperature: Not available
Flash Point: 100°C  (DIN 53213)
Decomposition Temperature:  Not available
Explosion Limits:
	Lower: Not available
	Upper: Not available
Solubility in water:  miscible
Specific Gravity/Density: 1.21 g/ml
Molecular Formula: C15H30N6O6
Molecular Weight:  390


Section 10: Stability and Reactivity


Chemical Stability: Stable

Conditions to Avoid: Heat above 40°C

Incompatibility with Other Materials: Polymerization initiators

Hazardous Decomposition of Products: Nitrogen compounds

Hazardous Polymerization:  May occur


Section 11: Toxicological Information


RTECS#:
    CAS#:   3089-11-0   XZ1065000
    CAS#:   50-00-0     LP8925000
    CAS#:   7732-18-5   ZC0110000

LD50/LC50 Information:
CAS #:3089-11-0
    Oryzias latipes     LC50 = 680 mg/l  
CAS #: 7732-18-5: 
    Oral, rat: LD50 = >90 ml/kg
CAS# 50-00-0:
    Draize test, rabbit, eye: 750 ug Severe
    Inhalation, mouse: LC50 = 505 gm/m3/2H
    Inhalation, rat: LC50 = 578 gm/m3/2H


Carcinogenicity:
CAS# 3089-11-0:
    Not listed by ACGIH, IARC, NTP, OR CA Prop 65
CAS# 7732-18-5:
    Not listed by ACGIH, IARC, NTP, OR CA Prop 65
CAS# 50-00-0:
    ACGIH: A2 - Suspected Human Carcinogen
    California: Carcinogen, Initial date 1-1-88 (gas)
    NTP: Suspect carcinogen
    IARC: Group 1 carcinogen
 

Teratogenicity:
Exposure to Formaldehyde may cause birth defects.

Reproductive Effects:
Exposure to Formaldehyde may cause adverse reproductive effects and
birth defects.  Adverse reproductive effects of Formaldehyde are
primarily based on animal studies.  Very few human studies have
been done on the adverse reproductive effects from exposure to
Formaldehyde. 

Neurotoxicity:
No data available.

Mutagenicity:
Exposure to Formaldehyde may affect genetic material.


Section 12: Ecological Information


Exotoxicity: No data available.

Environmental Fate: No data available.

Aquatic: No data available.

Atmospheric: No data available.

Physical: No data available.


Section 13: Disposal Considerations


RCRA P-Series: None listed. 
RCRA U-Series:
    CAS# 3089-11-0: Not listed.
    CAS# 7732-18-5: Not listed. 
    CAS# 50-00-0: U122

Dispose of in accordance with all federal, state and local regulations.


Section 14: Transport Information

US DOT Hazard Class: Not regulated.

IATA (for international shipments) Not regulated.


Section 15: Regulatory Information


United States:
TSCA
    CAS# 3089-11-0 is listed on the TSCA Inventory
    CAS# 7732-18-5: is listed on the TSCA Inventory.
    CAS# 50-00-0 is listed on the TSCA Inventory.

Health & Safety Reporting List
None of the chemicals in this product are on the Health & Safety
Reporting List.

Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.

Section 12b:
None of the chemicals in this product are listed under TSCA Section 12b.

TSCA Significant New Use Rule:
None of the chemicals in this product has a SNUR under TSCA.

CERCLA:
    CAS# 50-00-0:	100 lb final RQ, 45.4 kg final RQ


SARA:
Section 302 (TPQ)
    CAS# 50-00-0: 500 lb TPQ

SARA Codes
    CAS# 50-00-0: immediate, delayed

Section 313
    This material contains Formaldehyde (CAS# 50-00-0) (36.5-38%)
    which is subject to the reporting requirements of Section 313 of
    SARA Title III and 40 CFR Part 373.

Clean Air Act:
    CAS# 50-00-0 is listed as a hazardous air pollutant (HAP).

This product does not contain any Class 1 or Class 2 Ozone depletors.

Clean Water Act:
CAS# 50-00-0 IS LISTED AS A  Hazardous Substance under the CWA.l
None of the chemicals in this product is listed as Priority Pollutant
or as Toxic Pollutant under the CWA.

OSHA:
CAS# 50-00-0 is considered highly hazardous by OSHA.

State (Individual states in the USA)
CAS# 50-00-0 is present on the California, Massachusetts, Minnesota,
New Jersey and Pennsylvania state lists.


California Prop. 65:
This product contains formaldehyde, which the State of California has
found to cause cancer and which would require a warning under state
statue.
  

European/International Regulations:
European Labeling in Accordance with EC Directives

Hazard Symbols: Xi  Irritant
Risk Phrases:        
    R43: May cause sensitization by skin contact
Safety Phrases:
    S26: Incase of contact with eyes, rinse immediately with plenty 
        of water and seek medical advice
    S37: Wear suitable gloves
    S38: Wear suitable eye/face protection
    S51: Use only in well-ventilated areas

WGK (Water Danger/Protection):
CAS# 3089-11-0: no information available
CAS# 7732-18-5: no information available
CAS# 50-00-0: 2

Canada - DSL/NDSL
    CAS# 3089-11-0 is on the DSL List
    CAS# 7732-18-5 is listed on Canada's DSL List
    CAS# 50-00-0 is listed on Canada's DSL List



WHMIS classification: B3


Section 16: Other Information


Disclaimer of Liability:

Caution!  Do not use SPI Supplies products or materials in applications 
involving implantation within the body; direct or indirect contact with 
the blood pathway; contact with bone, tissue, tissue fluid, or blood; or 
prolonged contact with mucous membranes.  Products offered by SPI Supplies 
are not designed or manufactured for use in implantation in the human body 
or in contact with internal body fluids or tissues.  SPI Supplies will not 
provide to customers making devices for such applications any notice, 
certification, or information necessary for such medical device use 
required by US FDA (Food and Drug Administration) regulation or any 
other statute. SPI Supplies and Structure Probe, Inc. make no representation, 
promise, express warranty or implied warranty concerning the suitability of 
these materials for use in implantation in the human body or in contact with 
internal body tissues of fluids. This product is intended for external contact 
only with human skin.

************************************************************************


The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.

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Tuesday May 22, 2012
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