Information System
USA
Protection Association
USA
SPI-Chem™ SPI Supplies Division
Date Effective... March 30, 2006
(most recent revision)
Chemical Name/Synonyms... 2-pyrrolidinone, 1-ethenyl-, homopolymer
polyvinylpyrrolidone
Chemical family.......... Not known
Emergencies Contacting CHEMTREC 24 Hour Emergency
Use Only #'s.... Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #02652-AB PVP K-90
CAS #.................... 00009003-39-8
Chemical Formula......... (C6H9NO)x
| Hazardous
Material Information System USA | Health | 1 | National Fire Protection Association USA | |
| Fire Hazard | 0 | |||
| Reactivity | 0 | |||
| Personal Protection |
Component Name CAS # OSHA OSHA ACGIH ACGIH Carcinogenic
PEL STEL TLV STEL
None
Emergency overview:
Off-white powder, no known hazards.
This material is not hazardous by OSHA Hazard Communication
Definition
Oral Toxicity:
Rat LD50 > 100,000 mg/kg
Dermal Toxicity:
Not absorbed topically
Inhalation toxicity:
Human, guinea pig and rabbit; exposure to aerosols and dusts of small
particle size produced no evidence of harmful effects.
Skin irritation:
Human repeat insult patch test; not a primary irritant.
Eye irritation:
Rabbit; no irritation observed.
Sensitizer:
No. Human repeat insult patch test; not a sensitizer.
US DOT Corrosive:
No data found.
Primary routes of entry:
Contact
Signs and Symptoms of Exposure
Symptoms of ingestion:
No effects of exposure expected.
Symptoms of inhalation:
No effects of exposure expected
Symptoms of skin contact:
No effects of exposure expected due to absorption or contact. May possibly
cause irritation or dermatitis in some individuals upon prolonged contact.
Symptoms of eye contact:
No effects of exposure expected with the exception of possible irritation.
Medical conditions aggravated by exposure:
No data found
Other Toxicity:
Other accute toxicity:
No data found
Sub chronic oral toxicity:
Rodent and dog studies: No adverse effect level exceeds 10% of total diet;
no evidence of carcinogenic activity.
Sub chronic inhalation toxicity:
No data found.
Sub chronic miscellaneous toxicity:
No data found
Aquatic toxicity:
No data found
Tumorigenicity:
Chronic rodent and dog feeding studies show that the no adverse effect level
exceeds 10% of the diet with no evidence of carcinogenic activity.
Mutagenicity:
PVP was tested in the Ames Assay; dominant lethal test on mice: L5178Y Mouse
(TK +/-) Lymphoma assay; bone marrow chromosomal abberation assay; and the
BALB/C3T3 transformation. In each case PVP was found not to be metagenic.
Reproductive toxicity:
Teratology studies with PVP concentrations up to 10% of the diet show no
embryotoxicity, petotoxicity or teratogenicity.
Miscellaneous toxicity:
No data found.
First Aid for Ingestion: General precautionary measures suggest inducing vomiting immediately by giving two glasses of water and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician. First Aid for inhalation: None required. First aid for skin contact: For all foreign materials, wash after exposure. First aid for eye contact: For all foreign materials, immediately flush eyes with plenty of water.
Flash point: No flash point Autoignition temperature: No data found Flammable limits: No data found Firefighting media: Use media proper to primary cause of the fire. Special firefighting procedures: None known. Fire/Explosion hazards: None known.
Release response: Scoop up spilled material. Avoid dusting. Dispose of with solid waste according to federal, state ,and local regulations. Flush spill area with water. US EPA Hazardous Substance Reportaable Quantity: Not listed
Precautionary measures: Avoid breathing dust Disposal method: Dispose of with solid waste according to federal, state, and local regulations. RCRA Class: Not regulated
Ventilation: General precautionary measures suggest use with adequate ventilation. Respiratory protection: Dust mask where dust cannot be avoided. Eye protection: Safety glasses Skin protection: None required Personal hygiene: Observe ordinary measures of personal hygiene. Protective measures during repair/maintenance of equipment: Wash equipment thoroughly with steam or warm water until clean. Check for flammables with an "explosion meter" and also check the oxygen level with an oxygen meter. In all cases, follow good industrial safety practices before entering equipment. Exposure limits: Nuisance dust: TLV: TWA 10 mg/m3; Total 5 mg/m3 respirable.
Boiling Point/Range: No data found
pH of Solution: 3.00 to 9.00 (5% solution)
Vapor Pressure: Not volatile
Viscosity: Not applicable
Specific Gravity:
Solid/Liquid: No data found
Vapor: Not applicable
Water solubility: Complete
Octanol/Water Partition Coefficient in Kow: Specific value not known
Melting/Freezing Point: No data found
Evaporation Rate: Not applicable
Chemical Stability: The product is stable Conditions to Avoid: None known Incompatibility with: Strong oxidizing or reducing agents Hazardous Products of Deposition: Toxic fumes of NOx emitted when heated to decomposition. Reactions with Air and Water: Does not react with air, water or other common materials.
Domestic USA: DOT Shipping Name: Not regulated DOT Hazard Class: Not regulated Hazardous Ingredients(s): None Export (from USA): Export Shipping Name: Not regulated Export Hazard Class: Not regulated Hazardous Ingredients(s): None UN Number: None
Exotoxicity: Not known Environmental Fate: No information found in our selected references. Bioaccumulation: Not expected to occur.
This material is NOT classified as a hazardous material by RCRA. Use only licensed transporters and permitted disposal facilities and conform to all laws. Recycle to process, if possible.
Proper Shipping Name: Not regulated DOT Hazard Class: Non-Regulated UN/NA ID: Not Regulated Packing Group: Not Applicable Labels: Not Regulated Marine Pollutant: No NAER Guidebook: Not Regulated DOT Status: Not Regulated
TSCA: All components of this product are listed on the TSCA 8(b)
inventory. If identified components of this product are listed under
the TSCA 12(b) Export Notification Rule, they will be listed below.
TSCA 12(b) Component Listed under TSCA Section
SARA-Section 313 Emissions Reporting:
Component Reporting Threshold
SARA-Section 311/312: No components present in this product are
subject to the reporting requirements of this statute.
CERCLA Hazardous Substances and their Reportable Quantities:
Component Reportable Quantity
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer
products into the State of California to provide a warning statement
if the product contains ingredients for which the State has found to
cause cancer, birth defects or other reproductive harm. If this product
contains an ingredient listed by the State of California to cause cancer
or reproductive toxicity, it will be listed below:
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.********************************************************************** The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation.
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