Information System
USA
Protection Association
USA
SPI Supplies Division
Date Effective........... January 8, 2009
(most recent revision)
Chemical Name/Synonyms...
Toluidine Blue O;
CI Basic Blue 17;
3-Amino-7-(dimethylamino)-2-methylphenothiazin-5-ium Chloride;
Tolonium Chloride
Chemical Family... Not known
Emergencies Contacting CHEMTREC 24 Hour Emergency
Use Only #'s.... Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #02576-AB/02576-MB SPI-Chem™
Toluidine Blue O
CAS #.................... 92-31-9
EINECS No................ 202-146-2
Chemical Formula......... C15H16N3SCl
RTECS#: SP5670000
| Hazardous
Material Information System USA | Health | 1 | National Fire Protection Association USA | |
| Fire Hazard | 0 | |||
| Reactivity | 0 | |||
| Personal Protection | 0 |
Ingredient 1: Toluidine Blue O Stains Grade > 98%
Emergency overview:
This material is not hazardous by OSHA Hazard Communication
Definition.
Signal Word(s):
Harmful! Irritant!
Main Hazards:
Harmful by inhalation, in contact with skin, and if swallowed. Irritating to
eyes, respiratory system and skin.
Physical Health Hazards:
Dry dust may form respirable particulates if disturbed.
If this material gets into the eyes, it could be irritating.
Material could be irritating if the dust is inhaled. Could
also be irritating if skin is exposed to the dry powder.
Physical state: Dry powder
Color: dark green
Odor: None
Odor threshold: No data available
Potential Health Effects:
Routes of exposure:
Eye contact, ingestion, skin contact
Signs and Symptoms of Acute Exposure:
This material if used properly, should not pose any kind of real
hazard. If the material is used improperly, for example, if the
dust is inhaled, it could be very irritating to the respiratory
tract.
Eye contact:
Mechanical irritation is possible; can be irritant.
Ingestion:
Ingestion is unlikely, but if it does occur, material could
be expected to be an irritant. Drink one pint of water after
rinsing out mouth first. Try to prevent vomiting. Never give
anything to an unconscious person. Seek immediate medical
attention.
Symptoms:
Skin contact:
There may be irritation and redness at the site of contact. An itchy rash may
occur at the site of contact.
Eye contact:
There may be irritation and redness.
Ingestion:
Nausea and stomach pain may occur. There may be vomiting.
Inhalation:
Nausea and stomach pain may occur.
Action:
Skin Contact:
Remove all contaminated clothes and footwear immediately unless stuck to skin.
Drench the affected skin area with running water for ten minutes or longer if
substance is still on skin. Transfer to hospital if there are burns or
symptoms of poisoning.
Eye Contact:
Wash eyes with clean low-pressure water. Continue to rinse for 15 minutes.
Seek medical advice for examination and possible further treatment of the
affected eye(s).
Ingestion:
If product is swallowed, first rinse out mouth several times to remove material
from mouth and to keep more from being swallowed. Give one pint of water. Do
not induce vomiting. If unconscious and breathing is OK, place in the recovery
position. Seek medical attention at once.
Inhalation:
Remove victim from further exposure ensuring your own safety first. If
unconscious, and check for breathing and apply artificial respiration if
necessary. If unconscious and breathing is OK, place in the recovery
position. If conscious, ensure the victim sits or lies down. Seek immediate
medical attention.
Extinguishing Media: Use any suitable medium for extinguishing the supporting fire. Use water to keep fire-exposed containers cool. For fire specifically involving this product, use dry foam, dry chemical powder, polymer foam, CO2, sand, or earth to extinguish the fire. Exposure Hazards: In combustion emits toxic fumes. Protection of Fire-Fighters: Protective Equipment/Clothing: Wear a NIOSH approved positive pressure self-contained breathing apparatus and firefighter turnout gear. This should be selected on the basis of the supporting fire. Avoid having the fumes come in contact with skin and eyes.
See Sections 8 and 13. Personal precautions: Do not attempt to take action without suitable protective clothing. Do not create dust so that there are air borne particulates that could be inhaled. Environmental precautions: Do not discharge into drains, rivers, or lakes. Release response: Pick up with dry cloth or sweep up and retain for recycle or disposal. Do not flush spilled material to the sewer or the environment. Waste materials should be put into a labeled disposal container for disposal according to local regulations.
Handling: Use in well ventilated areas. Wear suitable gloves if prolonged exposure is contemplated. Avoid direct contact with the material. Storage: Store away from excessive heat and generally in a cool dry place. Keep container tightly closed. Keep away from direct sunlight. Avoid contact with water or humidity.
Engineering measures: Ensure that there is mechanical ventilation of the area. Respiratory protection: Use respiratory protective device with particle filter. Self-contained breathing apparatus must be available in case of emergency. Use NIOSH/MSHA or European Standard EN 149 approved respirator where needed. Hand protection: Use protective gloves to prevent skin exposure Eye protection: Use Chemical Safety goggles. Ensure eye bath is readily available. Skin protection: Use protective clothing with elastic cuffs and closed neck. Boots should be made of PVC. The product does not present a significant hazard in normal laboratory use as a light microscope stain. The data provided above refer to prolonged contact with large quantities of product.
Boiling Point/Range: Not applicable
pH: Not applicable
Vapor Pressure: Not known/not applicable
Viscosity: Not applicable
Specific Gravity:
Solid/Liquid Not known
Water solubility: Soluble
Ethanol solubility: Soluble
Octanol/Water Partition Coefficient in Kow: Specific value not known
Melting/Freezing Point: Not known
Evaporation Rate: Not applicable
Odor: None
Appearance and Physical State: dark green powder
Chemical Stability:
The product is stable under normal use conditions.
Conditions to Avoid:
Excessive heat, sunlight, humidity
Incompatibility (materials to avoid):
Strong oxidizing agents
Hazardous Products of Deposition:
In combustion, the material emits toxic fumes of Carbon monoxide,
Carbon dioxide, Hydrogen chloride, Nitrogen oxides, Sulfur oxides
Reactions with Air and Water:
Does not react with air, water or other common materials.
Effects of exposure: Watering of the eyes. Nausea. CAS# 92-31-9 is not listed as a carcinogen by ACGIH, IARC, NTP, OR California Prop. 65. LD50/LC50: No data available
None available from our selected sources.
Waste disposal: Arrange for collection by an approved hauler, following federal, state and local regulations. Another option, assuming it is legal to do so where you are located: Mix or dissolve the material with a combustible material and burn in a chemical incinerator equipped with afterburners and scrubbers. Disposal of packaging: Arrange for disposal following all federal, state, and local regulations. Clean first with water and the waste water should be discarded as a normal industrial waste, following all federal, state and local rules and regulations. RCRA P-Series: Not listed RCRA U-Series: Not listed
This product is not classified as dangerous.
DOT Hazard Class: Non-Regulated
UN/NA ID: Not Regulated
Packing Group: Not Applicable
Labels: Not Regulated
Marine Pollutant: No
NAER Guidebook: Not Regulated
DOT Status: Not Regulated
This preparation not classified as dangerous under The Chemical
(Hazard Information and Packaging Regulations) 1994 No.3247 or
Council Directive 88/379/EEC of 7 June 1988 relating the Classification,
Packaging and Labeling of Dangerous preparations.
The following safety phrases are appropriate:
Keep out of reach of children.
Avoid contact with skin and eyes.
If swallowed seek medical advice immediately and show this container or
label.
TSCA:
All components of this product are listed on the TSCA 8(b) inventory.
If identified components of this product are listed under the TSCA 12(b)
Export Notification Rule, they will be listed below.
TSCA 12(b) Component Listed under TSCA Section
SARA-Section 313 Emissions Reporting:
Component Reporting Threshold
SARA-Section 311/312:
No components present in this product are subject to the reporting
requirements of this statute.
CERCLA Hazardous Substances and their Reportable Quantities:
No components present in this product are subject to the reporting requirements
of CERCLA.
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer products
into the State of California to provide a warning statement if the product
contains ingredients for which the State has found to cause cancer, birth defects
or other reproductive harm. If this product contains an ingredient listed by the
State of California to cause cancer or reproductive toxicity, it will be listed
below:
No components are found in this product.
European Regulations:
Hazard symbols:
Harmful, irritant
Risk phrases:
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety phrases:
S22: Do not breathe dust.
S26: In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or you do not feel well, seek medical advice immediately.
WGK:
CAS# 62-31-9: not available
CANADA:
WHMIS
CAS# 92-31-9 has a WHMIS classification of D2B.
DSL/NDSL:
CAS# 92-31-9 is listed on the DSL List.
CAS# 92-31-9 is not listed on the NDSL List.
NOTE: n/a= Not available
If this product should be used in ways that are outside of the intended applications in scanning electron microscope laboratories, and if it is going to be formulated into some other system, so that it becomes just another component of that other system, read the MSDS sheets for the other components before blending as the resulting mixture may have the hazards of all of its parts.
Disclaimer of Liability:
Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute.
SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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