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Date Effective........... February 17, 2007
(most recent revision)
Trade Name............... Phloroglucinol Stain
Chemical Name/Synonyms... Acid-Phloroglucinol Stain
Chemical family.......... Not known
Manufacturer:
Integrated Paper Services
101 West Edison Ave,
Suite 250
Appleton, WI 54912
Phone: 1-(920)-749-3040
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s......
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #02513-AB Phloroglucinol Stain
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH OSHA
TLV STEL PEL STEL IDLH OTHER
Phloroglucinol 6099-90-7 < 1 NE NE NE NE NE NE
Dihydrate
Methyl Alcohol 67-56-1 20-30 200 ppm 250 ppm 200 ppm 250 ppm 25000 ppm NIOSH REL:
200 ppm (TWA)
250 ppm (STEL)
Hydrochloric Acid 7647-01-0 35-45 5 (C) NE 5 (C) NE 100 ppm NIOSH REL: 5 C
Water 7732-18-5 Balance NE NE NE NE NE NE
NE = Not Established C = Ceiling Level See Section 16 for Definitions of
Terms Used.
Hazardous
Material
Information System
USA Health
3 National Fire
Protection
Association
USA 
Fire
Hazard 2
Reactivity 0
Personal
Protection
NFPA Rating:
Health Flammability Reactivity Other
3 2 0 Corrosive
Emergency overview: This is a clear, colorless solution with an alcohol-like odor which is corrosive and can irritate or burn contaminated tissue. The product is combustible. Products of decomposition will include irritating vapors and toxic gases (carbon monoxide, carbon dioxide, hydrogen chloride). Symptoms of Over-Exposure by Route of Exposure: This solution can be very irritating to contaminated skin, eyes, mucous membranes, and contaminated tissue. Inhalation: If mists or sprays of this solution are inhaled, this product may cause pulmonary irritation, irritation of the mucus membranes, coughing, and a sore throat. Inhalation of large amounts of this solution may cause headaches, coughing, difficulty in breathing, lung irritation, and pulmonary edema. Inhalation of vapors may also affect the central nervous system. Contact with skin, or eyes: Contact with the eyes will cause irritation, pain, and reddening. Prolonged contact may cause blindness. Skin contact may cause reddening, discomfort, and irritation. Prolonged skin contact may cause burns. Other effects which may occur after ingestion include nausea, vomiting, gastrointestinal irritation, burns to mouth and throat. Injection: Accidental injection of this product, via laceration or puncture by a contaminated object may cause pain and irritation in addition to the wound. Health Effects or Risks from Exposure: An Explanation in Lay Terms. In the event of exposure, the following symptoms may be observed: ACUTE: This solution is irritating to eyes, skin, mucous membranes, and any other exposed tissue. If inhaled, irritation of the respiratory system may occur, with coughing, and breathing difficulty. Prolonged exposures may result in burns. CHRONIC: Persistent irritation may result from repeated exposures to this solution. Long-term exposures to relatively high doses of this solution may lead to liver, kidney, or lung damage.
Skin Exposure: If spilled on skin, immediately begin decontamination with running water. Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention. Eye Exposure: If chemical is splashed in eyes, open victim's eyes while under gentle running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Inhalation: If chemical is inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers. Ingestion: If chemical is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Rinse mouth with water immediately. Victim should drink milk, egg whites, or large quantities of water. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if necessary. Take copy of label and MSDS to physician or health professional with victim.
Flash Point, °C (method): For Methanol, 11°C.
Auto-Ignition Temperature, °C: 440°C (for Methanol).
Flammable Limits (in air by volume, %):
Lower (LEL): 6.0 (Methanol)
Upper (UEL): 36.5 (Methanol)
Fire Extinguishing Materials:
Water Spray: YES Carbon Dioxide: YES Foam: YES
Dry Chemical: YES Halon: YES Other: Any "ABC" Class.
Unusual Fire and Explosion Hazards:
When involved in a fire, this material may decompose and produce
irritating vapors and toxic gases (i.e. carbon monoxide, carbon dioxide).
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Though this material
does contain acetic acid, (which is a combustible material), because
of the dilute concentration, this product should not be sensitive to
static discharge. However, precaution should still be taken to avoid
exposing the product to static electrical energy.
Special Fire-Fighting Procedures: Incipient fire responders should
wear eye protection. Structural fire fighters must wear
Self-Contained Breathing Apparatus and full protective equipment.
If this product is involved in a fire, fire run-off water should be
contained to prevent possible environmental damage.
Spill and Leak Response: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a large spill, clear the affected area, protect people, and respond with trained personnel. In the event of a release where sprays or mists may be generated during clean-up, minimum Personal Protective Equipment should be Level C: triple-gloves (rubber gloves and nitrile gloves, over latex gloves), chemically resistant suit and boots, hard-hat, and Air-Purifying Respirator (with Acid Gas/ Particulate Filter). Use supplied air respiration protection during response procedures to non-incidental releases in which oxygen levels are below 19.5%. Absorb spilled liquid with polypads or other suitable absorbent materials. Neutralize residue with sodium bicarbonate or other acid-neutralizing solution. Decontaminate the area thoroughly. Place all spill residue in a double plastic bag and seal. Dispose of in accordance with Federal, State, and local hazardous waste disposal regulations (see Section 13).
Work Practices and Hygiene Practices: Avoid getting this product ON YOU or IN YOU. Wash hands after handling chemicals. Do not eat or drink while handling this solution. All work practices should minimize the generation of splashes and aerosols. Storage and Handling Practices: All employees who handle this material should be trained to handle it safely. Avoid breathing sprays or mists generated by this product. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store containers in secondary containment, away from caustic compounds. Keep container tightly closed when not in use. Wash thoroughly after using this material. Workers must be thoroughly trained to handle this product without causing over-exposure. Protective Practices During Maintenance of Contaminated Equipment: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out safely. Always use this product in areas where adequate ventilation is provided. Decontaminate equipment using sodium bicarbonate or another acid-neutralizing agent, followed by a triple-rinse with water, before maintenance begins. Collect all rinsates and dispose of according to applicable Federal, State, or local procedures.
Ventilation and Engineering Controls: Use with adequate ventilation. Use a mechanical fan or vent area to outside. Respiratory Protection: Maintain airborne contaminant concentrations below guidelines listed in Section 2. If respiratory protection is needed (i.e. Air-Purifying Respirator with Acid Gas/Particulate Filter), use only protection authorized in 29 CFR 1910.134, or applicable State regulations. Use supplied air respiration protection during response procedures to non-incidental releases in which oxygen levels are below 19.5%. Eye Protection: Splash goggles or safety glasses. Face shield should be worn when working with solutions over 1 gallon in volume. Hand Protection: Wear Neoprene Rubber or Vinyl gloves for routine industrial use. Use triple gloves for spill response, as stated in Section 6 of this MSDS. Body Protection: Use body protection appropriate for task. An apron, or other impermeable body protection is suggested. Full-body chemical protective clothing is recommended for emergency response procedures.
Vapor Density: Approximately equal to water.
Evaporation Rate (n-BuAc=1): Slightly faster than water.
Specific Gravity: Not available.
Melting Point or Range: < 0°C
Solubility in Water: 100% soluble.
Boiling Point: > 100 °C
Vapor Pressure, mm Hg @ 20 °C: Approximately 18 pH: < 1
Appearance and Color: This product is a clear-colorless solution
with an alcohol-like odor.
How to Detect this Substance (warning properties):
Litmus-paper will turn red upon contact with this solution.
Stability: Stable.
Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen chloride. Materials with which Substance is Incompatible: Strong bases, strong oxidizers, and water-reactive materials. Hazardous Polymerization: Will not occur. Conditions to Avoid: Contact with incompatible materials.
Toxicity Data:
Additional toxicology information for components greater than
1 percent in concentration are provided below.
Methanol:
Primary Irritant Test (skin, rabbit) 500 mg/24 hr, moderate
Primary Irritant Test (eye, rabbit) 40 mg, moderate
DNA Inhibition Test (human, lymphocyte) 300 mmol/L
Microsomal Mutagenicity Assay (mouse, lymphocyte) 7900 mg/L
TDLo(oral, rat) 7500 mg/kg; reproductive effects
TCLo(inhalation, rat) 10000 ppm/7 hr, teratogenicity effects
LDLo(oral, man) 6422 mg/kg
TDLo(oral, man) 3429 mg/kg; eye effects
LDLo(oral, human) 428 mg/kg
LDLo(oral, human) 143 mg/kg
TDLo(oral, woman) 4000 mg/kg; eye, pulmonary, gastrointestinal effects
TCLo(inhalation, human) 86000 mg/m3
TCLo(inhalation, human) 300 ppm; eye, central nervous system,
pulmonary effects
LD50(oral, rat) 5628 mg/kg
LC50(inhalation, rat) 64000 ppm/4 hr
LD50(oral, mouse) 7300 mg/kg
LD50(intraperitoneal, mouse) 10765 mg/kg
LD50(subcutaneous, mouse) 9800 mg/kg
LD50(intravenous, mouse) 4710 mg/kg
LDLo(oral, monkey) 7000 mg/kg
LCLo(inhalation, monkey) 1000 ppm
LDLo(skin, monkey) 393 mg/kg
Hydrochloric Acid:
LD50 (oral-rabbit) = 900 mg/kg.
LC50 (inhalation-rat) = 4701 ppm for 30 minutes; 5666 ppm for 30 minutes.
LC50 (inhalation-mouse) = 2644 ppm for 30 minutes; 2142 ppm for 30 minutes.
Suspected Cancer Agent:
The components of this solution are not found on the following lists:
FEDERAL OSHA Z LIST, NTP, IARC, CAL/OSHA.
Irritancy of Product:
This product is irritating to contaminated tissue, especially
after prolonged contact.
Reproductive Toxicity Information:
Listed below is information concerning the effects of this
product and its components on the human reproductive system.
Mutagenicity:
This product is not expected to produce mutagenic effects in
humans; however, clinical studies with animals exposed to
relatively high doses of Methanol have produced mutagenic effects.
Teratogenicity:
This product is not expected to cause teratogenic effects in
humans; however, clinical studies with animals exposed to
relatively high doses of Methanol have produced mutagenic effects.
Reproductive Toxicity:
This product is not expected to cause reproductive toxicity
effects in humans; however, clinical studies with animals exposed
to relatively high doses of Methanol have produced adverse
reproductive effects.
Medical Conditions Aggravated by Exposure:
Pre-existing dermatitis may be aggravated by over-exposure to this
product. Additionally, pre-existing kidney, lung, and liver conditions
may be aggravated by repeated exposures to relatively high doses of
this solution.
Recommendations to Physicians:
Monitor for shock, treat symptoms and reduce over-exposure.
Environmental Stability: This product will decompose to release organic and inorganic compounds. Effect of Material on Plants or Animals: Due to the corrosive properties of this solution, this product can be harmful to plant and animal life if released into the environment. All work practices must minimize potential or actual releases to the environment. Effect of Chemical on Aquatic Life: Due to the corrosive properties of this solution, this product can adversely affect aquatic environments if large quantities are released into water. All work practices must minimize potential or actual releases to the environment.
Preparing Wastes for Disposal: Waste disposal must be in accordance with appropriate Federal, State, and local regulations. This solution, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. Discharge into a sanitary sewer or storm drain may violate local ordinance for color or solids. EPA Waste #: D001 (Ignitable), D002 (Corrosive), applicable to wastes consisting only of this solution.
THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S.
DEPARTMENT OF TRANSPORTATION.
Proper Shipping Name: Corrosive Liquids, Flammable, n.o.s.
(Hydrochloric Acid, Methanol)
Hazard Class Number and Description: 8 (Corrosive)
UN Identification Number: UN 2920
Packing Group: II
DOT Label(s) Required: Corrosive, Flammable Liquid
Emergency Response Guide Number: 29
Marine Pollutant:
This product does not contain any components which are designated
by the Department of Transportation to be Marine Pollutants
(49 CFR 172.101, Appendix B).
Small Quantity Exception:
When shipped by surface, in 30ml or smaller bottles, this material
may qualify for Small Quantity exceptions to US DOT packaging,
labeling, and marking requirements as specified in 49 CFR 173.4.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
THIS MATERIAL IS CONSIDERED AS DANGEROUS GOODS. Refer to information
above for Canadian Shipments.
SARA REPORTING REQUIREMENTS:
This product is subject to the reporting requirements of
Section 302, 304 and 313 of Title III of the Superfund
Amendments and Reauthorization Act., as follows:
COMPONENT SARA 302 SARA 304 SARA 313
Phloroglucinol Dihydrate NO NO NO
Methanol NO YES YES
Hydrochloric Acid YES YES YES
SARA Threshold Planning Quantify: Hydrochloric Acid = 500 lbs.
TSCA Inventory Status:
All components of this solution are listed on the TSCA Inventory.
CERCLA Reportable Quantity (RQ): Methanol = 5000 lb;
Hydrochloric Acid = 5000 lbs.
State Regulatory Infomation:
The components of this solution (greater than 1 percent in concentration)
are covered the specific State regulations, as denoted below.
Alaska - Designated Toxic and Hazardous Substances: Methanol
California - Permissible Exposure Limits for Chemical
Contaminants: Hydrochloric Acid, Methanol
Florida - Substance List: Hydrochloric Acid, Methanol
Illinois - Toxic Substance List: Hydrochloric Acid
Kansas - Section 302/313 List: Hydrochloric Acid, Methanol
Massachusetts - Substance List: Hydrochloric Acid, Methanol
Minnesota - List of Hazardous Substances: Methanol
Missouri - Employer Information/Toxic Substance List: None
New Jersey - Right to Know Hazardous Substance List: Methanol
North Dakota - List of Hazardous Chemicals, Reportable
Quantities: Hydrochloric Acid, Methanol
Pennsylvania - Hazardous Substance List: Hydrochloric Acid, Methanol
Rhode Island - Hazardous Substance List: Hydrochloric Acid, Methanol
Texas - Hazardous Substance List: Methanol
West Virginia - Hazardous Substance List: Methanol
Wisconsin - Toxic and Hazardous Substances: Methanol
CALIFORNIA PROPOSITION 65: No component of this solution is on the
California Proposition 65 lists. LABELING (Precautionary Statements):
DANGER! Corrosive. Contact with splashes, sprays, and mists of this
product can cause irritation, reddening, and burns. Avoid direct contact
with this product. Do not ingest, inhale, swallow, or allow skin contact
with this product. Keep away from foodstuffs. Keep in closed container,
in a cool, dry location. Avoid contact with strong bases and strong
oxidizers. If spilled on skin or in eyes, rinse immediately with running
water for at least 15 minutes. If inhaled, provide fresh air. Seek
Medical attention. Consult Material Safety Data Sheet.
Target Organs: Central nervous system, respiratory system, skin, eyes.
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