SPI Supplies Division|
|
Date Effective........ January 8, 2009
(most recent revision)
Synonyms..............
Phosphoric acid, 2-ethylhexyl ester, sodium salt
Product Use: Surfactant/wetting agent
Chemical family....... Salt of alkyl acid phosphate
Chemical formula...... Mixture
Emergencies
Contacting CHEMTREC 24 Hour Emergency
Use Only #'s.......... Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300
Product or Trade Name.... Victawet 35B
CAS #: 68334-32-7 Polyphosphoric acids, 2-ethylhexyl esters, sodium salts
141-65-1 Phosphoric acid, bis(2-ethylhexyl)ester, sodium salt
7732-18-54 Water
Chemical Formula......... Mixture
Product Use.............. Surfactant/wetting agent
| Hazardous
Material Information System USA | Health | 2 | National Fire Protection Association USA |  |
| Fire Hazard | 1 | |||
| Reactivity | 0 | |||
| Personal Protection |
Substance Description % CAS# EC# Polyphosphoric acids, 2-ethylhexyl) esters, sodium salts 10-25 68334-32-7 269-823-2 Phosphoric acid, bis(2-ethylhexyl) ester, sodium salt 5-10 141-65-1 205-493-8 Water 20-25 7732-18-5 231-791-2
Appearance and Odor:
Light tan colored paste.
Statement of Hazards
Warning!
Causes eye irritation.
May cause eue and respiratory tract irritation.
Avoid Contact with Skin or Clothing
Avoid breathing vapor, mist, aerosol, or fumes
Keep container tightly closed
Use with adequate ventilation
Wash thoroughly after handling
Fire and Explosion Hazards
This product is not defined as flammable or combustible.
However, it may decompose under fire conditions to give
off toxic materials such as phosphorus oxides and flammable
organic substituents. The product is self-extinguishing
once the source of ignition is removed.
Primary Route of Exposure
Skin contact, eye contact and inhalation are the primary routes of
exposure to this product.
Inhalation Acute Exposure
Inhalation of fumes or vapors is irritating to the upper respiratory
system.
Skin Contact - ACUTE
Skin contact may cause severe irritation.
Eye Contact - ACUTE
Eye contact may cause mild irritation.
Ingestion - ACUTE
Irritation to the mouth, throat, esophagus and stomach may be caused
by ingestion of this material.
Carcinogenicity:
IARC: No
NTP: No
OSHA: No
AGCIH: No
Inhalation First Aid
If inhaled, remove victim to fresh air. If not breathing, give
artificial respiratory. If breathing becomes difficult, give oxygen
and get medical attention.
Skin Contact - First Aid
Immediately remove contaminated clothing and shoes. Flush skin with
plenty of soap and water for at least 15 minutes. Do not attempt
to neutralize with chemical agents. Get medical attention immediately.
Wash contaminated clothing before reuse. Thoroughly clean or destroy
contaminated shoes.
Eye Contact - First Aid
Immediately flush eyes with large quantities of running water for
a minimum of 15 minutes. If the victim is wearing contact lenses,
remove them. Hold the eyelids apart during the flushing to ensure rinsing
of the entire surface of the eye and lids with water. DO NOT let the victim
rub eyes(s). Do not attempt to neutralize with chemical agents. Oils or
ointments should not be used at this time. Get medical attention if eye
irritation occurs.
Ingestion - First Aid
Get medical attention by calling a physician or a poison control
center immediately. Give victim plenty of water to drink. Do not
induce vomiting unless directed to do so as directed by medical
personnel. Never give anything by mouth to an unconscious or
convulsing person. If vomiting occurs, keep head below hips to
reduce risk of aspiration. Get medical attention immediately.
Medical Conditions Aggravated
Persons with pre-existing skin disease may be at an increased risk
if exposed dermally to this material.
Note to Physician
Attending physician should treat exposed patients symptomatically.
Flash Point
93°C (199.4°F) Cleveland Open Cup
Auto Ignition Temperature:
No data available
Upper Explosion Limit:
No data available
Lower Explosion Limit:
No data available
Extinguishing Media
Use water fog, dry powder, foam or carbon dioxide extinguishing agents.
Fire Fighting Procedures:
As in any fire, prevent human exposure to fire, smoke,
fumes or products of combustion. Evacuate non-essential
personnel from the fire area. Fire fighters should wear
full-face, self-contained breathing apparatus and impervious
protective clothing.
Contaminated buildings, areas and equipment must not be used
until they are properly decontaminated. Dike fire water for
later disposal. Do not allow contaminated water to enter
waterways.
Fire and Explosion Hazards
This product is not defined as flammable or combustible.
However, it may decompose under fire conditions to give off
toxic materials such as phosphorous oxides and flammable organic
substituents. The product is self- extinguishing once the source
of ignition is removed.
Other Fire and Explosion Hazards
No other explosion hazards of this product are known.
Hazardous Products/Combustion
Under fire conditions this product may support combustion and
decompose to give off flammable alkene and phosphoric oxides as
well as carbon oxides. The product is self-extinguishing once
the source of ignition is removed. It is not sensitive to static
discharge.
Personnel-related safety precautions:
Restrict nonessential personnel. Follow appropriate
industrial hygiene practices as outlined in Section 8.
Clean up:
Stop source of spill. Dike area to prevent spill from
spreading. Soak up liquid with suitable absorbent such
as clay, sawdust, or kitty litter. Sweep up absorbed
material and place in a chemical waste container for
disposal. CAUTION! The spill area may be slippery.
With a stiff brush, work a slurry of powdered household
detergent and water into surface, including all cracks
and crevices. After allowing to stand for 2-3 minutes,
flush with water. Dike the water for later disposal.
Do not allow contaminated water to enter waterways or sewers.
Section 7: Handling and Storage
Handling:
Keep away from heat, sparks, and open flames. Avoid contact with skin.
Avoid inhalation of vapors and mists. Personnel handling this product
should wash thoroughly after contact with this product.
Storage:
Store away from foodstuffs or animal feed. Containers should
be stored in a cool, dry, well-ventilated area away from
flammable or incompatible materials and sources of heat or
flame. Exercise due caution to prevent damage to or leakage
from the container.
To prevent acid build-up, do not store the product at
temperatures above 49°C (120°F). This product is normally
shipped in polyethylene lined fiber cartons.
Maximum Storage Temperature:
48.88°C (120°F)
General comments:
Containers should not be opened until ready for use.
Engineering Controls:
Safety shower and eye wash station must be available to work area.
Respiratory Protection:
Use a NIOSH-approved organic vapor acid gas respirator
(OVAG) with dust , mist, and fume filters to reduce
potential for inhalation exposure if use conditions
generate vapor, mist, or aerosol and adequate ventilation
(e.g., outdoor or well ventilated area) is not available.
Where exposure potential necessitates a higher level of
protection use a NIOSH-approved, positive-pressure,
pressure demand, air-supplied respirator.
When using respirator cartridges or canisters, they must be
changed frequently (following each use or at the end of the
work shift) to assure breakthrough exposure does not occur.
Skin Protection:
Skin contact with this product should be prevented through
the use of suitable protective clothing, gloves, and footwear
selected with regard for the use condition exposure potential.
Eye Protection:
Wear safety glasses or chemical goggles during handling to avoid
eye contact.
Ventilation Protection:
At elevated processing temperatures, or in the event that use
conditions generate airborne vapor, aerosol or mist, the
material should be handled in a well-ventilated area. Where
adequate ventilation is not available, use a NIOSH-approved
organic vapor/acid gas (OVAG) respirator with dust, mist,
and fume filter to reduce exposure. Where exposure potential
under use conditions is greater, use a NIOSH-approved,
positive-pressure air-supplied respirator.
Other Protection:
During the development of safe handling procedures, consideration
should be given to the need for cleaning of equipment and piping
systems to render them nonhazardous before maintenance and repair
activities are performed. Waste resulting from these procedures
should be handled in an environmentally safe manner.
Applicable Exposure Limits:
Other than any exposure limits which may be displayed in
Section 8, there are no exposure limits applicable for this
product or its components.
CAS#68334-32-7: no data from OSHA, ACGIH, NIOSH.
CAS# 141-65-1: no data from OSHA, ACGIH, NIOSH.
Vapor pressure (mm Hg): No data available Vapor density (air=1): No data available Evaporation rate: No data available Volatile %: No data available Boiling point: Not applicable Odor threshold (ppm): No data available Specific gravity: No data available Bulk density: 9.7 pounds/gallon @ 25°C (77°F) Solubility in water: <1% @ 25°C (77°F) Solubility in other solvents: Not determined Coefficient of oil/water: No data available Pour point: No data available Melting point: No data available pH factor: 7.2 (0.5% solution) Cloud point: No data available Flash point: 93°C (199.4°F) Flash method: Cleveland Open Cup Upper explosion limit: No data available Lower explosion limit: No data available Auto ignition temperature: No data available Other: Viscosity: > 100000 cps @ 38°C(100°F)
Chemical Stability:
The product is stable at ambient temperatures and
atmospheric pressures. It is not self-reactive and has
an almost infinite shelf life under sealed conditions.
It is not sensitive to physical impact or static discharge.
Loss of residual moisture will occur at temperatures above
100°C (212°F). The residue will emit a flammable alkene if
heated to temperatures above 160°C (320°F).
Incompatibilities
This product is incompatible with strong oxidizers, strong
acids, and strong alkalis. It hydrolyzes slowly at ambient
temperatures in acidic or alkaline aqueous solutions.
Polymerization
Hazardous polymerization is not expected to occur.
Decomposition:
Under fire conditions the product supports combustion and
decomposes to give off toxic materials such as phosphorous
oxides and oxides of carbon.
Conditions to avoid:
Under wet alkaline or acidic condition, prolonged storage
at elevated temperatures should be avoided.
See Section 7, "Storage".
Toxicological - Inhalation
Inhalation toxicity data are not available for this product.
However, inhalation may be expected to cause irritation to
the upper respiratory system.
Inhalation Chronic Exposure
There is no specific information available for this product.
However, over-exposure may cause irritation of the nose,
throat and upper respiratory tract.
Toxicological - Dermal
LD50 (Dermal) >1000 mg/kg (rabbit)
However, skin contact, especially if prolonged or repeated,
may cause moderate to severe irritation.
Skin Contact - Chronic
Skin contact may cause severe irritation.
Toxicological - Eye
The acute eye effects of this product have not been determined.
However, eye contact is expected to cause severe irritation or
possibly burns.
Toxicological - Ingestion
The acute oral LD50 (rats) is 3366 mg/kg (slightly toxic)
Ingestion- Chronic
Chronic ingestion effects of this product are not known.
However, ingestion can result in severe irritation or burns
of the mouth, throat, esophagus and stomach. May cause vomiting,
diarrhea, or abdominal pain.
Carcinogenicity/Mutagenicity
The carcinogenic/mutagenic properties of this product are
not known.
Reproductive Effects:
The reproductive toxicity of this product is not known.
Neurotoxicity
The neurotoxic effects of this product are not known.
Target Organs:
Over-exposure to this product may effect the skin, eyes, and
respiratory system.
Ecotoxicological Information:
The ecological toxicity of this product is not known.
Distribution:
Other ecological information on this product is not known.
Chemical Fate:
Chemical fate information on this product is not known.
Material that can not be used or chemically reprocessed should be disposed of
in accordance with all applicable regulations. Product containers and/or bottles
should be thorough emptied before disposal.
NOTE: State and local regulations as well as those in other countries might be
more stringent than USA federal regulations.
Container Disposal:
Containers and bottles should be drained of all residual
product before disposal. Empty containers should be disposed
of in accordance with all applicable laws and regulations.
If unused, this product does not meet the EPA’s criteria as either a listed or
a characteristic hazardous waste under the RCRA as published in 40 CFR 261.
Shipping Description
DOT Regulations:
Proper shipping name: Corrosive liquid, Acidic, Organic, N.O.S.
(Phosphoric acid, mono(2-ethylhexyl)ester
Hazard Class: 8
Identification number: UN3265
Packing Group: III
Label: 8
Remarks: This product does not contain an environmentally hazardous
substance as per 49 CFR 172.101, Appendix A
IATA:
Proper shipping name: Corrosive liquid, Acidic, Organic, N.O.S.
Phosphoric acid, mono(2-ethylhexyl)ester
Hazard Class: 8
Identification number: UN3265
Packing Group: III
Label: 8
SARA:
Section 355: None of the ingredients in this product is listed.
Section 313: None of the ingredients in this product is listed as a toxic chemical
subject to the reporting requirements of Section 313 of Title III of the SARA Act of 1986
and 40 CFR 372.
SARA Title III: Section 304 – CERCLA: None of the ingredients in this product is
regulated under Section 304 for emergency release notification.
TSCA: This substance is listed on the TSCA inventory.
TSCA Section 12b: This product does not contain any chemicals subject to Section
12(b) notification.
OSHA: This product is considered to be a hazardous chemical under the OSHA Hazard
Communication Standard (29 CFR 1910.1200).
RCRA: This product is not considered to be a hazardous waste under RCRA (40 CFR
261).
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer products
into the State of California to provide a warning statement if the product
contains ingredients for which the State has found to cause cancer, birth
defects or other reproductive harm. If this product contains an ingredient
listed by the State of California to cause cancer or reproductive toxicity,
it will be listed below:
No such components exist in this product.
European Community
European Labeling in Accordance with EC Directives
Hazard Symbols: Xn, C Harmful, Corrosive
Risk Phrases:
R20 Harmful by inhalation
R21 Harmful in contact with skin
R22 Harmful if swallowed
R34 Causes burns
R36 Irritating to eyes
R37 Irritating to respiratory system
R38 Irritating to skin
R41 Risk of serious damage to eyes
Safety Phrases:
S 2 Keep out of the reach of children
S13 Keep away from food, drink and animal feeding stuffs
S20/21 When using do not eat, drink or smoke
S24 Avoid contact with skin
S25 Avoid contact with eyes
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S27 Take off immediately all contaminated clothing.
S28 After contact with skin, wash immediately with plenty of Soap and water
and seek medical advice.
S29 Do not empty into drains
S36 Wear suitable protective clothing
S37 Wear suitable gloves
S39 Wear eye/face protection
CANADA:
WHMIS: This product has a WHMIS Classification of D2B; E
DSL/NDSL:
CAS# 141-65-1 is listed on the DSL List.
CAS# 141-65-1 is not listed on the NDSL List.
CAS# 1732-18-5 is listed on the DSL List.
CAS# 1732-18-5 is not listed on the NDSL List.
CAS# 68334-32-7 is not listed on the DSL List.
CAS# 68334-32-7 is listed on the NDSL List.
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty c oncerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids. ********************************************************************** The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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