SPI Supplies Division|
|
Date Effective........... January 8, 2009
(most recent revision)
Chemical Name/Synonyms... Polyvinyl Butyral
Chemical family.......... Polyvinyl butyral resins
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s......
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #02466-BA, 02467-MB Pioloform® B Resin
CAS #.................... 63148-65-2 >99% polyvinylbutyral
Chemical Formula......... Not known
CAS #.................... 63148-65-2 >99% polyvinylbutyral
NFPA Rating: Not known
Emergency overview:
This material is not hazardous by OSHA Hazard Communication
Definition
Physical Health Hazards:
None known.
Physical state: Solid
Color: White powder
Odor: Slightly pungent
Odor threshold: No data available
Potential Health Effects:
Routes of exposure
Eye, ingestion, skin contact
Signs and Symptoms of Acute Exposure:
Not known.
Skin contact:
May cause irritation.
Inhalation:
May cause irritation.
Eye contact:
May cause irritation.
Ingestion:
May cause irritation. The toxicological properties of this substance
Have not been fully studied.
Chronic Health Effects Summary:
No known chronic health effects.
Conditions Aggravated by Exposure:
No known conditions are aggravated by this material.
Take proper precautions to ensure your own health and safety before
attempting to rescue and providing first aid. These practices include
avoiding all unnecessary exposure and removal of the material from eye,
skin, and clothing. For specific information refer to the Emergency
Overview in Section of this MSDS.
Inhalation:
If symptoms are experienced, move victim to fresh
air, if symptoms persist, obtain medical attention.
Eye Contact:
Wash eyes with clean low-pressure water. If
irritation persists, seek medical advice.
Skin Contact:
If powdered or dust form of the material contacts the skin,
immediately flush the skin with large amounts of water. If
irritation or other symptoms persist, seek medical attention.
Ingestion:
Adverse health effects due to ingestion are not
anticipated. If gastric irritation or discomfort
persists, seek medical advice.
NFPA Rating: Not known
Flammability classification: Not classified.
Flash Point/Method: Not applicable
Auto-Ignition Temperature: 390 °C
Flammable Limits:
Lower: Not applicable
Upper: Not applicable
Extinguishing Media:
Water spray, Carbon dioxide, Dry chemical powder, Chemical foam.
Fire Fighting Instructions:
Protective Equipment/Clothing: Wear a NIOSH approved positive
pressure self-contained breathing apparatus and firefighter
turnout gear. There could be the evolution of toxic products of
combustion. Firefighting equipment should be fully decontaminated
after use.
Instructions:
Use flooding quantities of water until well after fire is out.
Exposure hazards:
This material is an irritant.
Personal Protection:
Wear personal protection as noted in Section 8.
Release response:
Vacuum or sweep up material and store in an appropriate container
for disposal.
Section 7: Handling and StorageHandling: Do not breathe dust. Avoid contact with eyes, skin, clothing. Storage: Keep container dry, cool. Keep container tightly closed.
Engineering Controls: Safety shower, eye bath, and mechanical exhaust required. Personal Protection: Inhalation: Use government approved respiratory protection where atmosphere exceeds recommended limits or if irritation develops. Skin: Protective clothing such as long sleeves or a lab coat should be worn. Gloves: Wear chemical-resistant gloves. Eye: Always use safety glasses or goggles.
Boiling Point/Range: Not available pH: Not available Vapor Pressure: Not available Viscosity: Not available Specific Gravity: (Water = 1): 1.08 Solubility: Not available Melting/Freezing Point: Not available Evaporation Rate: Not available
Chemical Stability:
The product is stable and does not under go a hazardous
polymerization.
Conditions to Avoid:
Avoid contact with strong oxidizing agents.
Hazardous Products of Deposition:
Carbon dioxide, carbon monoxide
Summary:
Causes eye and skin irritation. May be harmful by inhalation,
ingestion, or skin absorption.
Skin Effects:
May cause skin irritation.
LD50/LC50:
Draize test, rabbit, eye: 100 mg/24H
Subchronic Effects:
None known
Exotoxicity: Exotoxicity is expected to be low based on the low
water solubility of polymers. No other information
is known on this topic.
Environmental Fate: No information found in our selected references.
Bioaccumulation: Not expected to occur.
Polyvinylbutyral is not a "hazardous waste" as that term is defined in the Resource Conservation and Recovery Act (RCRA), 40 DFR 261, "Identification and Listing of Hazardous Waste". Burn in an approved incinerator or dispose of in an approved landfill in accordance with all applicable local, state, and federal laws and regulations. Consult your appropriate regulatory officials for information on such disposal.
Proper Shipping Name: None DOT Hazard Class: Non-Regulated UN/NA ID: Not Regulated Packing Group: Not Applicable Labels: Not Regulated Marine Pollutant: Not known NAER Guidebook: Not Regulated DOT Status: Not Regulated
TSCA: This chemical is listed on the TSCA 8(b) inventory.
If identified components of this product are listed
under the TSCA 12(b) Export Notification Rule, they
will be listed below.
TSCA 12(b) Component Listed under TSCA Section
SARA-Section 313 Emissions Reporting:
Component Reporting Threshold
SARA-Section 311/312:
No components present in this product are subject to the reporting
requirements of this statute.
CERCLA Hazardous Substances and their Reportable Quantities:
Component Reportable Quantity
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer
products into the State of California to provide a warning statement
if the product contains ingredients for which the State has found to
cause cancer, birth defects or other reproductive harm. If this product
contains an ingredient listed by the State of California to cause cancer
or reproductive toxicity, it will be listed below:
European/International Regulations:
Hazard Symbold: Xi
Risk Phrases:
R 36 Irritating to eyes
R 37 Irritating to respiratory system
R 38 Irritating to skin
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
S 36 Wear suitable protective clothing
Canada:
CAS# 63148-65-2 is listed on Canada’s DSL list.
CAS# 63148-65-2 is not listed on Canada’s NDSL list.
WHMIS: not available
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty c on cerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids. ********************************************************************** The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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