Information System
USA
Protection Association
USA
SPI Supplies Division
Date Effective........... June 19, 2007
(most recent revision)
Chemical Name/Synonyms... Copper-filled diallyl phthalate powder
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s...
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI # 01362-AB
01362-AF
| Hazardous Material Information System USA |
Health | 1 | National Fire Protection Association USA |
|
| Fire Hazard | 0 | |||
| Reactivity | 0 | |||
| Personal Protection |
Component Name CAS # Percent EU # Copper 7440-50-8 >70 231-159-6 Epoxy Resin N/A <20 N/A Mineral Fillers Mixture <10 N/A Catalysts Mixture <01 N/A
Emergency overview: This product presents a moderate ingestion and inhalation hazard, with no unusual fire or spill hazards. Appearance: Copper brown capsules. Flash Point: None. Warning! Target Organs: Mucous membranes (chronic), nervous system (chronic). Potential Health Effects Eye: May cause irritation; fragments in cornea may cause cataracts. Skin: May cause irritation; potential 'flu-like' symptoms Ingestion: Ingestion may lead to moderate irritation of stomach lining or irritation of the upper respiratory tract. Ingestion may also cause headaches, nausea, vomiting, diarrhea, chills, fever, or aching muscles. Inhalation: Inhalation poses a low immediate health risk. Chronic: Chronic overexposure may cause anemia, "lead line" on gums, potential damage to the nervous system, or atrophic changes in mucous membranes. Acute overexposure can results in "metal fume fever" with flu-like symptoms lasting for 1-2 days.
Eyes: Flush eyes with copious amounts of running water for at least 15 minutes and seek medical attention. Skin: Wash contaminated areas with soap and water. Seek medical attention. Ingestion: Seek immediate medical attention. Inhalation: Remove victim to fresh air. Provide oxygen if breathing is difficult or labored. If irritation persists, seek medical attention. Notes to Physician: Treat supportively and symptomatically.
General Information: Always wear full protective equipment including self containing breathing apparatus with full-face protection and respirator set to positive pressure. Auto Ignition Temperature: N/A Flash Point: None. Flammability: Non-flammable. Hazardous Combustion Products: N/A Unusual Fire/Explosion Hazards: N/A Extinguishing Media: Dry sand or other inert material. Special Protective Measures: None needed.
Spills/Leaks: Wear appropriate protective equipment, including safety goggles and NIOSH/MSHA dust respirator. Contain the spill and avoid raising dust particles. Cover spill with a damp sand and place in an approved disposal container. Disposal Procedure: According to all local, state, and federal regulations.
Handling: Always wear protective equipment appropriate to the task. Always use adequate ventilation, and avoid generating dust clouds. Avoid breathing dust particles. Storage: Store in a dry, cool place, in closed containers, away from heat and acids. Keep out of the reach of children.
Engineering Controls: Local exhaust at a minimum face velocity of 60 fpm should be employed. Safety shower and eye wash stations should be readily available in work area. Exposure Limits Chemical Name ACGIH TLV OSHA - Final PELs Copper 1 mg/m3 1 mg/m3 Epoxy Resin Not established Not established Mineral Fillers 10 mg/m3 1.5 mg/m3 Catalysts Not established Not established Personal Protective Equipment Eyes: Chemical safety goggles or glasses with side shields are required. Skin: Chemical resistant gloves are required. Clothing: Protective clothing such as long sleeves with a lab apron or a lab coat should be worn. Neoprene or neoprene gloves are recommended. When handling heated materials, also be sure to use heat-resistant gloves, boots and face protection. Respirators: NIOSH (US) or European standard EN 149 approved respirators approved for dust should be employed when using product outside of a fume hood or when ventilation is not adequate.
Physical State: Solid.
Appearance: Copper brown capsules.
Odor: None.
pH: N/A
Vapor Pressure: N/A
Vapor Density: N/A
Evaporation Rate: N/A
Viscosity: N/A
Boiling Point: 4653° F (2567° C).
Freezing/Melting Point: 1981° F (1083° C).
Autoignition Temperature: N/A
Flash Point: None.
Decomposition Temperature: N/A
Explosion Limits
Lower: N/A
Upper: N/A
Solubility in water: None.
Specific Gravity/Density: 3.9
Molecular Formula: N/A
Molecular Weight: N/A
Chemical Stability: Stable under normal handling conditions.
Conditions to Avoid: N/A
Incompatibility with Other Materials: Strong acids.
Bromates.
Chlorates.
Iodates.
Hazardous Decomposition of Products: N/A
Hazardous Polymerization: Will not occur.
No toxicological hazards have been reported at this time.
No ecological information is available at this time.
Waste Disposal: Place product in an appropriate disposal container and dispose in accordance with all local, state, and federal regulations.
US DOT Hazard Class: Not regulated. IATA (for international shipments): Not regulated.
United States:
TSCA: On Toxic Substance Control Inventory.
CERCLA Reportable Quantity: Copper, 5000 lbs.
SARA Title III
Section 302 Extremely Hazardous Substances: None.
Sections 311/312 Hazardous Categories: Chronic, Acute.
Section 313 Toxic Chemicals Copper fumes.
European/International Regulations
Hazard Symbols: None.
Risk Phrases:
R36/38 Irritating to eyes and skin.
Safety Phrases:
S2 Keep out of the reach of children.
S3/9/14 Keep in a cool, well-ventilated place away from heat and acids.
S15 Keep away from heat.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S46 If swallowed, seek medical advice immediately and show this container or
label.
Canada
WHMIS: Not regulated.
DSL/NDSL: CAS # 7440-50-8 is specified on the DSL.
If this product should be used in ways that are outside of the intended applications in scanning electron microscope laboratories, and if it is going to be formulated into some other system, so that it becomes just another component of that other system, read the MSDS sheets for the other components before blending as the resulting mixture may have the hazards of all of its parts.
Disclaimer of Liability:
Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute.
SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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