SPI Supplies SPI Supplies Division
Structure Probe, Inc.

P.O. Box 656 West Chester, PA 19381-0656 USA
Phone: 1-(610)-436-5400 Fax: 1-(610)-436-5755
E-mail: spi3spi@2spi.com

WWW: http://www.2spi.com
Manufacturer's CAGE: 1P573

Material Safety Data Sheet

SPI #01201-AB; 01201-BC; 01202-AB; 01202-BC; 01210-AB Liqui-Nox® Critical Cleaning Liquid Detergent




Section 1: Identification

Date Effective........... May 23, 2007
                          (most recent revision)

Chemical Name/Synonyms... On Label: Liqui-Nox®

Emergencies                
Contacting CHEMTREC:

24 Hour Emergency Use Only #'s... 
Worldwide phone: 1-(703)-527-3887
Worldwide FAX:   1-(703)-741-6090 
Toll-free phone: 1-(800)-424-9300 USA only


Product or Trade Name.... SPI #01201-AB;
                          01201-BC;
                          01202-AB;
                          01202-BC;
                          01210-AB Liqui-Nox®
                          Critical Cleaning
                          Liquid Detergent 


Hazardous Material
Information System
USA
Health 1 National Fire
Protection Association
USA
Fire Hazard 0
Reactivity 0
Personal Protection  

Section 2: Composition

Component Name                   CAS #          Percent       EC #

Sodium Dodecylbenzenesulfonate   25155-30-0     10-30         246-680-4

Section 3: Hazard Identification

Emergency overview: May cause irritation of skin and eyes. May cause headache,
nausea, vomiting, diarrhea, or gastric distress.

Appearance: Pale yellow, odorless

Flash Point: None

Warning!

Target Organs: Skin, eyes.

Potential Health Effects

Eye: May cause eye irritation.

Skin: Prolonged contact may cause irritation, drying or chapping of
skin.

Ingestion: May cause vomiting, diarrhea or gastric distress.

Inhalation: May cause headache or nausea.

Chronic: See effects from acute exposure.


Section 4: First Aid Measures

Eyes: Upon contact, wash eyes throughly with copious amounts of water for
at least 15 minutes, holding the eyes open. Seek medical attention.


Skin: Flush area with copious amounts of water. Remove contaminated clothing,
wash thoroughly with soap and water. If irritation persists, seek medical attention.


Ingestion: Upon ingestion, dilute with 2-4 glasses of water. Do not induce
vomiting. Seek medical attention.


Inhalation: Remove victim to fresh air. If symptoms persist, seek medical
attention.


Notes to Physician: Treat supportively and symptomatically.


Section 5: Fire Fighting Measures

Flash Point: None
Explosion Limits: 
    Upper: N/A
    Lower: N/A
Autoignition Temperature: N/A


General Information: Wear full protective equipment including self containing
breathing apparatus.


Extinguishing Media
            Small fire: Water, foam, or dry chemical
            Large fire: Use extinguishing media suitable for the
            surrounding materials.

Special firefighting procedures:  No special measures required

Unusual Fire/Explosion Hazards:  None

Hazardous combustion products: May release SO2, carbon
monoxide, or carbon dioxide on burning.

Protection of fire fighters:  No special measures are required.

Section 6: Accidental Release Measures

General Information: Contain the released material and prevent from 
entering drains, sewers, or other waterways.


Spills/Leaks: Wear appropriate protective equipment. Contain the spill. 
Small amounts may be flushed to sewer with copious amounts of water. Soak up spill 
with absorbent material and place in appropriate disposal container. 


Section 7: Handling and Storage

Handling: Always wear protective equipment appropriate to the task. Avoid
contact with skin, eyes, and clothing. Avoid extreme temperatures and physical 
damage. 


Storage: Store away from strong acids and strong oxidizers, in closed
containers. Keep out of reach of children.

Section 8: Exposure Controls and Personal Protection

Engineering Controls: Normal ventilation. Safety shower and eye wash
station should be available in work area.
 

Exposure Limits:

Chemical Name                       ACGIH   NIOSH   OSHA - Final PELs

Sodium Dodecylbenzenesulfonate      N/A     N/A     N/A

OSHA Vacated PELs:  N/A

Personal Protective Equipment

Eyes: Glasses with side shields or chemical splash goggles are highly
recommended.

Skin: As necessary to prevent skin contact.

Clothing: Protective clothing such as long sleeves or a lab coat 
should be worn. Neoprene or nitrile gloves are recommended. When handling 
heated materials, also be sure to use heat-resistant gloves, boots and face 
protection. 

Respirators: None required under normal use.


Section 9: Physical and Chemical Properties

Physical State: Liquid.
Appearance: Pale yellow.
Odor: Odorless.
pH: 8.5
Vapor Pressure: 17 mm Hg @ 20° C (68° F).
Vapor Density: >1 (air = 1).
Evaporation Rate: <1 (butyl acetate = 1).
Viscosity: N/A
Boiling Point: 100° C (212° F).
Freezing/Melting Point: N/A
Autoignition Temperature: N/A
Flash Point: N/A
Decomposition Temperature: N/A
Explosion Limits:
        Lower: N/A
        Upper: N/A
Solubility in water: Complete
Specific Gravity/Density: 1.083 (water = 1)
Molecular Formula: N/A
Molecular Weight: N/A



Section 10: Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions.

Conditions to Avoid: Extreme temperatures.

Incompatibility with Other Materials: Strong acids, strong oxidizers.

Hazardous Decomposition of Products: May release SO2, carbon
monoxide, or carbon dioxide on burning.

Hazardous Polymerization: Will not occur.


Section 11: Toxicological Information

LD50: >5000 mg/kg (rat, oral)

Teratogenicity: N/A

Reproductive Effects: N/A

Neurotoxicity: N/A

Mutagenicity: N/A

Carcinogenic Effects: Not listed as a carcinogen.

Section 12: Ecological Information

Exotoxicity: N/A

Environmental Fate: N/A

Section 13: Disposal Considerations

Waste Disposal: In accordance with local and federal regulations.

Section 14: Transport Information

US DOT Hazard Class: Not hazardous for transport.

IATA (for international shipments): Not hazardous for transport.



Section 15: Regulatory Information

United States

TSCA All components of this product are listed on the TSCA inventory.

SARA Codes

SARA Hazard Categories Sections 311/312: 
               Immediate (Acute) Health Hazard: No.
               Delayed (Chronic) Health Hazard: No.
               Fire Hazard: No.
               Sudden Release of Pressure: No.
               Reactive: No.

Section 313 None

State (Individual states in the USA): This product nor any of its components
appear on any state health hazard lists.

  

European/International Regulations

This product is not dangerous as defined by the European Union.

Hazard Symbols: N/A

Risk Phrases: N/A          

Safety Phrases:
     S2: Keep out of the reach of children. 


Canada

WHMIS Classification: Not controlled.

DSL Status:
   CAS # 25155-30-0 is on the DSL 


Section 16: Other Information

If this product should be used in ways that are outside of the intended applications in scanning electron microscope laboratories, and if it is going to be formulated into some other system, so that it becomes just another component of that other system, read the MSDS sheets for the other components before blending as the resulting mixture may have the hazards of all of its parts.

Disclaimer of Liability:

Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute.

SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.

************************************************************************

The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.


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