SPI Supplies SPI Supplies Division
Structure Probe, Inc.

P.O. Box 656 West Chester, PA 19381-0656 USA
Phone: 1-(610)-436-5400 Fax: 1-(610)-436-5755
E-mail: spi3spi@2spi.com

WWW: http://www.2spi.com
Manufacturer's CAGE: 1P573

Material Safety Data Sheet

SPI # 01136-AB, 01136-AE, 01141-AB, Citrajet® Low-Foaming Liquid Acid Cleaner and Detergent




Section 1: Identification

Date Effective........... January 8, 2009
                          (most recent revision)

Chemical Name/Synonyms... Citrajet® Low-Foaming Liquid
                          Acid Cleaner and Detergent

Emergencies                
Contacting CHEMTREC:

24 Hour Emergency Use Only #'s... 
Worldwide phone: 1-(703)-527-3887
Worldwide FAX:   1-(703)-741-6090 
Toll-free phone: 1-(800)-424-9300 USA only


Product or Trade Name.... SPI # 01136-AB
                                01136-AE
                                01141-AB
                                Detergent


Hazardous Material
Information System
USA
Health 1 National Fire
Protection Association
USA
1
0
0
Fire Hazard 0
Reactivity 0
Personal Protection B
NFPA Rating: (estimated) Health: 1; Flammability: 0; Reactivity: 0

Section 2: Composition

Component Name            CAS #          Percent       EU #

Citric Acid               77-92-9        10-30         201-069-1

Section 3: Hazard Identification

Emergency overview: Routes of entry include skin and eye contact, inhalation,
and ingestion.

Appearance: Pale yellow liquid.
 
Flash Point: None.
 

Warning!  

Target Organs: Eyes, skin, gastrointestinal tract.

Potential Health Effects

Eye: May cause irritation.

Skin: Prolonged contact may cause irritation.

Ingestion: May cause diarrhea, vomiting, or gastric distress.

Inhalation: May cause irritation.

Chronic: This product contains a component that may be corrosive.



Section 4: First Aid Measures

Eyes: Immediately flush with running water for at least 15 minutes while
holding eyes open. Check for and remove contact lenses. Seek medical attention.

Skin: Wash contaminated area thoroughly with soap and water. Remove contaminated
clothing and launder before reuse. If irritation persists, seek medical attention.
Do not attempt to neutralize with chemical agents.


Ingestion: Upon ingestion, dilute with 2-4 glasses of water or milk. Do not
induce vomiting and seek medical attention immediately. 


Inhalation: Rinse nose and mouth with fresh water. Remove victim to fresh air.
If irritation persists, seek medical attention. 


Notes to Physician: Treat supportively and symptomatically.

Section 5: Fire Fighting Measures

General Information: Always wear full protective equipment including self 
containing breathing apparatus.

Auto Ignition Temperature: N/A

Flash Point: None.

Flammability: Not flammable.

Hazardous Combustion Products: Carbon oxides.
                               Oxygen.
                               Hydrogen.
                               Hydrocarbons.
                               Carbon.

Extinguishing Media: Carbon dioxide, dry chemical, water, water fog, foam.

Protective Measures: No special protective measures are required.


Section 6: Accidental Release Measures

Spills/Leaks: Wear appropriate protective equipment and contain the spill. 
Small amounts may be flushed into a sanitary sewer with copious amounts of water. 
Clean contaminated area thoroughly and notify the proper authorities
as required.

Section 7: Handling and Storage

Handling: Avoid breathing vapors or mist. Always use adequate ventilation
when handling the product. Avoid physical damage. Avoid contact with skin, eyes, 
and clothing. Wash thoroughly after use. Launder contaminated clothing before reuse.
Keep out of reach of children.

Storage: Store in a closed container and avoid extreme temperatures.


Section 8: Exposure Controls and Personal Protection

Engineering Controls: If exposure limit is exceeded, use a NIOSH approved
respirator. Safety shower and eye wash stations should be readily accessible in 
work area.

Exposure Limits: Not available for product.

Chemical Name           T.L.V.

Citric Acid             N/A


Personal Protective Equipment

Eyes: Chemical safety goggles or glasses with side shields are required.

Skin: As necessary to prevent contact with skin.

Clothing: Protective clothing such as long sleeves or a lab coat 
should be worn. Neoprene or rubber gloves are recommended. When handling 
heated materials, also be sure to use heat-resistant gloves, boots and face 
protection.  

Respirators: If exposure limit is reached or exceeded, a NIOSH approved
respirator for vapors and mists should be used.


Section 9: Physical and Chemical Properties

Physical State: Liquid.
Appearance: Pale yellow.
Odor: Nearly odorless.
pH: 2.5
Vapor Pressure: 17 mm Hg @ 20° C (68° F).
Vapor Density: >1 (air = 1)
Evaporation Rate: <1 (butyl acetate = 1).
Viscosity: N/A
Boiling Point: 103° C (217° F)
Freezing/Melting Point: N/A
Autoignition Temperature: N/A
Flash Point: None
Decomposition Temperature: N/A
Explosion Limits:
        Lower: N/A
        Upper: N/A
Solubility in water: Complete.
Specific Gravity/Density: 1.12 (water = 1).
Molecular Formula: N/A
Molecular Weight: N/A



Section 10: Stability and Reactivity

Chemical Stability: Stable under normal conditions.

Conditions to Avoid: Extreme temperatures.

Incompatibility with Other Materials: Strong oxidizing agents and strong
alkalies.

Hazardous Decomposition of Products: See hazardous combustion products.

Hazardous Polymerization: Will not occur.


Section 11: Toxicological Information

LD50: >5000 mg/kg (rat, oral)

LC50: Not available for product.

Teratogenicity: N/A

Carcinogenic Effects: Not listed as a carcinogen.

Reproductive Effects: N/A

Neurotoxicity: N/A

Mutagenicity: N/A

Other Studies:

CAS #                        LD50                           LC50

77-92-9                      3000 mg/kg (rat, oral)         N/A
                             5040 mg/kg (mouse, oral)

Section 12: Ecological Information

No ecological information is available at this time.



Section 13: Disposal Considerations

Waste Disposal: In accordance with local, state, and federal regulations.

Section 14: Transport Information

US DOT Hazard Class: Not regulated.

IATA (for international shipments): Not regulated.


Section 15: Regulatory Information

United States

TSCA: All ingredients in this product are listed on the TSCA inventory.

SARA Hazard Sections 311/312: 
                      Immediate (Acute) Health Hazard: No.
                      Delayed (Chronic) Health Hazard: No.
                      Fire Hazard: No.
                      Sudden Release of Pressure: No.
                      Reactive: No.

SARA Section 313: None.

State (Individual states in the USA): Neither this product nor any of its 
components appear on any state health hazard lists.
  

European/International Regulations

European Labeling Required

Hazard Symbols: Xi        Irritant.

Risk Phrases:    
     R36/38 Irritating to skin and eyes.      
     
Safety Phrases:
     S2 Keep out of the reach of children.
     S24/25 Avoid contact with skin and eyes. 


Canada

This product has a WHMIS classification of D2B

DSL Status: cas # 77-92-9 is listed on the DSL.


Section 16: Other Information

If this product should be used in ways that are outside of the intended applications in scanning electron microscope laboratories, and if it is going to be formulated into some other system, so that it becomes just another component of that other system, read the MSDS sheets for the other components before blending as the resulting mixture may have the hazards of all of its parts.

Disclaimer of Liability:

Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute.

SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.

************************************************************************

The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.


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