Material Safety Data Sheet

Section 1: Identification

Date Effective..........January 5, 2007
                        (most recent revision)

Chemical Name/Synonyms..Silicone replicating resin; Silicone rubber 

Emergencies
Contacting CHEMTREC:

24 Hour Emergency Use Only #'s... 
Worldwide phone: 1-(703)-527-3887
Worldwide FAX:   1-(703)-741-6090 
Toll-free phone: 1-(800)-424-9300 USA only

Product or Trade Name.. SPI #01090B-AB Silicone replicating resin
Synonyms............... Silicone rubber



Hazardous
Material
Information System
USA

Health
1
National Fire
Protection
Association
USA
 




Fire Hazard
0


Reactivity
0


Personal Protection
 


NFPA Rating:
(estimated) Health: 1 ; Flammability: 0 ; Reactivity:  0

Section 2: Composition

Component Name          CAS #           Percent     EINECS/ELINCS
Ethyl silicate          11099-06-2      1-5%        234-324-0
Dimethylpolysiloxane    70131-67-8      60-90%      not available
Calcium carbonate       471-34-1        10-30%      207-439-9

Section 3: Hazard Identification

Emergency overview: May cause eye irritation; may be harmful if
swallowed.

Appearance: ~298°C (568°F)

Flash Point: n/a 
 
Potential Health Effects

Eye: May cause eye irritation.

Skin: May cause skin irritation.

Ingestion: May be harmful if swallowed.

Inhalation: MMay cause mild respiratory irritation.

Chronic:
None of the components of this substance present >0.1% is listed as a
carcinogen or suspected carcinogen by NTP, IARC, or OSHA.

Other:
At temperatures above 150°C (300°F) in an oxygen containing atmosphere, this
product may generate formaldehyde, due to the presence of methylpolysiloxanes.
Formaldehyde is a potential cancer hazard, is an eye and throat irritant, a
skin and respiratory sensitizer, and an acute toxic hazard.  For more
information see our msds @ http://www.2spi.com/catalog/msds/msds02614.html.

Section 4: First Aid Measures

Eyes:
Flush eyes with copious amounts of water for at least 15 minutes, holding the
eyelids open.  If irritation occurs or persists, seek medical attention.

Skin:
In case of skin contact, wash contaminated area with copious amounts of soap
and water.

Ingestion:
Do not induce vomiting. If victim is alert and conscious, give one cupful of
water or milk and seek medical attention.

Inhalation:
In case of symptoms, remove to fresh air.  Seek medical attention is symptoms
persist.

Notes to Physician: None known.

Section 5: Fire Fighting Measures

Flash Point: 298°C (568°F)
Explosion Limits:
    Upper: n/a
    Lower: n/a
Autoignition Temperature: n/a
 
General Information:
Wear a NIOSH approved positive pressure self-contained breathing apparatus
and firefighter turnout gear. There could be the evolution of toxic products
of combustion. Firefighting equipment should be fully decontaminated after use.

Extinguishing Media:
Carbon dioxide, Carbon monoxide, Silicon dioxide, Formaldehyde

Hazardous Combustion Products:
All standard extinguishing media are suitable.

Section 6: Accidental Release Measures

General Information:
Wear protective equipment as detailed in the protective equipment section.

Spills/Leaks: 
Scrape up, wipe up, or soak up in an inert material and place in a suitable
container for disposal. To reduce slipping hazard, wash walking surfaces with
detergent and water once pick-up is complete.

Section 7: Handling and Storage

Handling:
Use only in well ventilated areas. Avoid inhalation of vapor or mist.  Avoid
contact with skin or eyes. Wash thoroughly after use.  Keep away from children.

Storage:
Store under refrigeration in tightly closed containers.

Section 8: Exposure Controls and Personal Protection

Engineering Controls:
Eyewash station must be available to work area.  Use only in well-ventilated
areas.

Exposure Limits:

Chemical Name           ACGIH   NIOSH   OSHA - Final PELs
Ethyl Silicate          n/a     n/a     n/a
Dimethylpolysiloxane    n/a     n/a     n/a
Calcium carbonate       n/a     n/a     n/a

OSHA Vacated PELs: n/a

Personal Protective Equipment

Eyes: Safety glasses

Skin: Rubber gloves

Clothing: Not known

Respirators:
Use appropriate respiratory protection if irritation is experienced. A
respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a
respirator's use. If respiratory irritation is experienced, use a NIOSH/MSHA
or European Standard En149 approved respirator. 

Section 9: Physical and Chemical Properties

Physical State:  Liquid
Appearance: white
Odor:  slight
pH:  n/a
Vapor Pressure:  Not available
Vapor Density:  Not available
Evaporation Rate: Not available 
VOC (excluding H2O and exempts): <6
Viscosity:  Not available
Boiling Point:  Not available
Freezing/Melting Point:  Not available
Autoignition Temperature: Not available
Flash Point: ~298°C (568°F)
Decomposition Temperature:  Not available
Explosion Limits:
	Lower: Not available
	Upper: Not available
Solubility in water:  insoluble
Solubility in organic solvent: toluene
Specific Gravity/Density: 1.2
Molecular Formula: n/a
Molecular Weight:  n/a

Section 10: Stability and Reactivity

Chemical Stability: Stable

Conditions to Avoid: Not known.

Incompatibility with Other Materials: Not known.

Hazardous Decomposition of Products: Carbon monoxide, Carbon dioxide,
Formaldehyde, Silicon Dioxide

Hazardous Polymerization:  Will not occur

Section 11: Toxicological Information

RTECS#: n/a

LD50/LC50 Information: n/a

Carcinogenicity: n/a

ACGIH:       n/a
California:  n/a
NIOSH:       n/a
NTP:         n/a
OSHA:        n/a
IARC:        n/a

Teratogenicity: n/a

Reproductive Effects: n/a

Neurotoxicity: n/a

Mutagenicity: n/a

Other Studies:  n/a

Section 12: Ecological Information

Exotoxicity: No data available.

Environmental Fate: No data available.

Aquatic: No data available.

Atmospheric: No data available.

Physical: No data available.

Section 13: Disposal Considerations

RCRA P-Series: n/a 
RCRA U-Series: n/a

Dispose of in accordance with all federal, state and local regulations.

Section 14: Transport Information

US DOT Hazard Class: Not regulated.

IATA (for international shipments) Not regulated.

Section 15: Regulatory Information

United States:

TSCA
All components of this product are listed on the TSCA Inventory List.

Health & Safety Reporting List
None of the components of this product are listed on the Health & Safety
Reporting List.

Chemical Test Rules
None of the components of this product is under a Chemical Test Rule.

Section 12b:
None of the components of this product is listed under TSCA Section 12b.

TSCA Significant New Use Rule:
None of the components of this product is under a Significant New Use Rule.

CERCLA Section 103:
None of the components of this product is listed under CERCLA Section 103.

SARA:

Section 302 (RQ)
None of the components of this product has an RQ.

Section 302 (TPQ)
None of the components of this product has a TPQ.

SARA Codes
(Section 311, 312): Acute Health Hazard; Chronic Health Hazard

Section 313
None of the components of this product is listed under SARA Section 313.

Clean Air Act:
None of the components of this product is listed under the Clean Air Act.

Clean Water Act:
None of the components of this product is listed under the Clean Water Act.

OSHA:
This product is not considered by OSHA to be highly hazardous.

State (Individual states in the USA)
This product does not contain any components listed on any state list.

California No Significant Risk Level: 
California Prop. 65:
This product does not contain any components known to the State of California
to cause cancer, or birth defects, or other harm.

European/International Regulations:
European Labeling in Accordance with EC Directives

Hazard Symbols: n/a
Risk Phrases:        
     	R n/a
     

Safety Phrases:
	S 2:  Keep out of reach of children
	S 7:  Keep container tightly closed.
	S 37/39  Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection): n/a


Canada
WHMIS:
This product has a WHMIS classification of D2B.

DSL/NDSL:
CAS# 11099-06-2 is on the DSL List and not on the NDSL List.
CAS# 70131-67-8 is on the DSL List and not on the NDSL List.
CAS# 471-34-1 is on the DSL List and not on the NDSL List.

NOTE:  n/a = not available

Section 16: Other Information

Disclaimer of Liability:

Caution!  Do not use SPI Supplies products or materials in applications 
involving implantation within the body; direct or indirect contact with 
the blood pathway; contact with bone, tissue, tissue fluid, or blood; or 
prolonged contact with mucous membranes.  Products offered by SPI Supplies 
are not designed or manufactured for use in implantation in the human body 
or in contact with internal body fluids or tissues.  SPI Supplies will not 
provide to customers making devices for such applications any notice, 
certification, or information necessary for such medical device use 
required by US FDA (Food and Drug Administration) regulation or any 
other statute. SPI Supplies and Structure Probe, Inc. make no representation, 
promise, express warranty or implied warranty concerning the suitability of 
these materials for use in implantation in the human body or in contact with 
internal body tissues of fluids. This product is intended for external contact 
only with human skin.

To Ask a Question or Make a Comment

To Place an Order or Request a Quote

• SPI Supplies MSDS Safety Sheets Table of Contents
• SPI Supplies Catalog Table of Contents
• SPI Supplies Home Page

© Copyright 2008. By Structure Probe, Inc.
Contacting SPI Supplies and Structure Probe, Inc.
All rights reserved.
All trademarks and trade names are the property of their respective owners.
Privacy Policy

Worldwide Distributors, Representatives, and Agents