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Date Effective........... October 27, 2005
(most recent revision)
Chemical Name/Synonyms... SPI Metal Bright Spray
Chemical family.......... Ethyl alcohol major constituent. Product
is described as being made up of
1]concentrate and
2]propellent. Composition of the concentrate
is as follows: 80% ethyl alcohol,
5% polycarbonic resin, and 15% other inert
ingredients.
Emergencies Contacting CHEMTREC 24 Hour Emergency
Use Only #'s............. Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #01050-AB Metal Bright Spray
(Formulated for use with vacuum
evaporators and other vacuum coaters
not requiring exposure to heat)
CAS #.................... 64-17-5 (for ethyl alcohol)
Chemical Formula......... CH3CH2OH
Information about propellent: A46 Blend, which consists of
· 85% isobutane CAS #75-28-5
· 15% propane CAS #74-98-6
| Hazardous
Material Information System USA | Health | 1 | National Fire Protection Association USA |  |
| Fire Hazard | 3 | |||
| Reactivity | 0 | |||
| Personal Protection |
Boiling Point............ 760 mm Hg : 173°F (78.3°C)
Coeff. of Water/Oil Dist. NOT DETERMINED
pH (Liquids Only)........ NOT DETERMINED
% Volatile By Volume..... 90%
Vapor Pressure........... mm Hg: Not known
Vapor Density/Air is 1... Not known
Solubility In Water...... Slightly
Appearance and Color...... Product exists in form of aerosol and has no
color in that form. As a liquid, which can
not be seen, it is yellow to clear.
Specific Gravity......... (H2O = 1): 0.83
Evaporation Rate......... (n-butyl acetate = 1): Not known
Odor..................... No odor
Flash Point................ 54.4°C (130°F) (ASTM D-56-69)
Flammable Limits in Air.... Flammable limit in air, % by vol.
LEL (Lower Explosive Limit) : Not known
UEL (Upper Explosive Limit) : Not known
Fire Extinguishing Media:
Dry Chemical, CO2, foam
Special Firefighting Procedure......Not normally neccessary
Unususal Fire and Explosion Hazards:
Containers may build pressure at elevated temperature. If exposed to
heat, if possible, containers should be cooled with a water spray.
Firefighting Procedure:
Wear self-contained breathing apparatus.
Stable: Yes
Hazardous Polymerization:
Does not occur.
Hazardous Decomposition Products:
CO2 (Carbon Dioxide)
Conditions to avoid:
Heat, Contact with ignition source.
Materials to avoid:
Oxidizing materials. Store away from all ignition sources.
Spill Response: A "spill" could only occur if a container was punctured. While there would be an immediate release of the contents, because of the vapor pressure , the volatiles would evaporate almost immediately, hence there would be nothing left to "clean up". Disposal considerations: Because of the above, there would be nothing left to dispose of except for the now completely empty and depressurized aerosol cans which could be discarded as any other non-hazardous metal can. However, in the unlikely event that there is actual liquid concentrate, in any case, do not flush down sewers or drains where danger of vapors becoming ignited is present.
Potential health effects (acute and chronic):
Symptoms of exposure:
Not known. However, the classic symptoms of exposure to alcohol in
excess would include irritation of the eyes and respiratory tract;
headache, dizziness, drowziness, fatigue, nausia, tremor, narcosis
Medical condition aggravated by exposure:
Not known.
Routes of entry:
Mainly inhalation, but to a much lesser degree via ingestion or skin
contact.
Carcinogenicity:
The material is not listed {IARC- International Agency for Research on
Cancer; NTP-National Toxicology Program; OSHA- Occupational Safety and
Health Administration)}as cancer causing agent. Not on "Z" list either.
Toxicity data:
Not known
Emergency and first aid procedures:
Get medical assistance for all cases of over-exposure.
Skin: Wash thoroughly with flowing water or shower.
Eyes: Immediately flush thoroughly with water for at
least 15 minutes.
Inhalation: Remove to fresh air. Artificial respiration if
breathing has stopped.
Ingestion: If conscious, drink water and induce vomiting.
Immediately as directed by medical personnel.
Never give anything by mouth to an unconscious person.
Engineering Controls / Personal Protection:
None needed
Handling and Storage: Do not store neat heat of flame or other source of ignition (e.g. Electrical wiring or motors). We would also recommend storage away from direct sunlight in order to minimize the chances that radiant heat could cause the container temperature to rise and therefore, also the pressure to rise, shortening the shelf life of the product. Other: Store in cool dry well-ventilated area. Discard when expiration date passes. At some point after the expiration date, it is possible that the ingredients will cause a slow corrosion of the metal side-walls. We are unaware of any catastrophic failure, but what does seem to happen is that a small pin hole develops at which point there is just a very slow and stead release of the propellant and also the ingredients. The failure phenomenon is virtually identical, and of no more concern, than the failure of an old can of hair spray or shaving cream.
Component Appr % Ethyl Alcohol 60 Bell Bright is considered a "flammable liquid": UN #1170 Packing Group II DOT Class 3 Flammable LiquidShipping Name: Ethyl alcohol (DOT) and Ethanol (IATA)
Exotoxicity:
Exotoxicity is expected to be low based on the high
vapor pressure of the ingredients and very low amount
of polymer present in each can.
Environmental Fate:
No information found in our selected references.
Bioaccumulation:
Not expected to occur.
This material is meant to be used until a can is empty. The only thing possibly remaining in the can would be a small amount of polymer residue, much like would be left over from a consumer can of hair spray. Disposal then should be according to local, state and federal regulations. The aerosol can itself should be suitable for recycling.
Proper Shipping Name:
Ethyl alcohol (DOT) and Ethanol (IATA)
DOT Hazard Class:
3 Flammable Liquid
UN/NA ID:
UN #1170
Packing Group:
II
Labels:
Flammable 3
Marine Pollutant:
No
TSCA:
All components of this product are listed on the TSCA 8(b)
inventory. If identified components of this product are
listed under the TSCA 12(b) Export Notification Rule,
they will be listed below.
TSCA 12(b) Component Listed under TSCA Section
SARA-Section 313 Emissions Reporting:
Component Reporting Threshold
SARA-Section 311/312:
No components present in this product are subject to the
reporting requirements of this statute.
CERCLA Hazardous Substances and their Reportable Quantities:
Component Reportable Quantity
California Prop. 65:
Proposition 65 requires manufacturers or distributors of
consumer products into the State of California to provide
a warning statement if the product contains ingredients
for which the State has found to cause cancer, birth defects
or other reproductive harm. If this product contains an
ingredient listed by the State of California to cause
cancer or reproductive toxicity, it will be listed below:
Disclaimer of Liability:Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
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