Information System
USA
Protection Association
USA
SPI Supplies Division
Date Effective......... May 18, 2007
(most recent revision)
Chemical Name/Synonyms. 1,1,2,2,3,3,3-hexafluoro propene,
oxidized, polymerized;
FOMBLIN® 25/6(Y-25) Perfluorinated
Polyether Mechanical Pump Fluid
Chemical Family: Fluorocarbons, Perfluorinated polyethers
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s...
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #00073-MB, 00073-XQ Fomblin® 25/6 (Y-25)
Synonyms................. 1,1,2,2,3,3,3-hexafluoro propene, oxidized, polymerized
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Hazardous Material Information System USA |
Health | 1 |
National Fire Protection Association USA |
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| Fire Hazard | 0 | |||
| Reactivity | 0 | |||
| Personal Protection |
Component Name CAS # Percent EINECS/ELINCS
1,1,2,2,3,3,3-hexafluoro propene, oxidized, polymerized
69991-67-9 100 not listed
Emergency overview: Clear, colorless liquid. Thermal decomposition product is hydrogen fluoride (HF), which is corrosive. Appearance: Clear, colorless liquid Flash Point: Not available Potential Health Effects Eye: May cause slight eye irritation by eye contact. Skin: May cause slight irritation by skin contact. Ingestion: May cause nausea and vomiting if ingested. Inhalation: May cause respiratory tract irritation.
Eyes: In case of eye contact, flush with copious amounts of water for at least 15 minutes. Seek medical attention if irritation persists. Skin: Wash thoroughly with mild soap and water. Flush with lukewarm water for at least 15 minutes. Ingestion: If conscious and alert, give three or four 8 ounce glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. If person is unconscious, immediately take person to the hospital. Inhalation: If symptoms of discomfort or irritation occur, immediately remove to fresh air. Give oxygen or artificial respiration as needed. Seek medical attention. Notes to Physician: None additional.
General Information:
Fluoropolymers will degrade upon prolonged heating or in fire conditions to
liberate carbonyl fluoride and hydrogen fluoride (HF). This gas is toxic if
inhaled or if it comes in contact with moist skin. HF has an ACGIH TLV of 3 ppm
(2.6 mg/m3) and an OSHA PEL TWA of 3 ppm. Carbonyl fluoride has and ACGIH TLV
TWA and OSHA PEL TWA of 2 ppm (5 mg/m3).
Use self-contained breathing apparatus and skin protection for acid gas
exposure. Do not enter fire area without proper protection. Fight fire from a
safe distance, using air monitoring if possible.
Extinguishing Media:
Water spray, water fog, foam, dry chemical, carbon dioxide
Flash Point: Not available
Explosion Limits: Not available
Upper: Not available
Lower: Not available
Autoignition Temperature: Not available
General Information: Extinguish all sources of ignition and evacuate the area. Use caution – the spill area may be slippery. Spills/Leaks: Absorb spilled material onto vermiculite or other inert material and place spilled material into a covered container for disposal. Use Perfluorosolv PFS1 Solvent to clean up any residual material. Dispose of in accordance with all federal, state, and local environmental regulations.
Handling: Wash hands thoroughly after use and before handling food or applying cosmetics. Do not use food or tobacco products in the immediate area. Keep containers closed. Storage: Store in closed containers in cool, dry area. Store away from heat, sparks, and flames. Do not store near combustible materials.
Engineering Controls:
Local exhaust ventilation at a rate of 50 feet per minute.
Exposure Limits:
Chemical Name ACGIH OSHA - Final PELs
1,1,2,2,3,3,3-hexafluoro propene, oxidized, polymerized
none established none established
OSHA Vacated PELs: None established
Personal Protective Equipment
Eyes: Chemical safety glasses with side shields to meet ANSI Z87.1, or
equivalent
Skin: Rubber or latex gloves recommended
Clothing: None listed.
Respirators: No occupational standards have been developed for this
material. Where exposure to vapors or mists is likely, NIOSH/MSHA approved
respirators are recommended. Respiratory protection programs must be in
accordance with 29 CFR 1910.134.
Physical State: Liquid
Appearance: Clear, colorless
Odor: Odorless
pH: Not available
Vapor Pressure: Not available
Vapor Density: Not available
Evaporation Rate: Not available
Viscosity: Not available
Boiling Point: Not available
Freezing/Melting Point: Not available
Autoignition Temperature: Not available
Flash Point: Not available
Decomposition Temperature: Not available
Explosion Limits:
Lower: Not available
Upper: Not available
Solubility in water: Insoluble
Specific Gravity/Density: 1.7 – 1.9
Molecular Formula: CF3-[(O-CF-CF3-CF2)n-(O-CF2)m-O-CF3
Molecular Weight: Not available
% Volatile by Volume: 0
Chemical Stability: This material is stable. Conditions to Avoid: Heat, sparks, flames, ignition sources; temperatures above 290°C (554°F). Incompatibility with Other Materials: Strong alkali, non-aqueous alkali, or Lewis acids above 100° C (212°F). Halogenated compounds. Hazardous Decomposition of Products: Thermal decomposition will generate hydrogen fluoride (HF) and carbonyl fluoride, which are corrosive, causing burns on contact with skin or other tissue. Reactivity: This material is not reactive.
RTECS#: Not available LD50/LC50 Information: CAS #: 69991-67-9 LD50 Rat, oral >25.65 g/kg LD50 Rat, intraperitoneal >25 g/kg LD50 Rat, dermal >2 g/kg Rabbit, skin not irritating Rabbit, eye not irritating Guinea pig not a sensitizer
There is no ecotoxicological information available for this product.
RCRA P-Series: Not listed RCRA U-Series: Not listed Material, as supplied, is not a hazardous waste. Landfill according to current federal, state and local regulations, or incinerate in a high-temperature incinerator designed to burn fluorine-containing materials. Processing, or use contamination, may make this information incomplete or inaccurate.
US DOT Hazard Class: Not regulated. IATA (for international shipments): Not regulated.
United States: TSCA All components of this product are listed on the TSCA Inventory Health & Safety Reporting List None of the components of this product are listed on the Health & Safety Reporting List. Chemical Test Rules None of the components of this product is under a Chemical Test Rule. Section 12b: None of the components of this product is listed under TSCA Section 12b. TSCA Significant New Use Rule: None of the components of this product has a TSCA SNUR. CERCLA Section 103: None of the components of this product is listed under CERCLA Section 103. SARA: Section 302 (RQ) None of the components of this product has an RQ. Section 302 (TPQ) None of the components of this product has a TPQ. SARA Codes Section 311/312 Acute: no Chronic: no Fire: no Reactivity: no Sudden Release of Pressure: no Section 313 Not listed Clean Air Act: Not listed Clean Water Act: Not listed OSHA: This product is not a “hazardous substance” as defined by OSHA Hazard Communication Standard (29 CFR 1910.1200). State (Individual states in the USA) Not listed California Prop. 65: Not listed European/International Regulations: European Labeling in Accordance with EC Directives Hazard Symbols: Not available Risk Phrases: Not available Safety Phrases: Not available Canada This product has a WHMIS classification of: This product is not a “controlled product” as defined by WHMIS. DSL/NDSL: This product is listed on the DSL List. This product is not listed on the NDSL List.
Disclaimer of Liability:
Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation.
Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies or SPI authorized agents and distributors, and in original SPI Supplies packaging, as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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