Information System
USA
Protection Association
USA
SPI Supplies Division
Section 01 Identification
Date Effective......... February 05, 2007
(most recent revision)
Chemical Name/Synonyms: Not known
Chemical Family......... HCFC's mixture
Synonyms............... Mixture
Emergencies Contacting CHEMTREC 24 Hour Emergency
Use Only #'s.... Worldwide phone : 1-(703)-527-3887
Worldwide FAX : 1-(703)-741-6090
Toll-free phone : 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #00025-XK and #00025-XM
Asahiklin® AK225
Emergency Overview:
Water white clear liquid. Warning! High concentrations
of vapor can reduce oxygen available for breathing. Harmful
if inhaled. May decompose on contact with flames or extremely
hot metal surfaces to produce toxic and corrosive products.
Chemical Name CAS # EINECS# Weight % 3,3-dichloro-1,1,1,2,2-pentafluoropropane (HCFC-225ca) CAS#422-56-0 2070169 42-52 1,3-dichloro-1,1,1,2,3-pentrfluoropropane (HCFC-225cb) CAS#507-55-1 2080769 50-60
| Hazardous
Material Information System USA | Health | 1 | National Fire Protection Association USA | |
| Fire Hazard | 1 | |||
| Reactivity | 0 | |||
| Personal Protection |
Eyes: Check for and remove any contact lens. In case of contact, immediately flush eyes with copious amounts of flowing water for at least 15 minutes, retracting eye lids often. Get medical attention if irritation persists. Skin: Immediately wash skin thoroughly with plenty of water. Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Ingestion: If swallowed, gently wipe or rinse the inside of the mouth with water. Do not induce vomiting. Sips of water may be given if person is fully conscious. Never attempt to give anything by mouth to an unconscious or convulsing person. Immediately contact a poison control center, emergency room or physician as further treatment may be necessary. Inhalation: Remove from exposure area to fresh air immediately. If not breathing, give artificial respiration or give oxygen by trained personnel. Get medical attention immediately. Notes to physician: Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of symptoms and the clinical conditions.
Flammability classification: Not flammable
Auto-Ignition Temperature: Not applicable
Flammable Properties:
Flash Point: Not available.
Flammable Limits: Lower: Not available
Upper: Not available
Flash Point/Method: None
Extinguishing Media:
Use alcohol foam, carbon dioxide, or water spray when fighting fires
involving this material.
Fire Fighting Procedures:
Use water spray to keep fire-exposed containers cool and to knock down
vapors which may result from product decomposition.
Fire Fighting Equipment:
As in any fire, wear self-contained breathing apparatus pressure-demand
(MSHA/NIOSH approved or equivalent) and full protective gear.
Hazardous Decomposition Products:
Toxic oxides of carbon and corrosive vapors of hydrogen chloride
Small spill and leak: Contain spill with dike to prevent entry into sewers Large spill and leak: If this material is released into a work area, evacuate the area immediately. General procedures: Dike areas to contain spill. Take precautions as necessary to prevent contamination of ground and surface waters. Recover spilled material on absorbent, such as sawdust or vermiculite, and sweep into closed containers for disposal. After all visible traces, including vapors, have been removed, thoroughly wet vacuum the area. Do not flush to sewers. If area of spill is porous, remove as much of the contaminated earth, gravel, etc. as necessary and place in closed containers for disposal. Special protective equipment: Only personnel equipped with proper respiratory and skin/eye protection should be permitted in area. See Section 8 for details. Recommended disposal: Dispose according to applicable local, state/provincial and federal regulations.
General Procedures: Contents may be under pressure. Exercise caution when opening container. If containers have been stored in direct sunlight or heating above the boiling point of the solvent, the container should be cooled to below the boiling point before opening. Handling: Use with sufficient ventilation to keep employee exposure below recommended limits. Provide adequate ventilation for storage, handling, and use, especially for enclosed or low spaces. Avoid contact of liquid with eyes and prolonged skin exposure. Do not allow product to contact open flame or electrical heating elements because dangerous decomposition products may form. Storage: Store in a cool, well-ventilated area of low fire risk. Storage in subsurface locations should be avoided. If container temperature exceeds boiling range, cool the container before opening.
Exposure Guidelines
OSHA Hazardous Components (29CFR 1910.1200)
Exposure limits
OSHA PEL ACGIH TLV Supplier OEL
ppm mg/m3 ppm mg/m3 ppm mg/m3
3,3-dichloro-1,1,1,2,2-pentafluoropropane TWA 100¹
STEL²
1,3-dichloro-1,1,1,2,3-pentrfluoropropane TWA 100
-----------------
¹ Limit established by supplier
² Not established
Engineering Controls:
Use process enclosures, local exhaust ventilation,or other engineering
controls to control airborne levels below recommended exposure limits.
Personal Protective Equipment:
Eyes and Face:
For normal conditions, wear safety glasses. Where there is reasonable
probability of liquid contact, wear splash-proof goggles.
Skin:
The gloves listed below may provide protection against permeation. Gloves
of other chemically resistant materials may not provide adequate protection.
Buna
Butyl
Neoprene
Solvex
Viton
Respiratory:
A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a
respirator's use.
Other use precautions:
Emergency shower and eyewash facility should be in close proximity.
Appearance: "Water white" clear liquid Color: Colorless Odor: Faint ethereal odor pH: Not applicable Vapor Pressure: Not known Vapor Density (Air=1): 7.0 Boiling Point/Range: Decomposes 54°C /129°F Melting Point/Range: Not available Specific Gravity at 60°F (15°C): Not known Solubility in water: Insoluble Molecular Formula: Not known Molecular Weight: Not available %Volatile by Volume: 100% Softening Point: Not applicable Viscosity: Not available VOC: 0 to 0 g/liter (non-exempt VOC) Octaonol/Water Partition Coefficient: Not determined Saturated Vapor Concentration: Not determined Molecular Weight: Not determined
Conditions to Avoid: Material is stable but it might decompose if heated. Stability: Stable Polymerization: Will not occur. Hazardous decomposition products: May form hydrochloric and hydrofluoric acids,possible carbonyl halides, when exposed to high temperatures. Incompatibility (materials to avoid): Oxidizing agents, alkalies, and bases.
Acute: Eyes: Moderately to severely irritating Dermal, LD50: Mildly to moderately irritating Oral LD50: Slight to very low toxicity Inhalation LC50: Slight to very low toxicity Skin Effects:
Exotoxicity: Invertebrate toxicity: LC50 (30 minutes). Photobacterium phosphoreum = 1540ppm Microtoxicity test. Environmental data: There is limited information available on the environmental fate and effects of this material. The primary environmental concern for release is the impact on aquatic and terrestrial species. Due care should be taken to avoid the accidental release of this material into the environment.
Disposal method: Recover by distillation or remove to permitted waste disposal facility. Comply with federal, state and local environmental control regulations. For large spills: Contaminated sawdust, vermiculite, or porous surfaces must be disposed of in a permitted hazardous waste management facility. Recovered liquids may be reprocessed or incinerated or must be treated in a permitted hazardous waste management facility. General Comments: Dispose of in a manner consistent with federal,state, and local environmental control regulations.
Proper Shipping Name: Nonhazardous DOT Hazard Class: Non-Regulated UN/NA ID: Not Regulated Packing Group: Not Applicable Labels: Not Regulated Marine Pollutant: No information DOT Status: Not Regulated Air (ICAO/IATA) Proper shipping name: Nonhazardous UN/NA Number: Not regulated Packing group: Not applicable
All components of this product are listed on the Toxic Substance Control
Act (TSCA).
SARA Section 302/304 Extremely Hazardous Substances:
No listed ingredients are present on the 302/304 list.
SARA 311/312 Categories:
Immediate/Delayed
SARA Section 313 Toxic Chemicals:
If none listed here or in Section 2, there are no 313 chemicals
present above threshold value.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA): 112 accidental release prevention: No products found
Clean Air Act (CAA): 112 regulated toxic substances: No products found
Clean Air Act (CAA): 112 regulated flammable substances: No products found
Clean Air Act (CAA): Section 602: CAS# 422-56-0 and CAS# 507-55-1 are Class II
Ozone Depletors and are regulated under the accelerated phaseout.
CERCLA (Comprehensive Response, Compensation, and Liability Act)
CERCLA Regulatory Information:
Releases to air, land, or water which exceed the RQ must be reported
to the National Response Center [In USA: 1-(800)-424-8802] and to
your Local Emergency Planning Committee.
State regulations:
No products were found.
No component present in this product at > 0.1% is presently listed as a
carcinogen by IARC, NTP, or OSHA.
California Prop. 65:
Proposition 65 requires manufacturers or distributors of consumer
products into the State of California to provide a warning statement
if the product contains ingredients for which the State has found to
cause cancer, birth defects or other reproductive harm. If this product
contains an ingredient listed by the State of California to cause cancer
or reproductive toxicity, it will be listed below:
No ingredients have been found.
Canada:
WHIMS (Worker Hazardous Materials Information System):
This MSDS has been prepared according to the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of
the information required by CPR.
WHIMS Class:
Class D2B - Toxic Materials
DSL/NDSL
CAS# 422-56-0 is listed on the NDSL list.
CAS# 507-55-0 is listed on the NDSL list.
European Community:
Hazard Symbols: Xn Harmful
Risk Phrases:
R20 Harmful by inhalation
R36/38 Irritating to eyes and skin
Safety Phrases
S24/25 Avoid contact with skin and eyes
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.********************************************************************** The information and recommendations set forth above are taken from sources believed to be accurate as of the date hereof, however SPI Supplies and Structure Probe, Inc. make no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assume no liability to any user thereof. The information contained in this sheet does not constitute a hazard assessment and should not be used in place of the user's own assessment of work place risks as required by other health and safety legislation. Be aware of the Structure Probe, Inc. Copyright Policy. Structure Probe, Inc. grants a nonexclusive license to make unlimited copies of this safety sheet for internal use only. Quite obviously, this information would pertain only to this material when purchased from SPI Supplies as product from other sources, with other ingredients and impurity levels could have substantially different properties.
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