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Date Effective........... April 5, 2006
(most recent revision)
Chemical Name/Synonyms... Glutaraldehyde; 1,5-Pentanedial; Glutaral;
Emergencies
Contacting CHEMTREC:
24 Hour Emergency Use Only #'s......
Worldwide phone: 1-(703)-527-3887
Worldwide FAX: 1-(703)-741-6090
Toll-free phone: 1-(800)-424-9300 USA only
Product or Trade Name.... SPI #02605-BA, 02607-BA, Glutaraldehyde,
Aqueous Solution, 8-25%
| Hazardous
Material Information System USA | Health | 3 | National Fire Protection Association USA |  |
| Fire Hazard | 0 | |||
| Reactivity | 1 | |||
| Personal Protection |
Component Name CAS # Percent EINECS/ELINCS Glutarladehyde 111-30-8 8-25% 203-856-5 Water 7732-18-5 92-75% 231-791-2
Emergency overview: Appearance: Clear, colorless liquid. Flash Point: None, Tag Closed Cup (ASTM D56) Warning! Causes burns of eye, skin, digestive tract, respiratory tract. May cause sensitization. Harmful if swallowed, inhaled, or absorbed through skin. Aspiration hazard if swallowed - can enter lungs and cause damage. Target Organs: Central nervous system, lungs, respiratory system, eyes, skin Potential Health Effects Eye: Liquid will cause severe and persistent conjunctivitis, including excess redness and swelling of the conjunctiva with profuse discharge. May develop severe corneal injury; permanent impairment of vision possible. Vapor will cause stinging sensations with excess tear production, blinking and redness of the conjunctiva. Seek medical attention immediately. Skin: May cause skin sensitization May cause hives. Brief contact will cause itching with mild to moderate local redness and possible swelling. Prolonged contact may result in pain, severe redness and swelling, with ulceration, tissue destruction and possible bleeding into inflamed area. Contact with glutaraldehyde solutions may result in a harmless yellow or brownish discoloration of the skin. Ingestion: Moderately toxic. May cause moderate to marked irritation and chemical burns of the mouth, throat, esophagus and stomach. May cause discomfort or pain in the chest and abdomen, nausea, vomiting, diarrhea, dizziness, faintness, drowsiness, thirst. Advanced cases may cause weakness, circulatory shock, collapse, coma, or death due to respiratory failure. Aspiration hazard: May cause damage to the lungs. Inhalation: Harmful if inhaled. Causes chemical burns to the respiratory tract. May cause bleeding from the nose, coughing, chest discomfort and tightness, difficulty breathing, and headache. May cause asthma and shortness of breath. Chronic: Effects may be delayed. May aggravate an existing dermatitis. May cause skin sensitization and allergic reaction.
Eyes: Immediately flush eyes with copious amounts of water for at least 15 minutes, lifting the upper and lower eyelids. Seek immediate medical attention - ophthalmologist recommended. Skin: Immediately flush skin with copious amounts of water for at least 15 minutes. Seek medical attention immediately. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: DO NOT INDUCE VOMITING. Urgently seek immediate medical attention. Do NOT give anything to drink. Call a poison control center. Oral toxicity of Glutaraldehyde increases with dilution - drinking water can enhance the toxicity. Inhalation: Seek medical attention immediately. Remove to fresh air. If breathing is difficult, administer oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration by use of oxygen and suitable mechanical device such as a bag and a mask. Notes to Physician: Treat symptomatically and supportively.
General Information: Flash Point: None, Tag Closed Cup (ASTM D56). Flammable limits: Not determined (aqueous system). Extinguishing Media: Non-flammable. After the water evaporates, the remaining material will burn. Use alcohol-type or all-purpose-type foam applied by manufacturer's recommended technique for large fires. Use CO2 or dry chemical media for small fires. Use self-contained breathing apparatus and protective clothing.
General Information: Use proper personal protective e1quipment as indicated in Section 8. Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions listed in the Protective Equipment section. Absorb spill using absorbent, non-combustible material such as sand, earth, or vermiculite. Provide ventilation.
Handling: Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin or clothing. Use only with adequate ventilation. Avoid breathing vapor. Storage: Keep container tightly closed when not in use. Store in cool, dry, well-ventilated area away from incompatible substances. Refrigeration recommended.
Engineering Controls: Use local exhaust ventilation or other engineering controls to maintain airborne levels below recommended exposure limits. An eyewash facility and a safety shower should be readily available. Exposure Limits: Chemical Name ACGIH NIOSH OSHA - Final PELs Glutaraldehyde 0.05 ppm Ceiling none listed none listed Water none listed none listed none listed OSHA Vacated PELs: None listed Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or there symptoms are experienced.
Physical State: Liquid Appearance: Clear, colorless Odor: Sharp odor pH: n/a Vapor Pressure: 15 mm Hg @ 20oC Vapor Density: 1.05 (air=1) Evaporation Rate: 0.93 (Butyl acetate =1) Viscosity: n/a Boiling Point: 101 oC Freezing/Melting Point: -21 oC Autoignition Temperature: n/a Flash Point: none Decomposition Temperature: n/a Explosion Limits Lower: n/a Upper: n/a Solubility in water: soluble Specific Gravity/Density: 1.131 g/ml Molecular Formula: C5H8O2 Molecular Weight: 100.5
Chemical Stability: Stable Conditions to Avoid: High Temperatures Incompatibility with Other Materials: Strong oxidizing agents, contamination with acids or bases Hazardous Decomposition of Products: carbon monoxide or carbon dioxide Hazardous Polymerization: Non-hazardous polymerization may occur. Avoid initiators, accelerators, heat, pressure, and contamination.
RTECS#: 111-30-8: MA2450000 7732-18-5: ZC0110000 LD50/LC50 Information: CAS # 111-30-8; Draize test, rabbit, eye: 1 mg Severe Draize test, rabbit, eye: 250ug/24H Severe Inhalation, rat: LC50=480 mg/m3/4h Oral, mouse: LD50= 100 mg/kg Oral, rat: LD50=2231 mg/kg Carcinogenicity: CAS# 111-30-8 is not listed by ACGIH, IARC, NTP, OR CA Prop 65. CAS# 7732-18-5 is not listed by ACGIH, IARC, NTP OR CA Prop 65 Teratogenicity: See RTECS entry for complete information Reproductive Effects: n/a Neurotoxicity: n/a Mutagenicity: n/a Other Studies: n/a
n/a
Dispose of in accordance with all federal, state and local regulations. RCRA P-Series: none listed RCRA U-Series: none listed
US DOT Hazard Class: Non-hazardous from stand point of shipping. IATA (for international shipments) Non-hazardous from stand point of shipping
United States:
TSCA
CAS# 111-30-8 is listed on the TSCA Inventory.
CAS# 7732-18-5 is listed on the TSCA Inventory.
Health & Safety Reporting List
None of the chemicals in this product is on the Health & Safety
Reporting list.
Chemical Test Rules
None of the chemicals in this product is under a Chemical Test Rule.
Section 12b:
None of the chemicals in this product is listed under TSCA Section 12b.
TSCA Significant New Use Rule:
None of the chemicals in this product has a SNUR under TSCA.
CERCLA Hazardous Substances:
None of the chemicals in this product has an RQ.
SARA Section 302 (TPQ)
None of the chemicals in this product has a TPQ.
SARA Codes
CAS# 111-30-8: Immediate
Section 313
None of the chemicals in this product is reportable under Section 313.
Clean Air Act:
This product does not contain any hazardous air pollutants, any Class 1 Ozone
depletors, or and Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product is listed as a Hazardous Substance, as a
Priority Pollutant, or as a Toxic Pollutant under the CWA.
OSHA:
None of the chemicals in this product is considered highly hazardous by OSHA.
State (Individual states in the USA)
CAS# 111-30-8 can be found on the California, Massachusetts, Minnesota, New Jersey,
and Pennsylvania right to know list.
CAS# 7732-18-5 is not present on any state list.
California Prop. 65:
California No Significant Risk Level: None of the chemicals in this
product is listed.
European/International Regulations:
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R22 Harmful if swallowed
R23 Toxic by inhalation
R34 Causes burns
R42 May cause sensitization by inhalation
R43 May cause sensitization by skin contact
Safety Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice
S36 Wear suitable protective clothing
S37 Wear suitable gloves
S38 Wear eye/face protection
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/safety
data sheets.
WGK (Water Danger/Protection):
CAS#111-30-8: 2
CAS#7732-18-5: n/a
Canada DSL/NDSL:
Cas# 111-30-8 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
Canada - WHMIS:
This product has a WHMIS Classification of D1B, E, D2A, D2B
Canadian Ingredient Disclosure List:
CAS# 111-30-8 is listed on the Canadian Ingredient Disclosure List.
Disclaimer of Liability: Caution! Do not use SPI Supplies products or materials in applications involving implantation within the body; direct or indirect contact with the blood pathway; contact with bone, tissue, tissue fluid, or blood; or prolonged contact with mucous membranes. Products offered by SPI Supplies are not designed or manufactured for use in implantation in the human body or in contact with internal body fluids or tissues. SPI Supplies will not provide to customers making devices for such applications any notice, certification, or information necessary for such medical device use required by US FDA (Food and Drug Administration) regulation or any other statute. SPI Supplies and Structure Probe, Inc. make no representation, promise, express warranty or implied warranty concerning the suitability of these materials for use in implantation in the human body or in contact with internal body tissues of fluids.
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